Eletrodeposição de ligas Zn-Co por corrente contínua e pulsada simples, a partir de banhos ambientalmente não agressivos

Revestimentos produzidos a partir de ligas de Zn-Co são comumente utilizados em indústrias (aeronáutica, de isoladores elétricos e automobilística, por exemplo) devido à sua ótima resistência à corrosão, principalmente quando comparados aos tradicionais revestimentos de Zn puro. Na co-deposição de zinco com metais, como o ferro, cobalto e níquel, ocorre o que se chama de deposição anômala, onde o metal menos nobre (zinco) é preferencialmente depositado, independente do modo de corrente aplicada (contínua ou pulsada). Recentemente, diversos trabalhos relacionam a produção de eletrodepósitos de liga Zn-Co a partir de banhos ambientalmente não agressivos, a fim de substituir os banhos alcalinos extremamente tóxicos, a base de cianeto. Na presente dissertação foram produzidos revestimentos de ligas de Zn-Co sobre substrato de aço carbono, empregando corrente contínua ou corrente pulsada simples, a partir de banhos contendo diferentes concentrações de Co2+ (0,05 mol/L e 0,10mol/L), 0,05 mol/l de Zn2+ e citrato de sódio (0,10 mol/L) como agente complexante, sob condições agitadas. Quatro diferentes valores de densidade de corrente (10 A/m2, 20 A/m2, 40 A/m2 e 80 A/m2) e de frequência de pulso (100 Hz, 500 Hz, 1000 Hz, 2000 Hz) foram aplicados para a produção da liga a partir dos dois banhos, tendo como objetivo avaliar a influência dos parâmetros de deposição(concentração de Co (II), densidade de corrente aplicada e, no caso de deposição por corrente pulsada simples, também da frequência de pulso), nas variáveis eficiência de corrente catódica, composição da liga, densidade de corrente de corrosão, microestrutura e morfologia dos depósitos de liga Zn-Co. As cores das camadas obtidas variaram do cinza claro ao escuro, quase sempre sem brilho, independente do modo de corrente empregado. Foi verificado que o processo normal de eletrodeposição foi prevalente na produção de revestimentos por corrente contínua, enquanto que apenas deposição anômala foi observada quando do uso de corrente pulsada. A maior eficiência de corrente catódica (60%) foi obtida, para corrente contínua, nas condições de menor concentração de Co2+ (0,05 mol/L) e maior densidade de corrente (80 A/m2). Nestas mesmas condições foi determinada uma eficiência de corrente catódica de 98% para corrente pulsada simples na freqüência de 2000 Hz. Maiores teores do metal mais nobre (cobalto) foram alcançados em maiores densidades de corrente para todas as condições empregadas. Os revestimentos assim obtidos apresentavam os menores valores de tamanho de grão, para cada uma das soluções estudadas. Os demais parâmetros estudados também influenciaram na granulometria e na morfologia das ligas obtidas. Revestimentos com melhor resistência à corrosão, contendo teores de cobalto entre aproximadamente 8 e 10% m/m, foram produzidos a partir do banho com maior concentração de Co2+, sob corrente pulsada simples

Um esquema de Fourier local para análise tempo-frequência de sinais não-estacionários aplicado a ruído eletroquímico

Sinais diversos estão presentes em nosso cotidiano, assim como nas medidas realizadas nas atividades de ciência e tecnologia. Dentre estes sinais, tem grande importância tecnológica aqueles associados à corrosão de estruturas metálicas. Assim, esta tese propõe o estudo de um esquema local de transformada de Fourier janelada, com a janela variando em função da curtose, aplicada a sinais de ruído eletroquímico. A curtose foi avaliada nos domínios do tempo e da frequência e processada pelo programa desenvolvido para esse fim. O esquema foi aplicado a sinais de ruído eletroquímico dos aços UNS S31600, UNS G10200 e UNS S32750 imersos em três soluções: FeCl3 0,1 mol=L (cloreto férrico), H2SO4 5%(ácido sulfúrico) e NaOH 0,1%(hidróxido de sódio). Para os aços inoxidáveis, estas soluções promovem corrosão localizada, uniforme e passivação, respectivamente. Visando testar o desempenho do esquema de Fourier desenvolvido, testes foram realizados utilizando-se inicialmente sinais sintéticos e em seguida sinais de ruído eletroquímico. Notou-se que os sinais têm características de não-estacionaridade e a maior parte da energia está presente em baixa frequência. Os intervalos de tempo e de frequência onde se concentra a maior parte da energia do sinal foram correlacionados. Para os picos máximos dos sinais de potencial e corrente obtidos de amperimetria de resistência nula, a correlação entre eles foi baixa, independente da forma de corrosão presente. Conclui-se que o método se adaptou bastante bem às características locais do sinal eletroquímico permitindo o monitoramento dos espectros tempo-frequência. O fato de ser sensível às características locais do sinal permite analisar aspectos dos sinais que do modo clássico não podem ser diretamente processados. O método da transformada de Fourier janelada variável (Variable Short-Time Fourier Transform - VSTFT) adaptou-se muito bem no monitoramento dos sinais originados de potencial de circuito aberto e amperimetria de resistência nula.

First Annual Report for the year ended 31st March, 1966

This is the first Annual report of the Cumberland River Authority on information of its activities and responsibilities on river management in its area between the beginning of April 1965, to the end of March 1966. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes periodical surveys, hydrometric schemes, acceptable flows, conservation works and a review of rainfall and river flow. The section on land drainage looks at work on improvement schemes, floods, charges and information on maintenance work carried out on rivers including Wampool, Waver, Marron, Irt, Esk, Eden, Caldew, Petteril, Eamont and Annas. The fisheries section covers 5 districts of the River Eden, Esk, Ellen, Derwent, and South West Cumberland. It includes angling information and a general report for salmon and sea trout, brown trout and freshwater fish. It also looks at fish hatchery, fisheries protection and byelaws including licence numbers issued for the different districts. The fourth section on pollution deals with water quality of the rivers and their tributaries from the same 5 areas mentioned above. It also covers information on sewage and trade effluents. The River Authorities preceded the Environment Agency which came into existence in 1996.

Second Annual Report for the year ended 31st March, 1967

This is the second Annual report of the Cumberland River Authority on information of its activities and responsibilities on river management in its area between the beginning of April 1966, to the end of March 1967. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes periodical surveys, hydrometric schemes, acceptable flows, conservation works and a review of rainfall and river flow. The section on land drainage looks at work on improvement schemes, floods, charges and information on maintenance work carried out on rivers including Wampool, Waver, Marron, Ellen, Derwent, Esk, Eden, Caldew, Petteril, Eamont, Gelt and Annas. The fisheries section covers 5 districts of the River Eden, Esk, Ellen, Derwent and South West Cumberland. It includes angling information and a general report for salmon and sea trout, Brown trout and freshwater fish. Fish disease and fish hatchery are also included as well as fisheries protection and byelaws. The fourth section on pollution deals with water quality and the results of samples taken from rivers Eden, Eamont, Caldew, Calder, Derwent, Ehen, Ellen, Wampool and Waver are also given. It also covers information on sewage and trade effluents. The River Authorities preceded the Environment Agency which came into existence in 1996.

Third Annual Report for the year ended 31st March, 1968

This is the third Annual report of the Cumberland River Authority on information of its activities and responsibilities on river management in its area between the beginning of April 1967, to the end of March 1968. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes periodical surveys, hydrometric schemes, acceptable flows, conservation works and a review of rainfall and river flow. The section on land drainage looks at work on improvement schemes, floods, charges and information on maintenance work carried out on rivers including Wampool, Waver, Glenderamackin, Marron, Eden, Caldew, and Lyvennet. The fisheries section covers 5 districts of the River Eden, Esk, Ellen, Derwent and South West Cumberland. It includes angling information and a general report for salmon and sea trout, brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as fisheries protection and licence duties. The fourth section on pollution deals with water quality, and the results of samples taken from rivers Eden, Eamont, Petteril, Caldew, Calder, Derwent, Ehen, Ellen, Wampool and Waver are also given. It also covers information on sewage and trade effluents. The River Authorities preceded the Environment Agency which came into existence in 1996.

Fourth Annual Report for the year ended 31st March, 1969

This is the fourth Annual report of the Cumberland River Authority on information of its activities and responsibilities on river management in its area between the beginning of April 1968, to the end of March 1969. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes periodical surveys, hydrometric schemes, acceptable flows, conservation works and a review of rainfall and river flow. The section on land drainage looks at work on improvement schemes, floods, charges and information on maintenance work carried out on rivers including Wampool, Waver, Marron, Ellen, Eden, Caldew, Esk, Annas, Irt and Glenderamackin. The fisheries section covers 5 districts of the River Eden, Esk, Ellen, Derwent and South West Cumberland. It includes angling information and a general report for salmon and sea trout, Brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as fisheries protection and licence duties. The fourth section on pollution covers water quality, and the results of samples taken from rivers Eden, Eamont, Petteril, Caldew, Calder, Derwent, Ehen, Ellen, Wampool and Waver are also given. It also covers information on sewage and trade effluents. The River Authorities preceded the Environment Agency which came into existence in 1996.

Fifth Annual Report for the year ended 31st March, 1970

This is the fifth Annual report of the Cumberland River Authority on information of its activities and responsibilities on river management in its area between the beginning of April 1969, to the end of March 1970. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, wich includes periodical surveys, hydrometric schemes, acceptable flows, conservation works and a review of rainfall and river flow. The section on land drainage looks at work on improvement schemes, floods, charges and information on maintenance work carried out on rivers including Wampool, Waver, Derwent, Ellen, Mite, Bleng, Eden, Caldew and Petteril. The fisheries section covers 5 districts of the River Eden, Esk, Ellen, Derwent and South West Cumberland. It includes angling information and a general report for salmon and sea trout, brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as fisheries protection and licence duties. The fourth section on pollution deals with water quality, and the results of samples taken from rivers Eden, Eamont, Petteril, Caldew, Calder, Bleng, Derwent, Ehen, Ellen, Wampool and Waver are also given. It also covers information on sewage and trade effluents. The River Authorities preceded the Environment Agency which came into existence in 1996.

Sixth Annual Report for the year ended 31st March, 1971

This is the sixth Annual report of the Cumberland River Authority on information of its activities and responsibilities on river management in its area between the beginning of April 1970, to the end of March 1971. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes periodical surveys, hydrometric schemes, acceptable flows, conservation works and a review of rainfall and river flow. The section on land drainage looks at work on improvement schemes, floods, charges and information on maintenance work carried out on rivers including Wampool, Waver, Derwent, Eden, Mite, Bleng, Annas and Irt. The fisheries section covers 5 districts of the River Eden, Esk, Ellen, Derwent and South West Cumberland. It includes angling information and a general report for salmon and sea trout, brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as fisheries protection and licence duties. The fourth section on pollution deals with water quality, and the results of samples taken from rivers Eden, Eamont, Petteril, Caldew, Calder, Irt, Derwent, Ehen, Ellen, Wampool and Waver are also given. It also covers information on sewage and trade effluents. The River Authorities preceded the Environment Agency which came into existence in 1996.

Seventh Annual Report for year ended 31st March, 1972

This is the seventh Annual report of the Cumberland River Authority on information of its activities and responsibilities on river management in its area between the beginning of April 1971, to the end of March 1972. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes periodical surveys, hydrometric schemes, acceptable flows, conservation works and a review of rainfall and river flow. The section on land drainage looks at work on improvement schemes, floods, charges and information on maintenance work carried out on rivers including Wampool, Waver, Derwent and Eden. The fisheries section covers 5 districts of the River Eden, Esk, Ellen, Derwent and South West Cumberland. It includes angling information and a general report for salmon and sea trout, brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as fisheries protection and licence duties. The fourth section on pollution deals with water quality, and the results of samples taken for chemical analysis from rivers Eden, Eamont, Petteril, Caldew, Calder, Irthing, Esk, Irt, Mite, Derwent, Ehen, Wampool and Waver are also given. It also covers information on sewage and trade effluents. The River Authorities preceded the Environment Agency which came into existence in 1996.

Eighth Annual Report for year ended 31st March, 1973

This is the eighth Annual report of the Cumberland River Authority on information of its activities and responsibilities on river management in its area between the beginning of April 1972, to the end of March 1973. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, including periodical surveys, hydrometric schemes, acceptable flows, conservation works and a review of rainfall and river flow. The section on land drainage looks at work on improvement schemes, floods, charges and information on maintenance work carried out on rivers including Wampool, Waver, Derwent, Eden and Caldew. The fisheries section covers 5 districts of the River Eden, Esk, Ellen, Derwent and South West Cumberland. It includes angling information and a general report for salmon and sea trout, brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as fisheries protection and licence duties. The fourth section on pollution deals with water quality, and the results of samples taken for chemical analysis from rivers Eden, Eamont, Leith, Lowther, Lyne, Petteril, Caldew, Calder, Irthing, Esk, Irt, Mite, Derwent, Ehen, Ellen, Annas, Wampool and Waver are also given. It also covers information on sewage and trade effluents. The River Authorities preceded the Environment Agency which came into existence in 1996.

Ninth Annual Report for year ended 31st March, 1974

This is the ninth Annual report of the Cumberland River Authority on information of its activities and responsibilities on river management in its area between the beginning of April 1973, to the end of March 1974. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes periodical surveys, hydrometric schemes, acceptable flows, conservation works and a review of rainfall and river flow. The section on land drainage looks at work on improvement schemes, floods, charges and information on maintenance work carried out on rivers including Wampool, Waver, Glenderamackin and Lyvennet. The fisheries section covers 5 districts of the River Eden, Esk, Ellen, Derwent and South West Cumberland. It includes angling information and a general report for salmon and sea trout, brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as fisheries protection and licence duties. The fourth section on pollution deals with water quality, and the results of samples taken for chemical analysis from rivers Eden, Eamont, Leith, Lowther, Lyne, Petteril, Caldew, Calder, Marron, Irthing, Esk, Irt, Mite, Derwent, Ehen, Ellen, Annas, Wampool and Waver are also given. It also covers information on sewage and trade effluents. The River Authorities preceded the Environment Agency which came into existence in 1996.

Ninth Annual Report for the year ended 31st March, 1960

This is the ninth Annual report of the Cumberland River Board on information of its activities and responsibilities on river management in its area between the beginning of April 1959, to the end of March 1960. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes information on the completion of a gauging station on the River Eden, and an approval for a similar station on the River Derwent. It also gives information on rainfall and river flow. The section on land drainage looks at work on improvement schemes and information on maintenance work carried out on rivers including Wampool, Waver, Wiza, Ellen, Cocker, Irt, Esk, Annas, Marron, Eden, Eamont, Caldew and Petteril. The fisheries section covers 4 districts of the River Eden, Esk, Derwent and South West Cumberland. It includes angling information and a general report for salmon and sea trout, brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as re-stocking and fisheries protection. The fourth section on pollution deals with water quality and information on sewage and trade effluents. The River Boards preceded the Environment Agency which came into existence in 1996.

Tenth Annual Report for the year ended the 31st March, 1961

This is the tenth Annual report of the Cumberland River Board on information of its activities and responsibilities on river management in its area between the beginning of April 1960, to the end of March 1961. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes information on the completion of gauging stations on the River Derwent and Eamont, and the building of a similar station on the River Esk. It also gives information on rainfall and river flow. The section on land drainage looks at work on improvement schemes and information on maintenance work carried out on rivers including Wampool, Waver, Wiza, Ellen, Cocker, Irt, Annas, Mite, Ehen, Marron, Eden, Caldew and Petteril. The fisheries section covers 5 districts of the River Eden, Esk, Derwent, Ellen and South West Cumberland. It includes angling information and a general report for salmon and sea trout, brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as re-stocking and fisheries protection. The fourth section on pollution deals with water quality and information on sewage and trade effluents. The River Boards preceded the Environment Agency which came into existence in 1996.

Eleventh Annual Report for the year ended 31st March, 1962

This is the eleventh Annual report of the Cumberland River Board on information of its activities and responsibilities on river management in its area between the beginning of April 1961, to the end of March 1962. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes information on the building of gauging stations, abstraction of water, and rainfall and river flow. The section on land drainage looks at work on improvement schemes and information on maintenance work carried out on rivers including Wampool, Waver, Wiza, Ellen, Cocker, Irt, Mite, Keekle, Eden, Esk, Caldew and Petteril. The fisheries section covers 5 districts of the River Eden, Esk, Derwent, Ellen and South West Cumberland. It includes angling information and a general report for salmon and sea trout, Brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as Byelaws and fisheries protection. The fourth section on pollution deals with water quality and information on sewage and trade effluents. The River Boards preceded the Environment Agency which came into existence in 1996.

Twelfth Annual Report for the year ended the 31st March, 1963

This is the twelfth Annual report of the Cumberland River Board on information of its activities and responsibilities on river management in its area between the beginning of April 1962, to the end of March 1963. The report contains 5 main sections on water resources, land drainage, fisheries, pollution, and finally the expenditure and income for the 12 month period. The first area that the report deals with is water resources, which includes information on the completion of gauging stations, abstraction of water and rainfall. The section on land drainage looks at work on improvement schemes, floods and information on maintenance work carried out on rivers including Wampool, Waver, Wiza, Ellen, Cocker, Greta, Marron, Ehen, Keekle, Esk, Bleng, Mite, Annas, Eden, Caldew and Petteril. The fisheries section covers 5 districts of the River Eden, Esk, Derwent, Ellen and South West Cumberland. It includes angling information and a general report for salmon and sea trout, brown trout and freshwater fish. Fish disease and fish hatchery are also covered as well as Byelaws and fisheries protection. The fourth section on pollution covers water quality and information on sewage and trade effluents. The River Boards preceded the Environment Agency which came into existence in 1996.