Report of the Inter-American Tropical Tuna Commission for the year 1964

ENGLISH: The Inter-American Tropical Tuna Commission operates under the authority and direction of a Convention originally negotiated between the Republic of Costa Rica and the United States of America, which entered into force in 1950. The Convention is open to adherence by other governments whose nationals participate in the fisheries covered by the Convention. Under this provision, the Republic of Panama adhered in 1953, the Republic of Ecuador in 1961 and the United Mexican States in 1964. SPANISH: La Comisión Interamericana del Atún Tropical funciona bajo la autoridad y dirección de una Convención negociada originalmente entre la República de Costa Rica y los Estados Unidos de América, la cuál entró en vigencia en 1950. La Convención está abierta a la adhesión de los gobiernos de otros países cuyos ciudadanos participan en las pesquerías objeto de la Convención. Acogiéndose a esta cláusula, la República de Panamá se adhirió a la Convención en 1953, la República de Ecuador en 1961 y los Estados Unidos Mexicanos en 1964. (PDF contains 98 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1966

ENGLISH: The Inter-American Tropical Tuna Commission operates under the authority and direction of a Convention originally entered into by the Republic of Costa Rica and the United States of America. The Convention, which came into force in 1950, is open to adherence by other governments whose nationals participate in the fisheries covered by the Convention. Under this provision the Republic of Panama adhered in 1953, the Republic of Ecuador in 1961, and the United Mexican States in 1964. SPANISH: La Comisión Interamericana del Atún Tropical funciona bajo la autoridad y dirección de una Convención formada originalmente entre la República de Costa Rica y los Estados Unidos de América. La Convención entró en vigencia en 1950, está abierta a la adhesión de otros gobiernos cuyos ciudadanos participen en las pesquerías objeto de la Convención. Bajo esta cláusula, la República de Panamá se adhirió en 1953, la República del Ecuador en 1961 y los Estados Unidos Mexicanos en 1964. (PDF contains 138 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1967

ENGLISH: The Inter-American Tropical Tuna Commission was created and operates under the authority of a Convention first negotiated between the governments of the Republic of Costa Rica and the United States of America. The Convention entered into force in 1950. It is open to adherence by other governments whose nationals fish for tunas in the eastern Pacific area. Under this provision, Panama adhered in 1953, Ecuador in 1961, the United Mexican States in 1964. Canada applied for membership in 1967. Her membership will become effective on April 1, 1968. On August 21, 1967 the Ecuadorian government, for financial reasons, elected to withdraw from active membership. Under Convention ruling, this means that she remains a full member until August 21, 1968. SPANISH: La Comisión Interamericana del Atún Tropical fue originada y está bajo la autoridad de una Convención que fue negociada inicialmente entre los gobiernos de la República de Costa Rica y los Estados Unidos de América. La Convención entró en vigencia en 1950. Está abierta a la afiliación de otros gobiernos cuyos ciudadanos pescan atunes en el área del Pacífico oriental. Bajo esta estipulación, Panamá se afilió en 1953, Ecuador en 1961 y los Estados Unidos Mexicanos en 1964. Canadá presentó su ap1licación en 1967. Su afiliación será efectiva el 1 de abril de 1968. El 21 de agosto de 1967, el gobierno ecuatoriano por razones financieras decidió retirar su participación activa. Bajo las reglas de la Convención el Ecuador sigue actuando como miembro hasta el 21 de agosto de 1968. (PDF contains 144 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1968

ENGLISH: The Inter-American Tropical Tuna Commission operates under the authority and direction of a Convention originally entered into by the Republic of Costa Rica and the United States of America. The Convention, which came into force in 1950, is open to adherence by other governments whose nationals fish in the eastern tropical Pacific. Under this provision the Republic of Panama adhered in 1953, the Republic of Ecuador in 1961, the United Mexican States in 1964 and Canada in 1968. In 1967 Ecuador gave notice of her intent to withdraw from the Commission and her withdrawal became effective on August 21, 1968. SPANISH:La Comisión Interamericana del Atún Tropical está bajo la autoridad y dirección de una Convención la cual fue originalmente formada por la República de Costa Rica y los Estados Unidos de América. La Convención, vigente desde 1950, está abierta a la afiliación de otros gobiernos cuyos nacionales pesquen en. el Pacífico oriental tropical. Bajo esta medida la República de Panamá se afilió en 1953, la. República del Ecuador en 1961, los Estados Unidos Mexicanos en 1964 y' el Canadá en 19Ei8. En 1967, el Ecuador anunció su intención de retirarse de la Comisión y la resignación se hizo efectiva el 21 de agosto de 1968. (PDF contains 128 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1969

ENGLISH: The Inter-American Tropical Tuna Commission operates under the authority and direction of a convention originally entered into by the Republic of Costa Rica and the United States of America. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas in the eastern Pacific Ocean. Under this provision the Republic of Panama adhered in 1953, the Republic of Ecuador in 1961, the United Mexican States in 1964 and Canada in 1968. In 1967, Ecuador gave notice of her intent to withdraw from the Commission, and her withdrawal became effective on August 21, 1968. SPANISH: La Comisión Interamericana del Atún Tropical está bajo la autoridad y dirección de una convención la cual fue originalmente formada por la República de Costa Rica y los Estados Unidos de América. La Convención, vigente desde 1950, está abierta a la afiliación de otros gobiernos cuyos nacionales pesquen túnidos en el Pacifico oriental tropical. Bajo esta medida la República de Panamá se afilió en 1953, la República del Ecuador en 1961, los Estados Unidos Mexicanos en 1964, y Canadá en 1968. En 1967, el Ecuador anunció su intención de retirarse de la Comisión y la renuncia se hizo efectiva el 21 de agosto de 1968. (PDF contains 117 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1970

ENGLISH: The Inter-American Tropical Tuna Commission operates under the authority and direction of a convention originally entered into by the Republic of Costa Rica and the United States of America. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas in the eastern Pacific Ocean. Under this provision the Republic of Panama adhered in 1953, the Republic of Ecuador in 1961, the United Mexican States in 1964, Canada in 1968 and Japan in 1970. In 1967, Ecuador gave notice of her intent to withdraw from the Commission, and her withdrawal became effective on August 21, 1968. SPANISH:La Comisión Interamericana del Atún Tropical está bajo la autoridad y dirección de una convención la cual fue originalmente formada por la República de Costa Rica y los Estados Unidos de América. La Convención, vigente desde 1950, está abierta a la afiliación de otros gobiernos cuyos nacionales pesquen atún en el Pacífico oriental tropical. Bajo esta medida la República de Panamá se afilió en 1953, la República del Ecuador en 1961, los Estados Unidos Mexicanos en 1964, Canadá en 1968 y el Japón en 1970. En 1967, el Ecuador anunció su intención de retirarse de la Comisión y la renuncia se hizo efectiva el 21 de agosto de 1968. (PDF contains 128 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1971

ENGLISH: The Inter-American Tropical Tuna Commission operates under the authority and direction of a convention originally entered into by the Republic of Costa Rica and the United States of America. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas in the eastern Pacific Ocean. Under this provision the Republic of Panama adhered in 1953, the Republic of Ecuador in 1961, the United Mexican States in 1964, Canada in 1968 and Japan in 1970. In 1967, Ecuador gave notice of her intent to withdraw from the Commission, and her withdrawal became effective on August 21,1968. SPANISH: La Comisión Interamericana del Atún Tropical está bajo la autoridad y dirección de una convención la cual fue originalmente formada por la República de Costa Rica y los Estados Unidos de América. La Convención, vigente desde 1950, está abierta a la afiliación de otros gobiernos cuyos nacionales pesquen atún en el Pacífico oriental tropical. Bajo esta medida la República de Panamá se afilió en 1953, la República del Ecuador en 1961, los Estados Unidos Mexicanos en 1964, Canadá en 1968 y el Japón en 1970. En 1967, el Ecuador anunció su intención de retirarse de la Comisión y la renuncia se hizo efectiva el 21 de agosto de 1968. (PDF contains 127 pages.)

I. Spectroscopic evidence for slow vibrational relaxation in excited electronic states of diatomics in rare gas solids. II. Static crystal field effects in the electronic spectra of isotopically mixed benzene crystals

Part I

Studies of vibrational relaxation in excited electronic states of simple diatomic molecules trapped in solid rare-gas matrices at low temperatures are reported. The relaxation is investigated by monitoring the emission intensity from vibrational levels of the excited electronic state to vibrational levels of the ground electronic state. The emission was in all cases excited by bombardment of the doped rare-gas solid with X-rays.

The diatomics studied and the band systems seen are: N₂, Vegard-Kaplan and Second Positive systems; O₂, Herzberg system; OH and OD, A ²Σ⁺ - X²II_i system. The latter has been investigated only in solid Ne, where both emission and absorption spectra were recorded; observed fine structure has been partly interpreted in terms of slightly perturbed rotational motion in the solid. For N₂, OH, and OD emission occurred from v' > 0, establishing a vibrational relaxation time in the excited electronic state of the order, of longer than, the electronic radiative lifetime. The relative emission intensity and decay times for different v' progressions in the Vegard-Kaplan system are found to depend on the rare-gas host and the N₂ concentration, but are independent of temperature in the range 1.7°K to 30°K.

Part II

Static crystal field effects on the absorption, fluorescence, and phosphorescence spectra of isotopically mixed benzene crystals were investigated. Evidence is presented which demonstrate that in the crystal the ground, lowest excited singlet, and lowest triplet states of the guest deviate from hexagonal symmetry. The deviation appears largest in the lowest triplet state and may be due to an intrinsic instability of the ³B_1u state. High resolution absorption and phospho- rescence spectra are reported and analyzed in terms of site-splitting of degenerate vibrations and orientational effects. The guest phosphorescence lifetime for various benzene isotopes in C₆D₆ and sym-C₆H₃D₃ hosts is presented and discussed.

I. Electronic states of heavily-doped molecular crystals--naphthalene. I. Theoretical. II. Experimental. II. Lowest singlet and triplet excited states of pyrazine

PART I

The energy spectrum of heavily-doped molecular crystals was treated in the Green’s function formulation. The mixed crystal Green’s function was obtained by averaging over all possible impurity distributions. The resulting Green’s function, which takes the form of an infinite perturbation expansion, was further approximated by a closed form suitable for numerical calculations. The density-of-states functions and optical spectra for binary mixtures of normal naphthalene and deuterated naphthalene were calculated using the pure crystal density-of-state functions. The results showed that when the trap depth is large, two separate energy bands persist, but when the trap depth is small only a single band exists. Furthermore, in the former case it was found that the intensities of the outer Davydov bands are enhanced whereas the inner bands are weakened. Comparisons with previous theoretical calculations and experimental results are also made.

PART II

The energy states and optical spectra of heavily-doped mixed crystals are investigated. Studies are made for the following binary systems: (1) naphthalene-h₈ and d₈, (2) naphthalene--h₈ and αd₄, and (3) naphthalene--h₈ and βd₁, corresponding to strong, medium and weak perturbations. In addition to ordinary absorption spectra at 4˚K, band-to-band transitions at both 4˚K and 77˚K are also analyzed with emphasis on their relations to cooperative excitation and overall density-of-states functions for mixed crystals. It is found that the theoretical calculations presented in a previous paper agree generally with experiments except for cluster states observed in system (1) at lower guest concentrations. These features are discussed semi-quantitatively. As to the intermolecular interaction parameters, it is found that experimental results compare favorably with calculations based on experimental density-of-states functions but not with those based on octopole interactions or charge-transfer interactions. Previous experimental results of Sheka and the theoretical model of Broude and Rashba are also compared with present investigations.

PART III

The phosphorescence, fluorescence and absorption spectra of pyrazine-h₄ and d₄ have been obtained at 4˚K in a benzene matrix. For comparison, those of the isotopically mixed crystal pyrazine-h₄ in d₄ were also taken. All these spectra show extremely sharp and well-resolved lines and reveal detailed vibronic structure.

The analysis of the weak fluorescence spectrum resolves the long-disputed question of whether one or two transitions are involved in the near-ultraviolet absorption of pyrazine. The “mirror-image relationship” between absorption and emission shows that the lowest singlet state is an allowed transition, properly designated as ¹B_3u ← ¹A_1g. The forbidden component ¹B_2g, predicted by both “exciton” and MO theories to be below the allowed component, must lie higher. Its exact location still remains uncertain.

The phosphorescence spectrum when compared with the excitation phosphorescence spectra, indicates that the lowest triplet state is also symmetry allowed, showing a strong 0-0 band and a “mirror-image relationship” between absorption and emission. In accordance with previous work, the triplet state is designated as ³B_3u.

The vibronic structure of the phosphorescence spectrum is very complicated. Previous work on the analysis of this spectrum all concluded that a long progression of v_6a exists. Under the high resolution attainable in our work, the supposed v_6a progression proves to have a composite triplet structure, starting from the second member of the progression. Not only is the v_9a hydrogen-bending mode present as shown by the appearance of the C-D bending mode in the d₄ spectrum, but a band of 1207 cm^-1 in the pyrazine in benzene system and 1231 cm^-1 in the mixed crystal system is also observed. This band is assigned as 2v_6b and of a_1g symmetry. Its anonymously strong intensity in the phosphorescence spectrum is interpreted as due to the Fermi resonance with the 2v_6a and v_9a band.

To help resolve the present controversy over the crystal phosphorescence spectrum of pyrazine, detailed vibrational analyses of the emission spectra were made. The fluorescence spectrum has essentially the same vibronic structure as the phosphorescence spectrum.

Report of the Inter-American Tropical Tuna Commission for the year 1972

ENGLISH: The Inter-American Tropical Tuna Commission operates under the authority and direction of a convention originally entered into by the Republic of Costa Rica and the United States of America. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas in the eastern Pacific Ocean. Under this provision the Republic of Panama adhered in 1953, the Republic of Ecuador in 1961, the United Mexican States in 1964, Canada in 1968 and Japan in 1970. In 1967 Ecuador gave notice of her intent to withdraw from the Commission, and her withdrawal became effective on August 12, 1968. The Commission held three meetings in 1972: the 26th meeting in Tokyo, Japan, on January 6, 7 and 13; the 27th meeting in Panama, Republic of Panama, on November 7, 8 and 11; and the 28th meeting in San Diego, California, on December 20. SPANISH: La Comisión Interamericana del Atún Tropical está bajo la autoridad y dirección de una convención la cual fue originalmente formada por la República de Costa Rica y los Estados Unidos de América. La Convención, vigente desde 1950, está abierta a la afiliación de otros gobiernos cuyos nacionales pesquen atún en el Pacífico oriental tropical. Bajo esta medida la República de Panamá se afilió en 1953, la República del Ecuador en 1961, los Estados Unidos Mexicanos en 1964, Canadá en 1968 y el Japón en 1970. En 1967, el Ecuador anunció su intención de retirarse de la Comisión y la renuncia se hizo efectiva el 21 de agosto de 1968. La Comisión celebró tres reuniones en 1972: la XXVI reunion en Tokio, Japón, el 6, 7 Y 13 de enero; la XXVII reunión en Panamá, República de Panamá, el 7, 8 Y 11 de noviembre; y la XVIII reunión en San Diego, California, el 20 de diciembre. (PDF contains 166 pages.)

Report of the Inter-American Tropical Tuna Commission for the year 1973

ENGLISH: The Inter-American Tropical Tuna Commission operates under the authority and direction of a convention originally entered into by the Republic of Costa Rica and the United States of America. The convention, which came into force in 1950, is open to adherence by other governments whose nationals fish for tropical tunas in the eastern Pacific Ocean. Under this provision the Republic of Panama adhered in 1953, the Republic of Ecuador in 1961, the United Mexican States in 1964, Canada in 1968 and Japan in 1970. In 1967 Ecuador gave notice of her intent to withdraw from the Commission, and her withdrawal became effective on August 12, 1968. The Commission held its 29th meeting on November 12, 13, 14 and 16, 1973, in Washington, D. C., U. S. A. SPANISH: La Comisión Interamericana del Atún Tropical está bajo la autoridad y dirección de una convención la cual fue originalmente formada por la República de Costa Rica y los Estados Unidos de América. La Convención, vigente desde 1950, está abierta a la afiliación de otros gobiernos cuyos nacionales pesquen atún en el Pacífico oriental tropical. Bajo esta medida la República de Panamá se afilió en 1953, la República del Ecuador en 1961, los Estados Unidos Mexicanos en 1964, Canadá en 1968 y el Japón en 1970. En 1967, el Ecuador anunció su intención de retirarse de la Comisión y la renuncia se hizo efectiva el 21 de agosto de 1968. La Comisión celebró su XXIX Reunión e112, 13,14 Y16 de Noviembre 1973, en Washington, D. C., E. U. A. (PDF contains 150 pages.)