Speleothems as sensitive recorders of volcanic eruptions - the Bronze Age Minoan eruption recorded in a stalagmite from Turkey

Mounting evidence exists that variations in sulphur content in stalagmites are closely linked to changes in volcanic or anthropogenic atmospheric sulphur. The strong dependency of sulphur on soil pH and ecosystem storage, however, can result in a delay of several years to decades in the registration of volcanic eruptions and anthropogenic emissions by stalagmites. Here we present synchrotron-radiation based trace element analysis performed on a precisely-dated section of a stalagmite from Sofular Cave in Northern Turkey. As this section covers the time interval of the intensively studied Minoan volcanic eruption between 1600 and 1650 BC, we can test whether this vigorous eruption can be traced in a stalagmite. Of all measured trace elements, only bromine shows a clear short-lived peak at 1621±251621±25 BC, whereas sulphur and molybdenum show peaks later at 1617±251617±25 and 1589±251589±25 respectively. We suggest that all trace element peaks are related to the Minoan eruption, whereas the observed phasing of bromine, molybdenum and sulphur is related to differences in their retention rates in the soil above Sofular Cave. For the first time, we can show that bromine appears to be an ideal volcanic tracer in stalagmites, as it is a prominent volatile component in volcanic eruptions, can be easily leached in soils and rapidly transferred from the atmosphere through the soil and bedrock into the cave and stalagmite respectively. Highly resolved oxygen and carbon isotope profiles indicate that the Minoan eruption had no detectable climatic and environmental impact in Northern Turkey.

Climate responses to anthropogenic emissions of short-lived climate pollutants

Policies to control air quality focus on mitigating emissions of aerosols and their precursors, and other short-lived climate pollutants (SLCPs). On a local scale, these policies will have beneficial impacts on health and crop yields, by reducing particulate matter (PM) and surface ozone concentrations; however, the climate impacts of reducing emissions of SLCPs are less straightforward to predict. In this paper we consider a set of idealised, extreme mitigation strategies, in which the total anthropogenic emissions of individual SLCP emissions species are removed. This provides an upper bound on the potential climate impacts of such air quality strategies. We focus on evaluating the climate responses to changes in anthropogenic emissions of aerosol precursor species: black carbon (BC), organic carbon (OC) and sulphur dioxide (SO2). We perform climate integrations with four fully coupled atmosphere-ocean global climate models (AOGCMs), and examine the effects on global and regional climate of removing the total land-based anthropogenic emissions of each of the three aerosol precursor species. We find that the SO2 emissions reductions lead to the strongest response, with all three models showing an increase in surface temperature focussed in the northern hemisphere high latitudes, and a corresponding increase in global mean precipitation and run-off. Changes in precipitation and run-off patterns are driven mostly by a northward shift in the ITCZ, consistent with the hemispherically asymmetric warming pattern driven by the emissions changes. The BC and OC emissions reductions give a much weaker forcing signal, and there is some disagreement between models in the sign of the climate responses to these perturbations. These differences between models are due largely to natural variability in sea-ice extent, circulation patterns and cloud changes. This large natural variability component to the signal when the ocean circulation and sea-ice are free-running means that the BC and OC mitigation measures do not necessarily lead to a discernible climate response.

(65)Zn(2+) transport by isolated gill epithelial cells of the American lobster, Homarus americanus

Gills are the first site of impact by metal ions in contaminated waters. Work on whole gill cells and metal uptake has not been reported before in crustaceans. In this study, gill filaments of the American lobster, Homarus americanus, were dissociated in physiological saline and separated into several cell types on a 30, 40, 50, and 80% sucrose gradient. Cells from each sucrose solution were separately resuspended in physiological saline and incubated in (65)Zn(2+) in order to assess the nature of metal uptake by each cell type. Characteristics of zinc accumulation by each kind of cell were investigated in the presence and absence of 10 mM calcium, variable NaCl concentrations and pH values, and 100 mu M verapamil, nifedipine, and the calcium ionophore A23187. (65)Zn(2+) influxes were hyperbolic functions of zinc concentration (1-1,000 mu M) and followed Michaelis-Menten kinetics. Calcium reduced both apparent zinc binding affinity (K (m)) and maximal transport velocity (J (max)) for 30% sucrose cells, but doubled the apparent maximal transport velocity for 80% sucrose cells. Results suggest that calcium, sodium, and protons enter gill epithelial cells by an endogenous broad-specificity cation channel and trans-stimulate metal uptake by a plasma membrane carrier system. Differences in zinc transport observed between gill epithelial cell types appear related to apparent affinity differences of the transporters in each kind of cell. Low affinity cells from 30% sucrose were inhibited by calcium, while high affinity cells from 80% sucrose were stimulated. (65)Zn(2+) transport was also studied by isolated, intact, gill filament tips. These intact gill fragments generally displayed the same transport properties as did cells from 80% sucrose and provided support for metal uptake processes being an apical phenomenon. A working model for zinc transport by lobster gill cells is presented.

Meteomap: Generation Of Meteorological Variables For Distributed Physically-Based Hydrological Modeling

Distributed energy and water balance models require time-series surfaces of the meteorological variables involved in hydrological processes. Most of the hydrological GIS-based models apply simple interpolation techniques to extrapolate the point scale values registered at weather stations at a watershed scale. In mountainous areas, where the monitoring network ineffectively covers the complex terrain heterogeneity, simple geostatistical methods for spatial interpolation are not always representative enough, and algorithms that explicitly or implicitly account for the features creating strong local gradients in the meteorological variables must be applied. Originally developed as a meteorological pre-processing tool for a complete hydrological model (WiMMed), MeteoMap has become an independent software. The individual interpolation algorithms used to approximate the spatial distribution of each meteorological variable were carefully selected taking into account both, the specific variable being mapped, and the common lack of input data from Mediterranean mountainous areas. They include corrections with height for both rainfall and temperature (Herrero et al., 2007), and topographic corrections for solar radiation (Aguilar et al., 2010). MeteoMap is a GIS-based freeware upon registration. Input data include weather station records and topographic data and the output consists of tables and maps of the meteorological variables at hourly, daily, predefined rainfall event duration or annual scales. It offers its own pre and post-processing tools, including video outlook, map printing and the possibility of exporting the maps to images or ASCII ArcGIS formats. This study presents the friendly user interface of the software and shows some case studies with applications to hydrological modeling.

Caracterização do beneficiamento de carvão por jigagem no Brasil

Em função da importância do processo de jigagem no beneficiamento de carvão no Brasil, onde 95% da produção bruta, ROM, é beneficiada em jigues para a obtenção de carvão energético ou carvão pré-lavado, e da inexistência de um trabalho sistemático de caracterização deste processo, esta dissertação apresenta um estudo detalhado do desempenho de jigues no beneficiamento de carvão nacional, através do levantamento dos critérios de avaliação de performance dependentes e independentes derivados das curvas de partição e análises densimétricas dos diversos produtos. São desenvolvidos "softwares" para o processamento dos diversos dados levantados "in situ", com aplicação nas áreas de cálculo de balanços de massas e metalúrgico, processamento de análises densimétricas, cálculo de coeficientes de partição, modelamento matemático de curvas de partição e cálculo dos critérios de avaliação de performance. Conclue-se que, de um modo geral, o processo de jigagem é mal empregado no Brasil, conduzindo obtenção de produtos de baixa recuperação. Isto ocorre basicamente em função das características peculiares do carvão nacional e do fato que, no Brasil, utiliza-se jigues de fabricação estrangeira, dimensionados para outros tipos de carvões de melhor qualidade. Este trabalho pretende alertar aos profissionais da área e oferece algumas sugestões com o objetivo de melhorar a baixa eficiência do beneficiamento de carvão observada em diversos lavadores.

Os impactos dos investimentos estrangeiros diretos na evolução da balança comercial brasileira no período pós-real

The purpose of the present study is to discuss the eventual relationship between foreign direct investment in Brazil and trade balance, considering the period after the beginning of "Plano Real" on 1994, which presented a new currency regime and a new profile of Brazilian macroeconomy. It is important to state that there is a controversial debate around the question, since those investments are seen as positive to receiving countries by some authors and negative by other ones. Those who are favorable, argue that the recent attitude assumed by a lot of companies towards internalization is changing the modus operandi in some markets, providing a much more competitive framework. It is also remarkable - they also mention - the potential advantages brought by these new strategies. On the other hand, some authors defend that it increases the exposure of the country that receives such resources, since the subsidiaries of those companies operate under marketing strategies of profit maximization, considered the competitive environment they face. We will go over these opinions troughout the study, trying also to capture the reasons that usually motivate foreign companies to look for new markets and branches and also the effects on receiving country's Balance of Payments. Besides that point, the approach presented will try to answer if the increase of foreign capital stock in Brazil helps to explain some positive response from the country's trade balance, and more, on Balance of Payments. It is also important to mention that the considered period is extremely representative, mainly when considered the huge amounts involved and the increasing liberalization verified in brazilian's external policies since 1990. There is special concern, troughout the study, to define the pattern of such investments, and more, the impacts that those resources brought to public budget. The present study will focus on official data, published by Central Bank of Brazil, mainly those ones regarding Census of Foreign Capitals, as well as the referable to the evolution of Balance of Payments. Finally, based on statistical procedures, it will be provided multiple regressions on available data that will help the reader to capture the effects of some selected variables, which will bring a much more oriented analysis to the discussion.

A contribuição dos conceitos da gestão da mudança para as relações entre civis e militares no campo político orçamentário

O objetivo deste estudo é entender como se dão as relações entre civis e militares no campo político-orçamentário e identificar as possíveis contribuições dos conceitos da gestão da mudança para essas relações. Utilizando-se paradigmas diferentes em busca de um todo mais completo, é construído o referencial teórico sobre assuntos necessários a compreensão de como se dão essas relações no atual campo político-orçamentário brasileiro. A democracia e o equilíbrio entre as características que marca as relações democráticas; o orçamento como um campo em que se buscam obter interesses, de acordo com normas específicas e relações de poder entre indivíduos e grupos; as relações entre civis e militares, não como uma relação dicotômica, mas como uma imbricada relação entre redes de interesse. O discurso é entendido como a principal ferramenta de mudança social nesse campo e procura-se analisar como utilizá-lo. A gestão da mudança é discutida como prática discursiva que gera mudanças tanto no interior da organização como fora dela, sendo capaz de gerar verdade para a sociedade e conquistar e manter a legitimidade, fonte dos meios de sobrevivência da organização. Por fim, busca-se analisar a gestão da mudança, primeiro em organizações que obtiveram sucesso ao aplicá-las e, em seguida, faz-se uma análise de iniciativas da gestão da mudança aplicadas à Marinha e do seu potencial em produzir as mudanças necessárias no campo político-orçamentário. São levantadas conclusões que oferecem um roteiro de medidas para utilizar a gestão da mudança no aperfeiçoamento das relações democráticas entre civis e militares no campo político-orçamentário brasileiro.

As reformas da previdência no Brasil e o equilíbrio e atuarial dos Regimes Próprios de Previdência Social (RPPS), dos entes federados estaduais da Região Sudeste

O desequilíbrio das contas públicas, notadamente em relação à previdência do servidor público no Brasil, tem levado a buscas constantes de soluções para garantir o custeio do modelo em desenvolvimento. As mudanças estabelecidas nas Reformas da Previdência têm contribuído de forma significativa para diminuir o passivo previdenciário acumulado ao longo dos anos, principalmente nos estados, municípios das capitais e dos demais constituídos antes da promulgação da Carta Magna de 1988. Os estados escolhidos para análise demonstraram desacertos, todavia apresentam resultados promissores para o equilíbrio financeiro e atuarial dos RPPS. A utilização de modelos parecidos aos implementados na América do Sul, para o setor público e privado, apresentam-se inadequados no Brasil para os servidores públicos. Precisamos continuar aprimorando os nossos conhecimentos, buscando novas alternativas que garantam a sustentabilidade e viabilidade do sistema, sem comprometer a capacidade de investimentos dos entes federados

Análise dos critérios de distribuição da cota-parte do ICMS paulista

O texto analisa os critérios que compõem o índice de participação dos municípios paulistas na cota-parte do Imposto Sobre Circulação de Mercadorias e Serviços – ICMS, e também propõe mudanças em sua definição. Esses critérios geram distorções no valor per capita destinado a cada município, caminhando na contramão da justiça fiscal e do equilíbrio federativo. De natureza estadual, o ICMS é o tributo que mais arrecada no país e uma das mais importantes fontes de recursos dos estados e municípios. É partilhado com os municípios conforme definido pela Constituição Federal de 1988: 75% para estado e 25% para municípios. Esses 25% que compõem a cota-parte municipal são distribuídos da seguinte forma: três quartos devolvidos na proporção do valor adicionado de suas operações e um quarto, conforme lei estadual.

A voz e a palavra do movimento negro na Assembleia Nacional Constituinte (1987/1988): um estudo das demandas por direitos

O objetivo do presente trabalho fora compreender de que modo se deu a tematização do racismo e das questões raciais no momento que inaugura as possibilidades de interlocução entre sociedade civil e instituições formais do Estado Brasileiro: a Assembleia Nacional Constituinte (ANC) de 1987-1988. Por meio do estudo dos documentos que registram a participação do Movimento Negro ao longo do processo Constituinte buscou-se responder as seguintes questões: 1- Quais foram as demandas pleiteadas por organizações do Movimento Negro no contexto da Assembleia Nacional Constituinte? 2- Que tipos de argumentos são mobilizados por tais atores/atrizes para sustentar a necessidade e viabilidade da inserção dos pleitos no texto constitucional? 3- Essas demandas foram incluídas na Constituição Federal? De que maneira? Para além da pesquisa documental, realizou-se pesquisa bibliográfica sobre o contexto sociopolítico em questão bem como fez-se considerações sobre a mobilização antirracista entre as décadas de 1970 e 1980. Através do estudo da atuação do movimento social na ANC e do balanço das inclusões e exclusões de dispositivos na Carta Constitucional apontamos os desafios do tratamento da temática pelo Estado brasileiro, os avanços e a persistência de determinadas questões passadas quase três décadas do evento histórico estudado.

Conteúdo material do equilíbrio econômico financeiro de contratos de concessão

Partindo da premissa de que o estabelecimento do equilíbrio econômicofinanceiro inicial em contratos de concessão precisa se utilizar de teorias, conceitos e metodologias de outras ciências que não somente as ciências jurídicas, em especial das ciências econômicas e contábeis, a dissertação identifica as metodologias aplicáveis para a definição do conteúdo material da equação econômico-financeira inicial e as diferentes formas de quantificação dos limites e efeitos da verificação da ocorrência de riscos na alteração do equilíbrio econômico-financeiro original dos contratos de concessão.

Salt as a stress response mitigator of matrinxa, Brycon cephalus (Gunther), during transport

The present study evaluated the physiological responses of matrinxa, Brycon cephalus (Gunther), submitted to transport stress under the influence of sodium chloride, Different salt concentrations (0.0%, 0.1%, 0.3% and 0.6%) were added to four 200-L plastic tanks. Each tank was stocked with 30 fish (mean weight 1.0 +/- 0.2 kg) and transported for 4 h. Blood was sampled prior to transport and immediately after and 24 and 96 h after transport. Plasma cortisol and glucose and serum sodium and potassium, plasma chloride and ammonia were analysed, Changes in plasma cortisol were observed immediately after transportation, except in fish transported in 0.3% and 0.6% salt. Twenty-four hours later, this hormone had returned to its initial level in all fish. Blood glucose was not changed in fish treated with 0.6% salt immediately after transport, and returned to the initial level within 96 h after the other treatments. All treatments resulted in lower levels of plasma chloride after transport, except for fish treated with 0.6% salt, with fish treated with 0.0% and 0.3% salt recovering 24 h later, Serum sodium decreased immediately after transport only in the control fish, returning to the initial level 24 h later, the results indicate that treatment with 0.6% NaCl reduces most of the physiological responses of matrinxa to the stress of transport.

Transport stress in matrinxa, Brycon cephalus (Teleostei : Characidae), at different densities

Matrinxa, Brycon cephalus, is a native teleost fish from the Amazon Basin, and is of economic importance for cultivation for food and sport in Brazil. Mortality losses due to handling and transport of this stenohaline freshwater species are common. The effects of transportation at different densities on the biochemical stress responses of matrinxa (mean weight 1 kg) were examined. Fish were subjected to three different transport densities (100, 200, and 300 kg m(-3)) for four h in water with added salt (0.6%). The fish were bled at departure (baseline level), arrival (immediately after transportation) and at 24 and 96 h after arrival (recovery period). Blood glucose, cortisol, sodium, chloride, potassium and ammonia were used as stress bioindicators. No mortality was observed and no alterations in plasma cortisol were registered. However, blood glucose and ammonia levels increased and serum sodium and plasma chloride decreased on arrival for the fish transported at the highest densities. These stress responses were transient and the concentrations returned to baseline levels within 24 h. This study showed that matrinxa can be transported at densities as high as those tested in the present study, at least under the conditions employed in this study. A recovery period of at least 24 h is strongly recommended.

Efeitos da calagem do solo no crescimento inicial e absorção de macronutrientes por plantas de trapoeraba (Commelina benghalensis)

A presente pesquisa foi conduzida visando estudar os efeitos da calagem do solo sobre o crescimento inicial e absorção de macronutrientes por plantas de trapoeraba (Commelina benghalensis L.). A fase experimental foi conduzida em casa de vegetação, em vasos de cinco litros e o substrato foi coletado na camada arável de um Latossolo Vermelho Escuro, distrófico, classe textural franco-argilo-arenosa e valor original de pH igual a 3,8. O experimento foi instalado no delineamento inteiramente casualizado com quatro repetições e os tratamentos constaram da incorporação de quantidades correspondentes às doses 0, I, 2, 3, 4 e 5 t/ha de calcário dolomítico calcinado. Foi efetuada uma incubação por 15 dias antes do plantio das mudas da trapoeraba. Os resultados foram avaliados 49 dias após o transplante. A planta daninha respondeu intensamente à calagem incrementando a área foliar e os acúmulos de matéria seca e de N, P, Ca, Mg e S. Os padrões de distribuição dos diferentes macronutrientes nas diversas estruturas morfológicas da planta foram alterados. O acúmulo de K cresceu até a dose de 2 t/ha de calcário e depois decresceu, possivelmente devido ao antagonismo com Mg, adicionado através do calcário.

Equações de Predição das Exigências de Proteína Bruta para Matrizes Pesadas em Crescimento

The objective of this work was to determine the crude protein requirements for broiler breeder pullets, using the factorial method. The protein requirements for maintenance were obtained by comparative slaughter technique and also by nitrogen balance technique, as usual. In the case of comparative slaughter technique we have examined the nitrogen retained as function of different nitrogen intake levels (ad libitum, 54, 24 and 19% of the ad libitum). For the nitrogen balance technique it has been investigated the nitrogen balance as function of nitrogen intake, at different protein levels (16, 10 6 and 3% CP). The results obtained were 3.77 and 2.02 CP/kg(0.75)/day for comparative slaughter and nitrogen balance techniques, respectively. The protein requirements for weight gain were achieved by weekly following the nitrogen level in the body, during the period from 3 to 20 weeks of age. The results were 350, 406 and 463 mg of CP/g of gain in the phases of 3 to 8, 9 to 14 and 15 to 20 weeks, respectively.