Modelagem de motor de combustão internae simulação do processo de queima de combustível

The internal combustion engine is a heat engine widely used in the automotive industry. In order to better understand its behavior many models in the literature have been proposed in the last years. The 0-D thermodynamic model is a fairly simple tool but it is very useful to understand the phenomenon of combustion inside the chamber of internal combustion engines. In the first phase of this work, an extensive literature review was made in order to get information about this kind of analysis and, after this, apply them in a model able to calculate the instantaneous temperature and pressure in one zone of the combustion chamber of a diesel engine. Therefore some considerations were made with the aim of increasing the accuracy of the model in predicting the correct behavior of the engine, adding the combined effects of heat transfer, leakage and injection. In the second phase, the goal was to study the internal flow of a three-dimensional model of an internal combustion engine. In order to achieve this goal the software Solidworks was used to create the geometries of an engine and the suite of softwares Ansys was used to create the moving mesh (ICEM CFD and CFX-Pre) and to solve the CFD problem (Ansys CFX code). The model was able to perform the air flow simulation during the four-stroke cycle of an engine: admission, compression, expansion and exhaust. The results obtained from both models were suitable and they open a new range of possibilities for future researches on the field

Geração de energia elétrica a partir da concentração solar

The current world's need for clean and renewable energy sources aligned with the strong Brazilian growth looking to diversify its electric power generation sources, highly dependent on hydropower and petroleum encourages the implementation of technologies that reach this growth with diversity and cleaning. The sun energy source is considered inexhaustible and can meet the demand for energy through thermo solar plants to generate electricity. Several technologies are being studied and developed in the world and they can be used to generate electricity from the solar concentration, but in Brazil its use is still not found commercially. It is therefore essential to understand these technologies and develop knowledge about them so they can be implemented in Brazil. This work brings an overview of the thermo solar generation in Brazil, showing the different technologies and a thermodynamic simulation of one of such technologies considering a hybrid plant with complementary generation biomass, aiming at the generation of 1 MW in the Brazilian Northeast

Aplicação do ciclo rankine orgânico alimentado termicamente pela queima da casca do arroz e resíduos de madeira

With the growing world energy demand mainly from developing countries like Brazil, Russia, India and China, the search for efficient sources of energy becomes a challenge for the coming years. Among the most widely used alternative sources, biomass is the one that grows in a more pronounced way. This study will assess the real possibility of having it as a heat source in an Organic Rankine Cycle, which employ heat transfer fluids as working fluids instead of water. From a regional data collection in agricultural production and their potential rice production and the resulting husk was defined as more appropriate. The availability of husks together with an amount of eucalyptus wood, provided by a company in the region on a monthly basis, were analyzed, and the low participation of the wood was discarded by the thermal contribution of little significance. Based on this, it was established the calorific value of fuel for thermodynamic calculations and the cycle to be used. It was then carried out the choice of working fluid from the literature and their availability in the library of software used for the simulations, the Engineering Equation Solver - ESS. The fluid most appropriate for the burning of biomass, Octamethyltrisiloxane (OMTS), was not included in the software and so the R227ea and R134a were selected. After the initial parameters modeling definition, as condensing temperature, efficiency and live steam conditions, the simulations were performed, and only the R227ea remained within the feasible thermodynamic and technological ranges. With this fluid the turbine power output was 265.7 [kW] for a scenario of 24 hours/day burning, 800.3 [kW] to biomass burning for 8 hours/day and 2134 [kW] for burning only 3 hours/day. The thermal efficiency of the cycle remained in the range of 6%, and for plants operating with the most... (Complete Abstract click eletronic access below)

Uso de cascas de laranja como adsorvente de contaminantes no tratamento de água

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Incorporação de novas tecnologias no setor sucroalcooleiro: produção de hidrogênio e aumento da oferta de eletricidade

This work studies the incorporation of new technologies in the sugarcane sector. Are considered the ethanol steam reforming and the gasification of sugarcane bagasse(by-product) processes associated with combined cycle systems (Gas Turbine + Steam Turbine), aggregating hydrogen production and increased electricity supply in the sector, respectively. To verify the technical feasibility of the incorporation processes was performed a thermodynamic analysis, considering data from a typical Brazilian Sugar Cane Industry. In another step the economic viability study of the hydrogen production process was made, with consideration on hydrated and anhydrous ethanol steam reform, comparing the cost of hydrogen production. Also considered studies of economic engineering of the gasification process and the generation of electricity associated. As conclusions, it follows that the ethanol steam reforming is a great alternative for hydrogen production, presenting production cost relatively low, especially when is considered the steam reforming of hydrated ethanol. For the gasification process associated with combined cycle, can be observed an increase of 8.56 times of the electricity production in the sugar cane industry, indicating a positive annual saving when the sales price of the supply electricity is greater than 0.070 US$/kWh. Finally it can be concluded that the incorporation of these new processes allow greater profitability and operational flexibility of Brazilian sugarcane mills

Parameters optimization of heat treatment for obtaining luminescent PZT powders

Low crystalline PZT powder samples were successfully synthesized using polymeric precursor method and slow decomposition steps. The polymeric resin precursor was thermal treated in a muffle type oven varying the temperature from 250 °C to 700 °C and the time from 3 to 24 hours in order to investigate the order/disorder mechanism toward the amorphous powders. Powder samples with low crystalline phases were obtained at lower temperatures and long time of thermal treatment, demonstrating a kinetic dependence for organic removal and a thermodynamic barrier for crystallization processes. Through XRD and FTIR spectroscopy characterizations the long time thermal treated samples showed to be composed of the solid solution of metal oxides in absent of organic matter, originating broad XRD peaks profiles and no carbonaceous bands in FTIR spectra. A Photoluminescence characterization showed that the peak emission is higher for disordered and homogeneous phases, which only can be reached through the long time of thermal treatment.

Clima e vulnerabilidade socioespacial: uma avaliação dos fatores de risco na população urbana do município de São Luís (MA)

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Obtenção e estudo de polímeros supramoleculares derivados de ácidos carboxílicos-meglumina em fase aquosa

Pós-graduação em Química - IQ

Sílica gel organofuncionalizada com 4-amino-5-(4-piridil) 4H-1,2,4-triazol-3-tiol (aptt): Propriedades adsortivas e eletroanalíticas

Pós-graduação em Ciência dos Materiais - FEIS

Purificação e estudos bioquímicos de exo-poligalacturonase (pectinase) produzida pelo fungo termofílico Rhizomucor pusillus, em cultivo submerso e aplicação na extração de sucos de frutas e hidrólise enzimática do bagaço de cana-de-açúcar

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Parâmetros termodinâmicos da casca de laranja desidratada

The global energy scenario is currently a widely discussed topic, with growing concern about the future supplies. Thus, much attention has been dedicated to the utilization of biomass as an energy resource. In this respect, orange peel has become a material of great interest, especially to Brazil, which generates around 9.5 million tons of this waste per year. To this end, the authors studied the kinetics of the thermal processing of dried orange peel in inert and oxidizing atmosphere. The thermodynamic parameters were determined by the Ozawa-Flynn-Wall method for the global process observed during heating from the 25 degrees C up to 800 degrees C. The thermal analysis in air and nitrogen showed 3-2 stages of mass loss, respectively, with approximately 20% residual mass under a nitrogen atmosphere. The increase in the values of activation energy for the conversion points between 20% and 60% for thermal effects in air and nitrogen atmosphere was observed. The activation energy obtained in an oxidizing atmosphere was higher than that obtained under a nitrogen atmosphere. The fourier-transform infrared spectroscopy and X-ray diffraction analysis showed that the material has a high level of complexity with the presence of alkali and alkaline earth groups as well as phosphate, plus substances such as pectin, cellulose and lignin.

Structure of importin-a from a filamentous fungus in complex with a classical nuclear localization signal

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

New insights into the structural characteristics of irradiated crotamine

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Superconducting properties of a parallelepiped mesoscopic superconductor: a comparative study between the 2D and 3D Ginzburg-Landau models

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Study on determination and removal of metallic ions from aqueous and alcoholic solutions using a new POSS adsorbent

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)