Quantificação de Fases Cristalinas de Incrustações em Colunas de Produção de Petróleo pelo Método Rietveld

The scale is defined as chemical compounds from inorganic nature, initially soluble in salt solutions, which may precipitate accumulate in columns of production and surface equipment. This work aimd to quantify the crystalline phases of scale through the Rietveld method. The study was conducted in scale derived from columns production wells in development and recipients of pigs. After collecting samples of scale were performed the procedure for separations of inorganic and organic phase and preparation to be analyzed at the X-ray Laboratory. The XRD and XRF techniques were used to monitor whether identifying and quantifying crystalline phases present in the deposits. The SEM technique was used to visualize the morphology of the scales and assess their homogeneity after the milling process. XRD measurements were performed with and without milling and with or without the accessory spinner. For quantify crystalline phases the program DBWStools was used. The procedure for conducting the first refinement was instrumental in setting parameters, then the structural parameters of the phases in the sample and finally the parameters of the function profile used. In the diffraction patterns of samples of scale observed that the best measures were those that passed through the mill and used the accessory spinner. Through the results, it was noted that the quantitative analysis for samples of scale is feasible when need to monitor a particular crystalline phase in a well, pipeline or oil field. Routinely, the quantification of phases by the Rietveld method is hardwork because in many scale was very difficult to identify the crystalline phases present

Lixiviação de sulfentrazone e amicarbazone em colunas de solo com adição de óleo mineral

O presente trabalho teve por objetivo avaliar a lixiviação dos herbicidas sulfentrazone e amicarbazone, com e sem óleo mineral, em área de plantio de cana-de-açúcar sobre um Latossolo Vermelho-Escuro, por meio de colunas de solo. Para avaliação da lixiviação, após acumuladas as precipitações de 35, 67 e 106 mm, tubos de PVC de 10 cm de diâmetro, seccionados longitudinalmente, foram enterrados até a profundidade de 35 cm, procurando-se manter a estrutura original do solo. Os tubos foram retirados, separados em suas metades e acondicionados em casa de vegetação, onde se semearam as plantas-teste sorgo (Sorghum bicolor) e corda-de-viola (Ipomoea nil) longitudinalmente ao longo do perfil de cada metade dos tubos. O delineamento experimental utilizado foi o de blocos ao acaso em esquema de parcelas subdivididas, com quatro repetições. As parcelas consistiram da aplicação dos dois herbicidas, adicionados ou não de adjuvante, e uma testemunha sem herbicida. Nas subparcelas estudaram-se as profundidades de percolação (0,0-2,5; 2,5-5,0; 5,0-10; 10-15; 15-20; 20-25; 25-30; e 30-35 cm). Aos 20 dias após a semeadura, determinou-se a matéria seca das plântulas. Observou-se que o sulfentrazone lixiviou até 10 cm de profundidade, mesmo com 106 mm de precipitação, sem efeito diferenciado do óleo. Os efeitos foram mais pronunciados para o sorgo. O amicarbazone não interferiu na matéria seca das plântulas de sorgo. Quanto à corda-de-viola, o herbicida sob precipitação de 35 mm reduziu o desenvolvimento das plântulas, independentemente da profundidade e sem efeito diferenciado do óleo; com 67 mm de precipitação, o herbicida lixiviou pelo solo, e o óleo mineral o manteve na camada mais superficial. Com 106 mm, o herbicida foi totalmente lixiviado e não se constatou efeito do óleo.

Medo e violência na cidade: imagens, discursos e sociabilidade nas praças de João Pessoa - PB

The present work analyses and discusses the sociability in the culture of contemporary cities focusing on the theme of fear and violence in the daily life of squares in the city of João Pessoa-PB. We analyse the relations between places in town and make correlations of history and setting of neighborhoods with the process of urban growth, including recent interventions of public authorities in their public spaces. We observed in this dynamics social attitudes and actions that range from a desired peaceful coexistence to social exclusion. Thus, we discuss, based upon the imaginary vision, that the squares exist as a locus of equality, citizenship and political, and, also, as a space for everyone, despite the existence of symbolic forces working towards segregation and privatization, ruled in fear and violence. We aimed to investigate the different symbolic logics from the issue of fear and violence that allows the exclusion and the inclusion of groups and individuals in the quotidian use of public spaces of contemporary cities. We believe that the social action is demarcated by violence ant its corollary, the social fear, and operates based on the logic of a relational game always confrontational but experienced in different forms according to the social segment or group under study. We used a qualitative and quantitative methodology relating data and statistical analysis with categories created for the understanding of subjective factors. Our analyses combined ethnographic elements, periodics research and images of the city and its spaces, with the contribution of a survey that allowed comparisions of five squares of neighborhood based on the daily life under investigation. Our proposal was to deepen the investigations related to the public space of contemporary cities, expanding the look on João Pessoa and its cultural dynamics with an analysis of discourses, images, the collective imaginary and the social appropriation of the spaces based on fear and violence. The research accomplished in different areas and the analysis of images and speeches published in newspapers reports, books, advertising etc. allowed the approach of differentiated patterns of sociability in the same urban process. The neighborhoods in study are indeed spatially and economically distanced and the process of creation and construction of squares occurred in very different ways in the respective location. We defend the thesis that neighborhood community squares provide reinvigorated spaces and public spheres in the urban process and in the dynamics of sociability in the cities. These squares are also social spaces par excellence for the perception of the logic of individualism and segregation so marked by fear and violence in contemporary cities

Análise e otimização de superfícies seletivas de Frequência utilizando redes neurais artificiais e algoritmos de otimização natural

The bidimensional periodic structures called frequency selective surfaces have been well investigated because of their filtering properties. Similar to the filters that work at the traditional radiofrequency band, such structures can behave as band-stop or pass-band filters, depending on the elements of the array (patch or aperture, respectively) and can be used for a variety of applications, such as: radomes, dichroic reflectors, waveguide filters, artificial magnetic conductors, microwave absorbers etc. To provide high-performance filtering properties at microwave bands, electromagnetic engineers have investigated various types of periodic structures: reconfigurable frequency selective screens, multilayered selective filters, as well as periodic arrays printed on anisotropic dielectric substrates and composed by fractal elements. In general, there is no closed form solution directly from a given desired frequency response to a corresponding device; thus, the analysis of its scattering characteristics requires the application of rigorous full-wave techniques. Besides that, due to the computational complexity of using a full-wave simulator to evaluate the frequency selective surface scattering variables, many electromagnetic engineers still use trial-and-error process until to achieve a given design criterion. As this procedure is very laborious and human dependent, optimization techniques are required to design practical periodic structures with desired filter specifications. Some authors have been employed neural networks and natural optimization algorithms, such as the genetic algorithms and the particle swarm optimization for the frequency selective surface design and optimization. This work has as objective the accomplishment of a rigorous study about the electromagnetic behavior of the periodic structures, enabling the design of efficient devices applied to microwave band. For this, artificial neural networks are used together with natural optimization techniques, allowing the accurate and efficient investigation of various types of frequency selective surfaces, in a simple and fast manner, becoming a powerful tool for the design and optimization of such structures

Arranjos Log-Periódicos Compactos em Microfita com Elementos Fractais de Koch

This work aims to present how the application of fractal geometry to the elements of a log-periodic array can become a good alternative when one wants to reduce the size of the array. Two types of log-periodic arrays were proposed: one with fed by microstrip line and other fed by electromagnetic coupling. To the elements of these arrays were applied fractal Koch contours, at two levels. In order to validate the results obtained some prototypes were built, which were measured on a vector network analyzer and simulated in a software, for comparison. The results presented reductions of 60% in the total area of the arrays, for both types. By analyzing the graphs of return loss, it was observed that the application of fractal contours made different resonant frequencies appear in the arrays. Furthermore, a good agreement was observed between simulated and measured results. The array with feeding by electromagnetic coupling presented, after application of fractal contours, radiation pattern with more smooth forms than the array with feeding by microstrip line

Descontinuidade na seção transversal em laminados compósitos poliméricos: efeitos e propriedades

The growing demand in the use of composite materials necessitates a better understanding its behavior to many conditions of loading and service, as well as under several ways of connections involved in mechanisms of structural projects. It is know that most of the structural elements are designed with presence of geometric discontinuities (holes, notches, etc) in their longitudinal sections and / or transversals, and that these discontinuities affect the mechanical response of these elements. This work has aims to analyze a study of the mechanical response, when in the presence geometric discontinuity, of polymer matrix composite laminates (orthophthalic polyester) to the uniaxial tensile test. The geometric discontinuity is characterized by the presence of a center hole in the transversal section of the composite. In this study, different kinds of stacking sequences are tested, with and without the presence of the hole, so as to provide better understanding of the mechanical properties. This sense, two laminates were studied: the first is only reinforced by with seven layers short mats of fiberglass-E (CM) and the second where the reinforcement of fiberglass-E comes in the form of bidirectional fabric (CT), with only four layers. The laminate CT has the presence of anisotropy (sense of continuous fibers with respect to the applied load) as the main parameter influencing its mechanical behavior, behavior this, not observed for the CM. In addition to the mechanical properties was also studied the fracture characteristics developed in each composite laminated. The results also showed that the presence of the hole in the transversal section decreased the ultimate strength of laminates and changed the final characteristic of fracture in all kinds of composite laminated studied

Estudo da presença de entalhes semicirculares em compósitos poliméricos híbridos

Composite materials have a wide application in various sectors, such as the medical field in the manufacture of prostheses, in automotive and aerospace. Thus it is essential to the development of new composite and a better understanding in the face of various loading conditions and service. Several structural elements are manufactured in the presence of geometric discontinuity (notch, hole, etc ) in their longitudinal sections and/or cross-cutting, and these affect the mechanical response of these elements. The objective is to study the mechanical response of laminated polymer matrix hybrid composites reinforced with glass fiber/jute in a uniaxial tensile test. The mechanical response takes in account both the influence of the presence of a geometric discontinuity (semicircular notches) and the orientation of fibers in the layers (anisotropy). The semicircular notches are located in longitudinal section (with a reduction in cross section) of the same. In this analysis, the anisotropy is characterized by types of configurations (with different orientations of fibers in the outer layers). A comparative study of mechanical properties with and without the presence of notches is developed. Both configurations consist of four layers of woven jute fiber bidirectional and a central layer of bidirectional woven glass fibers. In addition to the mechanical properties was also studied the characteristics of the fracture developed in each composite laminate. The results showed that in the comparative study, the anisotropy and the presence of semicircular notches directly influences the mechanical behavior of laminates composites, mainly in reducing the tensile strength, and well as the final characteristics of the fracture

Publicação e avaliação de periódicos científicos: paradoxos da classificação Qualis em Psicologia

Recently, Brazilian scientific production has increased greatly, due to demands for productivity from scientific agencies. However, this high increases requires a more qualified production, since it s essential that publications are relevant and original. In the psychological field, the assessment scientific journals of the CAPES/ANPEPP Commission had a strong effect on the scientific community and raised questions about the chosen evaluation method. Considering this impact, the aim of this research is a meta-analysis on the assessment of Psychological journals by CAPES to update the Qualis database. For this research, Psychology scientific editors (38 questionnaires were applied by e-mail) were consulted, also 5 librarians who work with scientific journals assessment (semi-structured interviews) and 8 members who acted as referees in the CAPES/ANPEPP Commission (open questions were sent by e-mail). The results are shown through 3 analysis: general evaluation of the Qualis process (including the Assessment Committee constitution), evaluation criteria used in the process and the effect of the evaluation on the scientific community (changes on the editing scene included). Some important points emerged: disagreement among different actors about the suitability of this evaluation model; the recognition of the improvement of scientific journals, mainly toward normalization and diffusion; the verification that the model does not point the quality of the journal, i.e., the content of the scientific articles published in the journal; the disagreement with the criteria used, seemed necessary and useful but needed to be discussed and cleared between the scientific community. Despite these points, the scientific journals evaluation still is the main method to assure quality for Psychology publications

Compromisso social do psicólogo em artigos publicados em periódicos científicos no Brasil

Psychologist s social commitment in scientific articles published in scientific papers in Brazil. A situation analysis of the scientific production concerning psychologist s social commitment can aid the historical constitution of this theme and also subsidize reflections about the course of this profession in Brazil. In order to contribute to this debate, the theme social commitment of psychologist was analyzed in the scientific literature concerning psychologist profession in the country. Specifically, papers about the profession that mentioned the theme social commitment were characterized and their approach of this matter was analyzed. In order to accomplish these goals, two research stages were fulfilled: first, in a systematic search for scientific literature in internet databases, studies about the psychologist profession in the country were gathered; in the second stage, scientific papers relating to social commitment in their titles, abstracts or keywords were selected. 61 papers were retrieved, organized in electronic database and full-text analyzed, based in two axis: scientometric and thematic. The papers were identified, in general, as recent, of theoretic character and aligned with several Psychology subareas; mainly produced in public universities, in country s southwest; were of conjunctural interest to the authors research projects, individually published, by professors in touch with post-graduation; published in open access journals, with high Qualis evaluation. It was verified that there is no consensus on the meaning of the theme, prevailing definitions concerning the understanding of the social reality, to the majority of people or to a progressive-aligned professional performance. Are adduced as committed agents: the psychologist (sometimes together with other kinds of professionals or with users), the academia, and the representative entities of the profession. Depending on the subareas and the nature of study, all papers mentioned at least one of the following criteria: expansion of target-audience, renewal of practices, political direction, defined theoretical approach or adequate technical competence, sometimes relating each other. In short, psychologist s social commitment is a contradictory issue which have earned projection in scientific literature, reiterating the historical custom of evaluate the psychologist profession. As conclusion, it is regarded as indispensable to intensify the reflection about the role whose psychologist plays in a class-cleaved society and the limits and potentials of his performing in that framework.

Violência sexual intrafamiliar contra crianças e adolescentes: o estado da arte em periódicos em psicologia

Intrafamily sexual violence against children and adolescents is a highly complex and serious issue in terms of the damage caused to this population. However, despite the relevance of this discussion, the matter only began to be addressed in the second half of the twentieth century, with its inclusion in academic research from the perspective of damage caused to the victims. Debate on intrafamily sexual violence against children and adolescents has intensified in recent decades, particularly with the enactment of the Statute on Children and Adolescents (Federal Law 8069/90), which recognizes children and adolescents as rights holders. Open discussion on the issue meant several fields of knowledge began to study the topic. Particularly prominent among these areas is the field of Psychology, promoting theoretical discussions and practical interventions focusing on this type of violence. Given the theoretical and methodological diversity of psychological science and the many possibilities for the production of knowledge, this study aims to map and debate research conducted in the field that discusses intrafamily sexual violence against children and adolescents in Brazil. To that end, articles published in Psychology journals were analyzed. In order to achieve this objective, a search was conducted of Scielo Brasil using descriptors on the subject, chosen from a list reported by Faleiros (2000). The time frame studied was between 1990 and 2013, therefore included the date of the enactment of the Statute of Children and Adolescents. Qualitative analysis was selected as a data analysis technique around two main themes. The first involved analyzing the concept of intrafamily sexual violence based on its components. The second analytical theme addressed the theoretical and methodological strategies used by the authors. The aim was to identify and discuss the approaches chosen to achieve the proposed objectives as well as the justifications provided by the authors for their research. Analyses of these themes were based on theoretical discussions on intrafamily sexual violence against children and adolescents. Difficulties were identified in conceptualizing intrafamily sexual violence so as to include all its elements and differentiate it from sexual exploitation. The studies assessed showed substantial diversity in both the theoretical and methodological approaches used, contributing to understanding the phenomenon. It is expected that this study will contribute to reflection on intrafamily sexual violence against children and adolescents, promoting new studies and/or practical interventions

Indexação automatizada de artigos de periódicos científicos: análise da aplicação do software SISA com uso da terminologia DeCS na área de Odontologia

The indexing automation has been discussed by researches in the area of Information Science however the discussions have not been so clear on the use of indexing software. Thus, it is necessary to know the indexing software, as well as its application in the analysis of documentary contents. To do so, it is proposed, here, to investigate both the consistency of indexing and the exhaustiveness and precision of the information retrieval, by means of comparative analysis between SISA (Sistema de Indizacion Semi-Automatico) automatic index and BIREME ( Centro Latino-Americano e do Caribe de Informação em Ciencias da Saude) manual indexing. The aim of this paper is to contribute to the theoretical development of the indexing automation and the improvement of SISA. Thus, SISA application and evaluation was used based on the calculation of the consistency indexes between the two types of indexing, and the calculation of the exhaustiveness and precision indexes in information retrieval, by means of searching into BDSISA and BIREME databases, composed by descriptors taken from SISA and manual indexing respectively. The differences among the terms used in scientific papers comparing to the DeCS ones were the main difficult factor to achieve higher consistency indexes in the indexing. These differences influenced the exhaustiveness and precision indexes in the information retrieval, showing that it is necessary to improve the documentary language used by SISA software and to incorporate linguistic methods.

Periódicos de bioética. ¿Hay muchos? ¿Hay pocos? ¿Cuál es la situación?

This work presents a bibliometric profile of Bioethics Journal according to the following journal databases: MEDLINE, LILACS, The Philosopher' s Index, Ulrich's, SciELO and Qualis classification system (Brazil). We found that: from 38 titles indexed in MEDLINE, 25 (66%) still exist; the country with the highest number is the U. S. A (36%); most Bioethics journals appeared in the 1990's (47%), and 36% have less than 10 years of existence. From those that disappeared (34%), the average survival time was about 4 years. There are only 12 countries with indexed journals. In Brazil, from 3 Bioethics journals, only one is (partially) indexed. English is the preponderant language (45%). Only 3% of journals are monthly. LILACS has two additional publications (Acta Bioethica, Chile, and Revista Latino Americana, Colombia). SciELO has only Acta Bioethica. In Ulrich's database, there are eight additional publications. In "Qualis" classification system there are four journals.

Iinterpretação conjunta de dados de GPR e medidas de permeabilidade sobre um análogo de reservatório siliciclástico falhado na bacia de Tucano, no NE do Brasil

It is presented an integrated geophysical investigation of the spatial distribution of faults and deformation bands (DB´s) in a faulted siliciclastic reservoir analogue, located in Tucano Basin, Bahia State, northeastern Brazil. Ground Penetrating Radar (GPR) and permeability measurements allowed the analysis of the influence of DB´s in the rock permeability and porosity. GPR data were processed using a suitable flow parametrization in order to highlight discontinuities in sedimentary layers. The obtained images allowed the subsurface detection of DB´s presenting displacements greater that 10 cm. A good correlation was verified between DB´s detected by GPR and those observed in surface, the latter identified using conventional structural methods. After some adaptations in the minipermeameter in order to increase measurement precision, two approaches to measure permeabilities were tested: in situ and in collected cores. The former approach provided better results than the latter and consisted of scratching the outcrop surface, followed by direct measurements on outcrop rocks. The measured permeability profiles allowed to characterize the spatial transition from DB´s to undeformed rock; variation of up to three orders of magnitude were detected. The permeability profiles also presented quasi-periodic patterns, associated with textural and granulometric changes, possibly associated to depositional cycles. Integrated interpretation of the geological, geophysical and core data, provided the subsurface identification of an increase in the DB´s number associated with a sedimentary layer presenting granulometric decrease at depths greater than 8 m. An associated sharp decrease in permeability was also measured in cores from boreholes. The obtained results reveal that radagrams, besides providing high resolution images, allowing the detection of small structures (> 10 cm), also presented a correlation with the permeability data. In this way, GPR data may be used to build upscaling laws, bridging the gap between outcrop and seismic data sets, which may result in better models for faulted reservoirs

Caracterização macro, meso e microscópica das estruturas frágeis do corpo arenítico conglomerático da região de Santana do Acaraú (CE) e seu embasamento circundante

The structural framework of the sedimentary basins usually plays an important role in oil prospects and reservoirs. Geometry, interconectivity and density of the brittle features developed during basin evolution could change the permo-porous character of the rocks involved in generation, migration and entrapment of fluid flow. Once the structural characterization of the reservois using only sub-surface data is not an easy task, many studies are focused in analogous outcrops trying to understand the main processes by which brittle tectonic is archieved. In the Santana do Acaraú region (Ceará state, NE Brazil) a pack of conglomeratic sandstone (here named CAC) has its geometry controlled mainly by NE trending faults, interpreted as related to reactivation of a precambrian Sobral Pedro II Lineament (LSP-II). Geological mapping of the CAC showed a major NE-SW trending synform developed before its complete lithification during a dextral transpression. This region was then selected to be studied in details in order of constrain the cretaceous deformation and so help the understanding the deformation of the basins along the brazilian equatorial margin. In order to characterize the brittle deformation in different scales, I study some attributes of the fractures and faults such as orientation, density, kinematic, opening, etc., through scanlines in satellite images, outcrops and thin sections. The study of the satellite images showed three main directions of the macrostructures, N-S, NE-SW and E-W. Two of theses features (N-S and E-W) are in aggreement with previous geophysical data. A bimodal pattern of the lineaments in the CAC´s basement rocks has been evidenciated by the NE and NW sets of structures obtained in the meso and microscale data. Besides the main dextral transpression two others later events, developed when the sediments were complety lithified, were recognized in the area. The interplay among theses events is responsible for the compartimentation of the CAC in several blocks along within some structural elements display diferents orientations. Based on the variation in the S0 orientation, the CAC can be subdivided in several domains. Dispite of the variations in orientations of the fractures/faults in the diferents domains, theses features, in the meso and microscopic scale, are concentrated in two sets (based on their trend) in all domains which show similar orientation of the S0 surface. Thus the S0 orientation was used to group the domains in three major sets: i) The first one is that where S0 is E-W oriented: the fractures are oriented mainly NE with the development of a secondary NW trending; ii) S0 trending NE: the fractures are concentrated mainly along the trend NW with a secondary concentration along the NE trend; iii) The third set, where S0 is NS the main fractures are NE and the secondary concentration is NW. Another analized parameter was the fault/fracture length. This attribute was studied in diferent scales trying to detect the upscale relationship. A terrain digital model (TDM) was built with the brittlel elements supperposed. This model enhanced a 3D visualization of the area as well as the spatial distribution of the fault/fractures. Finally, I believe that a better undertanding of the brittle tectonic affecting both CAC and its nearby basement will help the future interpretations of the tectonic envolved in the development of the sedimentary basins of the brazilian equatorial margin and their oil reservoirs and prospects, as for instance the Xaréu field in the Ceará basin, which subsurface data could be correlated with the surface ones