(Table 1) Grain size parameters of intertidal channel sand bars near Sylt, North-Frisian Wadden Sea

The aim of the present study is to investigate directional asymmetric properties and internal structures of the bedforms on the intertidal sand bars in comparison with the migration problems of the sand bodies developed in the channel systems of the tidal basin off the west coast of Schleswig-Holstein. The tidal channel sand bodies studied have 'V'-shaped outlines and are asymmetric in cross-section. Based on such knowledge it was hoped to understand and find possible factors for application to recent and ancient tidal depositional environments. The V-shaped intertidal channel sand bodies developed in the tidal environments between Sylt and Föhr Island are constantly migrating sand bars. The migration directions are in good agreement with the resultant vector mean directions of internal cross-stratification structures of asymmetric sedimentary bedforms. Finally, it is shown that the orientation of the apex of V-shaped sand bar as an equilibrium form alone can not indicate the migration direction, but that the orientation of the resultant vector mean of internal structures of sedimentary bedforms does indicate the migration direction. Based on the analyses of textural parameters of the migrating intertidal bar sands, it seems that sands of typical intertidal sand bars are negatively skewed and well sorted. The high rounding of quarz sand grains of these tidal channel sand bars seems to be an additional characteristical criterion for tidal depositional environments, as also indicated by Balazs and Klein (1972).

Processed CO2/O2 Float data from 4 deployments near Cape Verde Island (11/2010 - 06/2011)

In recent years, profiling floats, which form the basis of the successful international Argo observatory, are also being considered as platforms for marine biogeochemical research. This study showcases the utility of floats as a novel tool for combined gas measurements of CO2 partial pressure (pCO2) and O2. These float prototypes were equipped with a small-sized and submersible pCO2 sensor and an optode O2 sensor for highresolution measurements in the surface ocean layer. Four consecutive deployments were carried out during November 2010 and June 2011 near the Cape Verde Ocean Observatory (CVOO) in the eastern tropical North Atlantic. The profiling float performed upcasts every 31 h while measuring pCO2, O2, salinity, temperature, and hydrostatic pressure in the upper 200 m of the water column. To maintain accuracy, regular pCO2 sensor zeroings at depth and surface, as well as optode measurements in air, were performed for each profile. Through the application of data processing procedures (e.g., time-lag correction), accuracies of floatborne pCO2 measurements were greatly improved (10-15 µatm for the water column and 5 µatm for surface measurements). O2 measurements yielded an accuracy of 2 µmol/kg. First results of this pilot study show the possibility of using profiling floats as a platform for detailed and unattended observations of the marine carbon and oxygen cycle dynamics.

Abundance and biomass of phytoplankton in the Black Sea near Gelendzhik in 2002-2005

It is shown that in 2002-2005 mass development of coccolithofore Emiliania huxleyi on the Gelendzhik shelf (northeast Black Sea) occurred annually and in May-June its abundance reached 1500000 cells/l. In 2004-2005 bloom of E. huxleyi was accompanied by mass development of diatom alga Chaetoceros subtilis var. abnormis f. simplex (600000-900000 cells/l). For the first time it was registered as a dominating form of Black Sea phytoplankton. Small flagellates and picoplankton algae played a noticeable role in phytoplankton throughout the entire period of the studies. Meanwhile in the early summer period the bulk of biomass consisted of coccolithophores (50-60%), while in the late summer period diatomaceous algae dominated (50-70%). Among ecological factors that favor coccolithophore development one may note microstratification of the upper mixed layer at a high illumination level and high temperature in surface waters (18-21°C). Terrigenous runoff during the rainy period had a negative effect on E. huxleyi development, while storms dispersed the population over the upper mixed layer. A wind-induced near-shore upwelling stimulated development of diatoms.

Chemical and mineral compositions of bottom sediments and ferromanganese crusts and nodules near Iceland

Results of study of bottom sediments near Iceland and on the Jan Mayen Island are reported. It was found that in recent sediments chemical elements are mainly associated with pyro- and volcanoclastics. In some areas adjusted to deep-seated faults ancient iron-manganese crusts and sediments occur. They are rich in Ni, Co, V, Cu, Mo, Cd and other elements associated with endogenic matter.

Composition and age of ores and bottom sediments accumulated within and near the Rainbow hydrothermal field

Results of direct geological and geochemical observations of the modern Rainbow hydrothermal field (Mid-Atlantic Ridge, 36°14'N; 33°54'W) carried out from the deep-sea manned Mir submersibles during Cruises 41 and 42 of the R/V Akademik Mstislav Keldysh in 1998-1999 and data of laboratory studies of collected samples are under consideration in the paper. The field lacks neovolcanic rocks and the axial part of the rift is filled in with a serpentinite protrusion. In this field there occur metalliferous sediments, as well as active and relict sulfide edifices composed of sulfide minerals; pyrrhotite, chalcopyrite, isocubanite, sphalerite, marcasite, pyrite, bornite, chalcosine, digenite, magnetite, anhydrite, rare troilite, wurtzite, millerite, and pentlandite have been determined. Sulfide ores are characterized by concentric-zoned textures. During in situ measurements during 35 minutes temperature of hydrothermal fluids was varying within a range from 250 to 350°C. Calculated chemical and isotopic composition of hydrothermal fluid shows elevated concentrations of Cl, Ni, Co, CH4, and H2. Values of d34S of H2S range from +2.4 to +3.1 per mil, of d13C of CH4 from -15.2 to -11.2 per mil, and d13C of CO2 from +1.0 to -4.0 per mil. Fluid inclusions are homogenized at temperatures from 140 to 360°C, whereas salinity of the fluid varies from 4.2 to 8.5 wt %. d34S values of sulfides range from +1.3 to +12.5 per mil. 3He/4He ratio in mineral-forming fluid contained in the fluid inclusions from sulfides of the Rainbow field varies from 0.00000374 to 0.0000101. It is shown that hydrothermal activity in the area continues approximately during 100 ka. It is assumed that the fluid and sulfide edifices contain components from the upper mantle. A hypothesis of phase separation of a supercritical fluid that results in formation of brines is proposed. Hydrothermal activity is related to the tectonic, not volcanic, phase of the Mid-Atlantic Ridge evolution.