Compositions of paleosols from the Salarevo Formation, Sukhona River valley (Severnaya Dvina basin)

Paleosols crop out in the Sukhona River valley as several members up to 10 m thick embedded into the Salarevo Formation sediments. Principal characteristics of the paleosols include a dense network of root channels, indications of eluvial gley alteration, redistribution and formation of secondary carbonates represented by several generations, and formation of block-prismatic soil structure with specific clayey films at structural jointing faces. The paleosols are divided into a number of genetically interrelated horizons (from top to bottom): presumably organogenic accumulation (AElg), eluvial gley horizon (Elg), illuvial horizons (B1 and B2), illuvial gley horizon (Bg), and transitional horizons (ElBg and BElg). The paleosols formed under conditions of a semiarid climate with sharp seasonal or secular and multisecular oscillations of atmospheric precipitation. Such soils point to specific ecological environments existed in the northern semiarid belt of the Earth before the greatest (in Phanerozoic) biospheric crisis at the Permian-Triassic boundary.

Sulfur compounds in bottom sediments and interstitial waters of the Pacific Ocean to the east of Japan

In near-shore Pacific bottom sediments to the east of Japan unusually high content of free H2S ocurs. H2S resulting from bacterial reduction of sulfates from interstitial waters has a number of derivatives; pyrite dominates among them. Contents of other derivatives of H2S: sulfide sulfur and organic sulfur do not exceed 0,01%, content of organic sulfur does not exceed 0.1%. Due to reduction content of sulfates can reduce to 0,03% S. Capacity of the process of sulfate reduction, estimated by sum of all reduced forms of S - derivatives of H2S, is a function of organic matter content in sediments. Ability of bottom sediments to accumulate free H2S depends on content of reactive forms of Fe. Spatial distribution of reduced forms of S in the studied sediments is considered.

Chemical composition of sepiolites and palygorskites from bottom sediments of the Eastern Indian

In fault zones of the East Indian Ridge and adjacent areas of ocean floor almost monomineral sepiolite- and palygorskite clays have been found. They have been studied by a complex of optical and physical methods. Formation of authigenic sepiolites and palygorskite had occurred under influence of Mg- and Si-rich hydrothermal solutions by metasomatic replacement of montmorillonite clays, or by precipitation from saturated solutions in cracks of various rocks.

Properties, sedimentation and accumulation rates, and chemical composition of bottom sediments from the Deryugin Basin, Sea of Okhotsk

Results of a study of contents and accumulation rates of Fe, Mn, and some trace elements in Upper Quaternary sediments of the Deryugin Basin are presented. Maps of average contents and accumulation rates of excessive Fe, Mn, Zn, Ba, Ni, Pb, Cu, and Mo in sediments of the first oxygen isotope stage (OIS) have been plotted. Anomalous contents and accumulation rates are confined to peripheral zones of the Deryugin sedimentary basin and large fracture zones. Different mechanisms of influence of fluid-dynamic processes on rate of hydrogenic and biogenic accumulation of ore elements are assumed.

Chemical composition in phosphate materials from the ocean floor

Content, distribution patterns, and speciation of Cl in phosphorites and bone phosphate from the ocean floor, as well as in a set of samples from the land are studied. Total Cl content varies from 0.05 to 4.25% in phosphorites and from 2.48 to 2.75% in recent phosphate-bearing sediments. Recent phosphorites are enriched in Cl relative to ancient ones. Bound Cl content (not extractable by washing), which increases with lithification, varies from 0.17 to 0.60% in ocean and land phosphorites and from 0.02% to 1.30% in bone phosphate. Na content in most samples is higher relative to Na of NaCl due to its incorporation into the crystal lattice of apatite. However, the opposite relationship is observed in some samples indicating partial Cl incorporation into the anion complex of phosphate. Behavior of Cl in phosphorites from the present-day ocean floor is controlled by early diagenetic processes, whereas the role of weathering, catagenesis, and hydrogeological factors may be crucial for phosphorites on continents.

Composition of phosphorites from continental margins, seamounts, and islands

Behavior of molybdenum and manganese is studied in phosphorite samples from shelves, seamounts, and islands of the ocean. In shelf phosphorites molybdenum and manganese contents are 2-128 and 12-1915 ppm, respectively, while the Mo/Mn ratio varies from 0.004 to 4.5. Phosphorites from ocean seamounts impregnated with ferromanganese oxyhydroxides contain 0.84-14.5 ppm Mo and 0.1-17% Mn. The Mo/Mn ratio varies within 0.0008-0.004. Phosphate bearing ferromanganese crusts overlying seamount phosphorites contain 54-798 ppm Mo and 10-20% Mn; the Mo/Mn ratio varies within 0.002-0.005. Corresponding values for most island phosphorites are 0.44-11.2 ppm, 27-287 ppm, and 0.008-0.20. Phosphorites from reduced environment are characterized by relative enrichment in Mo and depletion in Mn, whereas the Mo/Mn ratio reaches maximum values. The ratio decreases with transition to suboxic and oxic conditions. Molybdenum content in recent shelf sediments is commonly higher than that in authigenic phosphorites from these sediments. Recent phosphorite nodules from the Namibian shelf become depleted in Mo and Mn during their lithification, but Pliocene-Pleistocene nodules of similar composition and origin from the same region are enriched in Mo and characterized by variable Mn content. Higher Mo contents in phosphate bearing ferromanganese crusts result from coprecipitation of Mo and Mn from seawater. Unweathered phosphorites on continents and phosphorites from ocean shelves are largely enriched in Mo with the Mo/Mn ratio varying from 0.01 to 1.0. This is an evidence of their formation in reduced conditions.