Pollen analyses of sediment core GeoB9508-5

Millennial-scale dry events in the Northern Hemisphere monsoon regions during the last Glacial period are commonly attributed to southward shifts of the Intertropical Convergence Zone (ITCZ) associated with an intensification of the northeasterly (NE) trade wind system during intervals of reduced Atlantic meridional overturning circulation (AMOC). Through the use of high-resolution last deglaciation pollen records from the continental slope off Senegal, our data show that one of the longest and most extreme droughts in the western Sahel history, which occurred during the North Atlantic Heinrich Stadial 1 (HS1), displayed a succession of three major phases. These phases progressed from an interval of maximum pollen representation of Saharan elements between ~19 and 17.4 kyr BP indicating the onset of aridity and intensified NE trade winds, followed by a millennial interlude of reduced input of Saharan pollen and increased input of Sahelian pollen, to a final phase between ~16.2 and 15 kyr BP that was characterized by a second maximum of Saharan pollen abundances. This change in the pollen assemblage indicates a mid-HS1 interlude of NE trade wind relaxation, occurring between two distinct trade wind maxima, along with an intensified mid-tropospheric African Easterly Jet (AEJ) indicating a substantial change in West African atmospheric processes. The pollen data thus suggest that although the NE trades have weakened, the Sahel drought remained severe during this time interval. Therefore, a simple strengthening of trade winds and a southward shift of the West African monsoon trough alone cannot fully explain millennial-scale Sahel droughts during periods of AMOC weakening. Instead, we suggest that an intensification of the AEJ is needed to explain the persistence of the drought during HS1. Simulations with the Community Climate System Model indicate that an intensified AEJ during periods of reduced AMOC affected the North African climate by enhancing moisture divergence over the West African realm, thereby extending the Sahel drought for about 4000 years.

Sequential variation of carbonate cycles in South Atlantic DSDP locations

We report well-dated Late Cretaceous and Early Tertiary precessional climatic cycles, recorded by rhythmic carbonate maxima and minima in South Atlantic deep sea sites. Spectral analyses of digitized sediment color, a suitable carbonate proxy, show prominent regularities in the spacing marl-carbonate beds. Magnetostratigraphic dating over a number of magnetic chrons constrains the duration of the cycles, which can be detected over at least 20 Myr of sedimentation at 7 coring locations. Their mean absolute period of 23.5 +/- 4.4kyr agrees closely with the predicted late Cretaceous precessional period of 20.8 kyr. Because they can be matched to a physical forcing mechanism with a known repeat time, the cycles offer a new high-resolution tool to measure rates of climate change before and after the Cretaceous-Tertiary (K/T) boundary. From counts of carbonate cycles, we derive the position of the K/T boundary within C29R at 350 kyr after the base of the reversal. The constancy of cycle thickness (linearly related to sedimentation rate) and amplitude up to the "boundary clay" does not give evidence for climate instability preceding the boundary. Orbital chronometry records a step-function decrease in sediment accumulation rate at the Cretaceous-Tertiary boundary that is consistent with a geologically instantaneous event.

Body sizes and dive characteristics of narwhals (Monodon monoceros) from Kakiak Point and Melville Bay (2005-2007)

We report on wintertime data collected from Baffin Bay and northern Davis Strait, a major gateway linking the Arctic with the subpolar North Atlantic, using narwhals (Monodon monoceros) as an oceanographic sampling platform. Fourteen narwhals were instrumented with satellite-linked time-depth-temperature recorders between 2005 and 2007. Transmitters collected and transmitted water column temperature profiles from each dive between December and April, where >90% of maximum daily dive depths reached the bottom. Temperature measurements were combined with 15 helicopter-based conductivity-temperature-depth (CTD) casts taken in April 2007 across central Baffin Bay and compared with hydrographic climatology values used for the region in Arctic climate models. Winter temperature maxima for whale and CTD data were in good agreement, ranging between 4.0°C and 4.6°C in inshore and offshore Baffin Bay and in Davis Strait. The warm Irminger Water was identified between 57°W and 59°W (at 68°N) between 200 and 400 m depths. Whale data correlated well with climatological temperature maxima; however, they were on average 0.9°C warmer ±0.6°C (P < 0.001). Furthermore, climatology data overestimated the winter surface isothermal layer thickness by 50-80 m. Our results suggest the previously documented warming in Baffin Bay has continued through 2007 and is associated with a warmer West Greenland Current in both of its constituent water masses. This research demonstrates the feasibility of using narwhals as ocean observation platforms in inaccessible Arctic areas where dense sea ice prevents regular oceanographic measurements and where innate site fidelity, affinity for winter pack ice, and multiple daily dives to >1700 m offer a useful opportunity to sample the area.

Mid-Pleistocene Mg/Ca, temperature and stable isotopes from Globigerinoides ruber white and Globorotalia inflata of sediment core GeoB3801-6 from the subtropical South Atlantic

The glacial marine isotope stage 14 (MIS 14) appears in many climate records as an unusually warm glacial. During this period an almost monospecific, up to 1.5 m thick, laminated layer of the giant diatom Ethmodiscus rex has been deposited below the South Atlantic Subtropical Gyre. This oligotrophic region is today less favorable for diatom growth with sediments typically consisting of calcareous nannofossil oozes. We have reconstructed temperatures and the stable oxygen isotopic compositions of sea surface and thermocline water (d18Ow) from planktonic foraminiferal (Globigerinoides ruber and Globorotalia inflata) Mg/Ca and stable oxygen isotopes to test whether perturbations in surface ocean conditions contributed to the deposition of the diatom layer at ~530 kyr B.P. Temperatures and d18Ow values reconstructed from this diatom ooze interval are highly variable, with maxima similar to interglacial values. Since the area of the Ethmodiscus oozes resembles the region where Agulhas rings are present, we interpret these hydrographic changes to reflect the varying influence of warm and saline water of Indian Ocean origin that entered the Subtropical Gyre trapped in Agulhas rings. The formation of the Ethmodiscus oozes is associated with a period of maximum Agulhas leakage and a maximum frequency of Agulhas ring formation caused by a termination-type position of the Subtropical Front during the unusual warm MIS 14. The input of silica through the Agulhas rings enabled the shift in primary production from calcareous nannoplankton to diatoms, leading to the deposition of the massive diatom oozes.

(Table 1) Near surface water chemistry of south Patagonian waters during spring and winter

Both the biomass of autotrophic dinoflagellates and its contribution to total chlorophyll were found to increase significantly with seawater temperature and the level of stratification in southern Patagonian waters during spring and winter. The highest peak of biomass corresponded to a single species, Prorocentrum minimum (Pavillard) Schiller, and was detected in middle shelf waters, coinciding with the primary productivity and CO2 uptake maxima reported for the area under spring conditions.

Stable isotope ratios and organic carbon accumulation rates of late Pleistocene sediments of ODP Hole 117-724C

Stable isotope records of coexisting benthic foraminifers Uvigerina spp. and Cibicidoides spp. and planktonic G. ruber (white variety) from Site 724 are used to study the late Pleistocene evolution of surface and intermediate water hydrography (593 m water depth) at the Oman Margin. Glacial-interglacial d18O amplitudes recorded by the benthic foraminifers are reduced when compared to the estimated mean ocean changes of d18Oseawater . Epibenthic d13C remains at its modern level or is increased during glacial times. This implies that Red Sea outflow waters which are enriched in d18Oseawater and d13C (Sum CO2) have been replaced during glacial periods by intermediate waters still positive in d13C (Sum CO2) but more negative in d18Oseawater. Glacial-interglacial amplitudes of the planktonic d18O record exceed those of the mean ocean d18Oseawater variation and imply decreased surface water temperatures (SST) during glacial times. Throughout most of the records these cooling events correlate with enhanced rates of carbon accumulation. However, both negative (colder) SST and positive Corg accumulation rate anomalies do not correlate with potential physical upwelling maxima as inferred from the orbital monsoon index. This is in conflict with the established hypothesis that upwelling in the estern Arabia Sea should be strongest during maxima of the southwest monsoon.

(Appendix A) Dissolved manganese concentrations during POLARSTERN Cruise ARK-XXII/2

A total of 773 samples were analysed for dissolved manganese (Mn) in the Arctic Ocean aboard R.V. Polarstern during expedition ARK XXII/2 from 28 July until 07 October 2007 from Tromsø (Norway) to Bremerhaven. Concentrations of Mn were elevated in the surface layer with concentrations of up to 6 nM over the deep Basins and over 20 nM in the Laptev Sea. The general distribution of Mn through the water column is consistent with previous studies, but there are differences in the absolute concentrations that are most likely related to differences in sample area, sampling and filtration. The elevated concentrations of Mn in the surface layer are related to fresh water input. This was visible in the strong negative correlations observed between dissolved Mn and salinity. The correlation between Mn and salinity and the correlation between Mn and the quasi conservative trace water mass tracer PO4*, showed fluvial and melt water input and the Pacific and Atlantic origin of the surface waters. A large portion of the Mn delivered by the Arctic rivers is removed in the shelf seas and does not pass into the central basins. Most likely a benthic flux is at the origin of the elevated concentrations of Mn near the sediments in the Barents and Kara Seas. These elevated concentrations of Mn apparently affected the deep basins as well, as maxima in the concentrations of Mn were observed that corresponded with lowered transmission over the continental slope. A maximum in the concentration of Mn in the deep basin corresponded with anomalies in light transmission, potential temperature and dissolved iron, confirming the hydrothermal origin. The hydrothermal plume was observed throughout the Nansen Basin and over the deep Gakkel Ridge around 2500 m depth and a smaller plume was observed around 3200 m. The concentration of Mn at the Mn maximum around 2500 m depth decreased exponentially, consistent with a first order scavenging model. The concentrations of Mn were extremely low in the deep Makarov Basin (~0.05 nM) and slightly higher in the Eurasian Basin (~0.1 nM) outside the influence of the hydrothermal activity.

Siliceous phytoplankton in Late Quaternary sediments of ODP Site 175-1077

Late Quaternary fluctuations in the intensity of Congo River freshwater load were reconstructed using three different proxies (marine and freshwater diatoms, and the delta18O record of Globigerinoides ruber) preserved in the sediments of Ocean Drilling Program (ODP) Site 1077, located at the northern rim of the Congo River fan (5°10'S, 10°26'E). An abrupt change in the diatom assemblage is evident at Termination II: a two- to four-fold increase in (a) the relative abundance of a marine planktonic diatom tolerant of low salinity conditions (Cyclotella litoralis), and (b) in the concentration of freshwater diatoms. The microfossil data suggest a change in the environmental conditions surrounding Site 1077 from predominantly marine to mixed marine/brackish/fresh. The delta18O record of the planktic foraminifera G. ruber (pink) revealed negative deviations from the global oxygen isotope signal since Termination II which occurred during warm stage 1 and substages 3.2, 5.1, 5.3, and 5.5. Comparison of the isotopic signal of ODP Site 1077 with the record from a pelagic location (core GeoB1041 at 3°48'S, 7°05'W) confirms these results. The construction of an artificial delta18O curve using alkenone-derived sea surface temperature (SST) data from a nearby core (GeoB1008 at 6°S, 10°E) allowed us to estimate salinity and temperature effects on the ODP Site 1077 isotopic signal. Although increased SSTs may account for lighter delta18O values during warmer periods, they do not explain the extremely light values documented in the sediments of Site 1077. We used the oxygen isotope difference (Delta delta18O) between our site and GeoB1041 as a proxy for freshwater input. A general trend in the Delta delta18O was observed, with more negative values since Termination II. In addition, conspicuous Delta delta18O negative pulses coincided with periods of northern hemisphere summer insolation maxima over the African continent, suggesting an increase in the freshwater discharge from the Congo River due to enhanced precipitation on the hinterland. Here we propose that the abrupt change in environmental conditions at Site 1077 since Termination II is a consequence of a major reorganization in the depositional environment of the Congo River delta. This reorganization involved sustained equatorward displacement of the Angola-Benguela Front causing a northward deflection of the Congo River plume thus moving plume waters further north than normal and over Site 1077.

Species abundance and water and sediment characteristics for three ANDEEP stations on Maud Rise and the Weddell Sea

The benthic fauna was investigated during the expedition ANT-XXIV/2 (2007/08) in relation to oceanographic features, biogeochemical properties and sediment characteristics, as well as the benthic, pelagic and air-breathing fauna. The results document that Maud Rise (MR) differs distinctly from surrounding deep-sea basins investigated during previous Southern Ocean expeditions (ANDEEP 2002, 2005). Considering all taxa, the overall similarity between MR and adjacent stations was low (~20% Bray-Curtis-Similarity), and analyses of single taxa show obvious differences in species composition, abundances and densities. The composition and diversity of bivalves of MR are characterised by extremely high abundances of three species, especially the small sized Vesicomya spp. Exceptionally high gastropod abundance at MR is due to the single species Onoba subantarctica wilkesiana, a small brooder that may prey upon abundant benthic foraminiferas. The abundance and diversity of isopods also show that one family, Haplomunnidae, occurs with a surprisingly high number of individuals at MR while this family was not found at any of the 40 bathyal and abyssal ANDEEP stations. Similarly, polychaetes, especially the tube-dwelling, suspension-feeder fraction, are represented by species not found at the comparison stations. Sponges comprise almost exclusively small specimens in relatively high numbers, especially a few species of Polymastiidae. Water-column sampling from the surface to the seafloor, including observations of top predators, indicate the existence of a prospering pelagic food web. Local concentrations of top predators and zooplankton are associated with a rich ice-edge bloom located over the northern slope of MR. There the sea ice melts, which is probably accelerated by the advection of warm water at intermediate depth. Over the southern slope, high concentrations of Antarctic krill (Euphausia superba) occur under dense sea ice and attract Antarctic Minke Whales (Balaenoptera bonaerensis) and several seabird species. These findings suggest that biological prosperity over MR is related to both oceanographic and sea-ice processes. Downward transport of the organic matter produced in the pelagic realm may be more constant than elsewhere due to low lateral drift over MR.

Age determination of sediment cores from the Panama Basin

High-resolution percent Corg and delta18Oforam records obtained from Panama Basin core Atlantis II 54-25PC and additional data from nearby core P7 show that enhanced burial of organic carbon has characterized every major glacial period for the last 500 kyr in that area. Both Corg concentration and mass accumulation rate profiles exhibit a sawtooth pattern with maxima occurring typically in the later stages of glacial periods. Comparison with dust records suggests that the carbon accumulation rate profile reflects both the upwelling history and a variable rate of iron input during the late Quaternary. The sawtooth character may derive from increased wind velocities and rates of upwelling during glacials which are indirectly related to ice volume (Sarnthein et al., 1988). The rapid decline in export production at the end of glacials in the equatorial Pacific may be attributed to the retreat of ice sheets (thus reduced wind velocities and upwelling) coupled with a coincident decline in atmospheric dust load and/or delivery rate. The Corg accumulation rate profiles do not correlate well with atmospheric CO2 records. For example, atmospheric CO2 was already at a minimum 40 kyr ago when production in the Panama Basin began increasing dramatically, commensurate with an increase in global dust levels. Using the relationship between the degree of photosynthetic fractionation and the concentration of free CO2 in the surface ocean postulated by Popp et al. (1989), delta13Corg measurements made on core P7 show that Panama Basin surface waters have been supplying CO2 to the atmosphere continually for at least the last 50 kyr. There is no evidence for a flux of CO2 into the surface ocean in this area at any time during this period despite the higher production. If the Panama Basin cores are representative of the eastern and central equatorial Pacific, then these observations weaken the influence on CO2 drawdown postulated for increased glacial productivity at low latitudes.

Sea surface temperature reconstruction on three sediment profiles off Portugal

Sea Surface Temperature (SST), river discharge and biological productivity have been reconstructed from a multi-proxy study of a high-temporal-resolution sedimentary sequence recovered from the Tagus deposition center off Lisbon (Portugal) for the last 2000 years. SST shows 2 °C variability on a century scale that allows the identification of the Medieval Warm Period (MWP) and the Little Ice Age (LIA). High Iron (Fe) and fine-sediment deposition accompanied by high n-alkane concentrations and presence of freshwater diatoms during the LIA (1300-1900 AD) (Science 292 (2001) 662) suggest augmented river discharge, whereas higher total-alkenone concentrations point to increased river-induced productivity. During the MWP (550-1300 AD) (Science 292 (2001) 662) larger mean-grain size and low values of magnetic susceptibility, and concentrations of Fe, n-alkanes, and n-alcohols are interpreted to reflect decreased runoff. At the same time, increased benthic and planktonic foraminifera abundances and presence of upwelling related diatoms point to increased oceanic productivity. On the basis of the excellent match found between the negative phases of the North Atlantic Oscillation (NAO) index and the intensified Tagus River discharge observed for the last century, it is hypothesized that the increased influx of terrigenous material during the LIA reflects a negative NAO-like state or the occurrence of frequent extreme NAO minima. During the milder few centuries of the MWP, stronger coastal upwelling conditions are attributed to a persistent, positive NAO-like state or the frequent occurrence of extreme NAO maxima. The peak in magnetic susceptibility, centered at 90 cm composite core depth (ccd), is interpreted as the result of the well-known 1755 AD Lisbon earthquake. The Lisbon earthquake and accompanying tsunami are estimated to have caused the loss of 39 cm of sediment (355 years of record-most of the LIA) and the instantaneous deposition of a 19-cm sediment bed.

Sedimentary climate indicators of sediment core MD08-3167 and GeoB1711-4, southwestern Africa

The past climate evolution of southwestern Africa is poorly understood and interpretations of past hydrological changes are sometimes contradictory. Here we present a record of leaf-wax dD and View the MathML source taken from a marine sediment core at 23°S off the coast of Namibia to reconstruct the hydrology and C3 versus C4 vegetation of southwestern Africa over the last 140 000 years (140 ka). We find lower leaf-wax dD and higher View the MathML source (more C4 grasses), which we interpret to indicate wetter Southern Hemisphere (SH) summer conditions and increased seasonality, during SH insolation maxima relative to minima and during the last glacial period relative to the Holocene and the last interglacial period. Nonetheless, the dominance of C4 grasses throughout the record indicates that the wet season remained brief and that this region has remained semi-arid. Our data suggest that past precipitation increases were derived from the tropics rather than from the winter westerlies. Comparison with a record from the Congo Basin indicates that hydroclimate in southwestern Africa has evolved in antiphase with that of central Africa over the last 140 ka.

(Table 1) Dissolved and particulate organic carbon, phosphorus, and nitrogen in waters of the Sea of Japan

Concentrations of dissolved and particulate organic carbon (DOC and POC, respectively), phosphorus (DP and PP, respectively) and particulate organic nitrogen (PON) were determined at Station VITYAZ6656 in the Sea of Japan in 12 sea water samples collected in June 1972 with a 200-liter sampling bottle. Mean weighted concentrations from the surface to 2000 m were: DOC - 1.58 mg/l, POC - 17.9 µg/l, DP - 13.9 µg/l, PP - 0.185 µg/l, PON - 2.7 µg/l, the ratios were DOC:DP=100:9 and POC:PON:PP=100:14:1. Relation between POC (µg/l)and the light attenuation index "e" (1/m) for the visible part of the spectrum is described by the equation POC = ca. 170e. The maximum of POC in the upper layer correlated with the maxima of phyto- and bacterioplankton and protozoa.

Planktonic foraminifera in Core ML2_66, North Atlantic

Evolution of approaches and methods for reconstruction of paleoenvironmental conditions from microfossils contained in bottom sediments is assessed. Authors elaborated a new actualistic basis for such reconstructions, consisting of a database on contents of tests of planktonic foraminifers in the surface layer of Atlantic sediments and a package of mathematical tools for computer data processing. Structure of the database is described. It contains data on test contents for 29 species and varieties of planktonic foraminifers in 381 samples. A mathematical model designed for reconstructions is based on factor analysis and multidimensional spline interpolation. The model allows one to deduce Quaternary hydrological parameters (paleotemperature, paleosalinity) for standard hydrological levels down to depth of 250 m for the four seasons of the year. Reconstructions are illustrated by an example of a sedimentary core from the North Atlantic representing a period of 300 ky. During the next to last and the last maxima of continental glaciation (oxygen isotope stages 8, 6, 4, and 2), the subarctic water mass was spread here. Winter and summer surface water temperatures comprised 1-5° and 5-7°C, respectively. During interglacials and in Holocene the conditions were close to present ones: winter and summer surface water temperatures comprised 10-12 and 15-17°C, respectively. Vertical paleohydrological profiles compiled for peaks of climatostratigraphic intervals suggest that during cold intervals water stratification was stronger than during the warm ones. At depth 50 m seasonal salinity oscillations did not exceed 0.4 per mil and commonly salinity was minimum in winter and maximum in summer.

Particle flux determined from traps in the Canary Island region

We present a 3 year record of deep water particle flux at the recently initiated ESTOC (European Station for Time-series in the Ocean, Canary Islands) located in the eastern subtropical North Atlantic gyre. Particle flux was highly seasonal, with flux maxima occurring in late winter-early spring. A comparison with historic CZCS (Coastal Zone Colour Scanner) data shows that these flux maxima occurred about 1 month after maximum chlorophyll was observed in surface waters in a presumed primary source region 100 km * 100 km northeast of the trap location. The main components of the particles collected with the traps were mineral particles and carbonate, both correlating strongly with organic matter sedimentation. Mineral particles in the sinking matter are indicative of the high aeolian input from the African desert regions. Comparing particle fluxes at 1 km and 3 km depth, we find that particle sedimentation increased substantially with depth. Yearly organic carbon sedimentation was 0.6 g m**-2 at 1 km depth compared with 0.8 g m**-2 at 3 km. We hypothesize that higher phytoplankton biomass observed further north could be a source of laterally advecting particles that interact with fast sinking particles originating from the primary source region. This hypothesis is also supported by the differences in size distribution of lithogenic matter found at the two trap depths.