Use of electrochemical impedance spectroscopy for study of CO2 corrosion prevention by batch treatment inhibitor films

Electrochemical impedance spectroscopy (EIS) was used to study and evaluate commercial batch treatment inhibitors which are used for protecting oil wells, gas wells, and pipelines from CO2 corrosion, focusing on the evaluation of inhibitor film persistency. It was found that theformation and deterioration of batch treatment inhibitor films were accompanied by typical impedance spectral changes. During the formation of inhibitor films, electrode impedance showed a rapid increase and the Bode phase angle plots also showed a sudden change. Thus, the formation of inhibitor film was a very fast process. During the deterioration of inhibitor films, electrode impedance showed a gradual decrease and the Bode phase angle plots showed changes which characterised the three stages of the inhibitor film deterioration process. The relationships between EIS and corrosion rate are discussed, including comparisons with weight loss measurements. Based on the experimental findings in the present work, a method is suggested for estimating the persistency of inhibitor films by monitoring the characteristic changes in the Bode phase angle plots and by measuring electrochemical charge transfer resistance at the second and third stages of the inhibitor film deterioration process.

Pressure- and heat-induced insertion of CO2 into an auxetic small-pore zeolite

When the small-pore zeolite natrolite is compressed at ca. 1.5 GPa and heated to ca. 110 °C in the presence of CO₂, the unit cell volume of natrolite expands by 6.8% and ca. 12 wt % of CO₂ is contained in the expanded elliptical channels. This CO₂ insertion into natrolite is found to be reversible upon pressure release.

Studies of CO2 corrosion product scales using electrochemical impedance spectroscopy and surface characterisation techniques

Electrochemical impedance spectroscopy (EIS) was used to study carbon dioxide (CO2) corrosion product scales and their effects on further CO2 corrosion. Objectives were to determine the suitability of EIS for studying corrosion scales and to investigate the influence of environmental factors on scale formation. EIS provided useful information about protective abilities and electrochemical properties of corrosion scales. CO2 corrosion scales formed at high-temperature and pressure provided better protection than those formed at low-temperature and pressure. The level of protection of the scale formed at higher temperature and pressure increased with exposure time. EIS results were compared with coupon weight-loss measurements. Scales were analyzed using a combination of Fourier transform infrared (FTIR) analysis, x-ray diffraction (XRD), and electron microscopy

Measurement and solutions to thermal comfort, CO2 and ventilation rates in schools

An Australian research facility, conducted a study on several different school classrooms in regards to their thermal comfort, CO2 levels, air temperature stratification and ventilation rates in a selection of Victorian (Melbourne, Australia) schools during a winter season. A brief literature review reveals similar IAQ problems elsewhere (outside Australia) and suggests several HVAC concepts that provide potential solutions. Our intention is to highlight particular IAQ discrepancies in existing school classroom design resulting from these case study measurements, suggesting construction and mechanical operational conditioning improvements.In particular this research confirms the urgency and necessity of addressing IAQ problems in schools, world wide. Our results of the Australian school classroom measurements are similar to other parts of the world, indicating that CO2 levels, ventilation rates and air temperatures are non-compliant with the standards.

Fabrication of polycarbonate microfluidic devices using a focusing and defocusing methods of CO2 laser system

Fabrication of microfluidic devices has always been a challenging endeavour due to its characteristics and cost involved. Recently, laser ablation using low cost engravers has been exploited for fast and cheap prototyping. In this paper, we explore the various parameters affecting the fabrication of polycarbonate microfluidic channels using CO2 laser ablation. The results show that, by manipulating the focus length of the laser beam, we can achieve good cross sectional profiles with low surface roughness. The results also show that various profiles can be fabricated by changing the laser parameters such as laser power, cutting speed and number of laser pulses.

Mapping Co2 emission from commuting in regional Australia : greater Geelong case study

Commuting to work is one of the most important and regular routines of urban transportation. From a geographic perspective, the length of people's commute is influenced, to some degree, by the spatial separation of their home and workplace and the transport infrastructure. The rise of car ownership in Australia has been accompanied by a considerable decrease of public transport use. Increased personal mobility has fuelled the trend of decentralised housing development, mostly without a clear planning for local employment, or alternative means of transportation. As a result, the urban patterns of regional Australia is formed by a complex network of a multitude of small towns, scattered in relatively large areas, which are totally dependent and polarized by few medium and large cities. Such hierarchical and dispersed geographical structure implies significant carbon dioxide emissions from transportation. Transport sector accounts for 14% of Australia's net greenhouse gas emissions, and without further policy action, they are projected to continue to increase. The aim of this paper is to demonstrate the importance of incorporating urban climate understanding and knowledge into urban planning processes in order to develop cities that are more sustainable. A GIS-based gravity model is employed to examine the travel patterns related to hierarchical and geographical urban region networks, and the derived total carbon emissions, using the Greater Geelong region as a case study. The new challenges presented by climate change bring with them opportunities. In order to fully reach the very challenging targets of carbon reduction in Australia an integrated and strategic vision for urban and regional planning is necessary.

Investigating and understanding CO2 levels in school classrooms

 It is a reported fact that a high CO2 concentration is a problem in school classrooms. However, the mere reporting of such results stops short of investigating causes; understanding is often missing. Steady-state results are often used in situations where changes occur frequently, such as varying student numbers, opening and closing classroom doors and windows and changing weather conditions. We revisit the mass balance model commonly used to predict or track CO2 concentrations in enclosed spaces as these factors change over time under varying conditions. This has prompted the study in several classrooms of actual air exchange rates, student exhalation rates, room volumes and ventilation design. In these cases, student numbers, room ventilation conditions (open and closed doors), room volume and the CO2 concentration have been recorded throughout the day. By fitting the model equation to the data, unknown parameters such as actual air change rates and CO2 exhalation rates per student can be determined. Having verified that the data can be modelled, we can predict behaviour in other cases such as a realistic rate of CO2 increase. This allows designers to size classrooms and ventilation systems to achieve a desired CO2 characteristic for known usages while saving energy.

CO2 laser manufacturing of miniaturised lenses for lab-on-a-chip systems

This article describes the manufacturing and characterisation of plano-convex miniaturised lenses using a CO2 laser engraving process in PMMA substrates. The technique allows for lenses to be fabricated rapidly and in a reproducible manner at depths of over 200 µm and for lens diameters of more than 3 mm. Experimental characterisation of the lens focal lengths shows good correlation with theory. The plano-convex lenses have been successfully embedded into capillary microfluidic systems alongside planar microlenses, allowing for a significant reduction of ancillary optics without a loss of detection sensitivity when performing fluorescence measurements. Such technology provides a significant step forward towards the portability of fluorescence- or luminescence-based systems for biological/chemical analysis.

Fabrication of polymeric microchannels with focused and defocused CO2 lasers

 The control of energy distribution or energy intensity inside a laser spot using a defocusing method enables the formation of high-quality microchannels of multiple cross-sections in polycarbonate. Moreover, a thermal mathematical model of the process was developed to aid understanding of the process and to allow channel topology prediction.