石化产业空间组织研究进展与展望

石化产业在国民经济中占有重要地位,关系到国家经济安全、政治安全和国防安全。石化产业空间组织是产业部门地理研究的重要领域之一,有必要考察其研究进展和发展趋向。在厘清石化产业空间组织基本内涵的基础上,本文从区位因子及作用机制、空间组织模式、跨国石油公司和石化产业集群等4个方面,回顾了石化产业空间组织的相关研究及最新进展,并对其进行了总结和评述。研究认为,今后我国石化产业空间组织研究应在以下方面加强:在研究尺度上,应基于全球、国家和地区3个空间尺度,研究石化产业空间组织的演变轨迹和演进机理;在研究视角上,应基于跨国公司和产业集群的视角,研究跨国石油公司和主要石化产业集聚区的空间组织模式及内在机制;在研究内容上,应基于我国石化产业空间组织演变轨迹的梳理和演进阶段的判断,结合我国石化产业发展现状及存在问题,优化我国石化产业的空间组织。

安徽省蒙城县作物秸秆资源利用现状及其影响因素分析

通过实地农户调查分析、评价安徽省蒙城县的秸秆利用现状。蒙城县作物秸秆利用率很高,主要用于饲料和燃料,秸秆利用方式虽"合理却非有效(低效)",没有充分发挥秸秆营养和能量效率的传统利用方式仍是目前农户采用的主要方式。增加收入,利用剩余劳动时间,养牛市场带动是造成目前利用现状的几个最主要主客观因素。强化市场带动作用,改善土地流通政策环境,扩大经营规模,推广应用新技术是今后秸秆利用应重视解决的问题。

Biosorption of Cd2+, Cu2+, Ni2+ and Zn2+ ions from aqueous solutions by pretreated biomass of brown algae

In this paper, marine brown algae Laminaria japonica was chemically modified by crosslinking with epichlorohydrin (EC1 and EC2), or oxidizing by potassium permanganate (PC), or crosslinking with glutaraldehyde (GA), or only washed by distilled water (DW). They were used for equilibrium sorption uptake studies with Cd2+, Cu2+, Ni2+ and Zn2+.

Hydrogen peroxide biosensor based on horseradish peroxidase-Au nanoparticles at viologen grafted glassy carbon electrode

A novel hydrogen peroxide biosensor was fabricated that is based on horseradish peroxidase-Au nanoparticles immobilized on a viologen-modified glassy carbon electrode (GCE) by amino cation radical oxidation in basic solution. The immobilized BAPV acts as a mediator and a covalent linker between GCE and the Au nanoparticles. The biosensor exhibited fast response, good reproducibility, and long-term stability.

Biosorption of Cd2+, Cu2+, Ni2+ and Zn2+ ions from aqueous solutions by pretreated biomass of brown algae

In this paper, marine brown algae Laminaria japonica was chemically modified by crosslinking with epichlorohydrin (EC1 and EC2), or oxidizing by potassium permanganate (PC), or crosslinking with glutaraldehyde (GA), or only washed by distilled water (DW). They were used for equilibrium sorption uptake studies with Cd2+, Cu2+, Ni2+ and Zn2+. The experimental data have been analyzed using Langmuir, Freundlich and Redlich-Peterson isotherms. The results showed that the biosorption equilibrium was well described by both the Langmuir and Redlich-Peterson isotherms.

Investigation of Chemical Bond Characteristics, Thermal Expansion Coefficients and Bulk Moduli of alpha-R2MoO6 and R2Mo2O7 (R = rare earths) by Using a Dielectric Chemical Bond Method

Theoretical researches are performed on the alpha-R2MoO6 (R = Y, Gd, Tb Dy, Ho, Er, Tm and Yb) and pyrochlore-type R2Mo2O7 (R = Y, Nd, Sm, Gd, Tb and Dy) rare earth molybdates by using chemical bond theory of dielectric description. The chemical bonding characteristics and their relationship with thermal expansion property and compressibility are explored. The calculated values of linear thermal expansion coefficient (LTEC) and bulk modulus agree well with the available experimental values. The calculations reveal that the LTECs and the bulk moduli do have linear relationship with the ionic radii of the lanthanides: the LTEC decreases from 6.80 to 6.62 10(-6)/K and the bulk modulus increases from 141 to 154 GPa when R goes in the order Gd, Tb Dy, Ho, Er, Tm, and Yb in the alpha-R2MoO6 series; while in the R2Mo2O7 series, the LTEC ranges from 6.80 to 6.61 10(-6)/K and the bulk modulus ranges from 147 to 163 GPa when R varies in the order Nd, Sm, Gd, Tb and Dy.

Synthesis of mesoporous YF3 nanoflowers via solvent extraction route

Mesoporous YF3 nanoflowers were successfully prepared via solvent extraction route. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations indicated that these nanoflowers with uneven porous architectures had a spherical shape and were consisted of many YF3 nanosheets with a thickness of about 15 not. Energy-dispersive spectroscopy (EDS) analysis was used to check the chemical composition and purity of the products. YF3 nanoflowers had bimodal mesoporous distribution and Brunauer-Emmett-Teller (BET) surface area of 116 m(2)/g.

Tris(2,2 '-bipyridyl) ruthenium(II) doped silica film modified indium tin oxide electrode and its electrochemiluminescent properties

An approach was reported to synthesize silica hybridized ruthenium bipyridyl complex through amidation reaction by covalent attachment of bis(bipyridyl)-4,4'-dicarboxy-2,2'-bipyridyl-ruthenium to (3-aminopropyl)-triethoxysilane. The hybrid complex then was gelatinized through acid catalytic hydrolysis method and a sol-gel modified indium, tin oxide electrode was prepared via spin coating technique. As prepared indium tin oxide electrode possesses good stability therein with excellent electrochemiluminescence behavior.

Ordered droplet formation by thin polymer film dewetting on a stripe-patterned substrate

The dewetting process of thin polystyrene (PS) film on flat and stripe-patterned substrates is presented. Different dewetting processes were observed when the thin PS films annealed at above the glass transition temperature on these different kinds of substrates. The final dewetting on the flat substrate led to formation of polygonal liquid droplets, while on the stripe-patterned substrate, the droplets were observed to align at the centers of the stripes. A possible explanation for the dewetting process on the stripe-patterned substrate is proposed.

自组装单分子膜包覆的金属纳米粒子的电化学研究

介绍了近年来自组装单分子膜包覆的金属纳米粒子这一领域的最新发展,包括单分子层膜包裹的纳米粒子的合成、衍生化、光学和电化学性质及应用,其中重点介绍了其量子化充电现象.对该领域的深入研究将大大地促进化学、生物科学、材料科学和纳米电子学等前沿学科的发展.

Synthesis and catalytic kinetics of tellurium-modified hyaluronic acid with glutathione peroxidase activity

A novel mimic TeHA was synthesized by modifying hyaluronic acid (HA) with tellurium, whose function is similar to that of glutathione peroxidase (GPX). The structure of TeHA was characterized by means of infrared spectroscopy and nuclear magnetic resonance spectroscopy, showing that the target Te is located at -CH2OH of the N-acetyl-D-glucosamine of HA. The activity of TeHA is 163.6 U/mu mol according to Wilson's method. In contrast to other mimics, TeHA displays a high activity. Moreover, TeHA can use many hydroperoxides as substrates, such as H2O2, cumenyl hydroperoxide, and tert-butyl hydroperoxide, and cumenyl hydroperoxide is the optimal substrate. A ping-pong mechanism was deduced for the reduction reactions catalyzed by TeHA according to the steady-state kinetic studies.