A hybrid neutron diffraction and computer simulation study on the solvation of N-methylformamide in dimethylsulfoxide

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Caracterização de biomassa lignocelulósica para uso em processos térmicos de geração de energia

Pós-graduação em Química - IQ

A study of the main oxidation products of natural pyrite by voltammetric and photoelectrochemical responses

(Photo)electrochemical experiments on pyrite electrodes in acetic acid-acetate buffer (pH = 4.5) are conducted to clarify the main oxidation reactions and the nature of the products. Electrochemical reactions in the -0.40 to 1.25 V (SHE) potential range are studied, and the production of iron (III) polysulfide from anodically formed iron oxides and polysulfides is discussed. Charges experimentally obtained are considered for the estimation of the most likely stoichiometry of the metallic polysulfide. The photoselectivity of the pyrite corrosion process indicates that the oxidation reactions of Fe2+ and S-2(2-) an not consecutive. The changes in stoichiometry and/or annihilation of crystalline structure defects are responsible for the observed photosensitivity of pyrite. A description of light effects on the interfacial behaviour and stability of pyrite is presented in terms of conduction and valence band energies, and thermodynamic potentials. (C) 2001 Elsevier Science B.V. All rights reserved.

Shell beds from the Low Head Member (Polonez Cove Formation, early Oligocene) at King George Island, west Antarctica: new insights on facies analysis, taphonomy and environmental significance

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Optical spectrum of bottom-up graphene nanoribbons: towards efficient atom-thick excitonic solar cells

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Measurement of the muon charge asymmetry in inclusive pp -> W plus X production at root s=7 TeV and an improved determination of light parton distribution functions

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Instability of nonminimally coupled scalar fields in the spacetime of slowly rotating compact objects

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Substratum choice for nesting in male Nile tilapia Oreochromis niloticus

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

A DFT Study of Structural and Electronic Properties of ZnS Polymorphs and its Pressure-Induced Phase Transitions

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Triple-aspect monism: Physiological, mental unconscious and conscious aspects of brain activity

Brain activity contains three fundamental aspects: (a) The physiological aspect, covering all kinds of processes that involve matter and/or energy; (b) the mental unconscious aspect, consisting of dynamical patterns (i.e., frequency, amplitude and phase-modulated waves) embodied in neural activity. These patterns are variously operated (transmitted, stored, combined, matched, amplified, erased, etc), forming cognitive and emotional unconscious processes and (c) the mental conscious aspect, consisting of feelings experienced in the first-person perspective and cognitive functions grounded in feelings, as memory formation, selection of the focus of attention, voluntary behavior, aesthetical appraisal and ethical judgment. Triple-aspect monism (TAM) is a philosophical theory that provides a model of the relation of the three aspects. Spatially distributed neuronal dendritic potentials generate amplitude-modulated waveforms transmitted to the extracellular medium and adjacent astrocytes, prompting the formation of large waves in the astrocyte network, which are claimed to both integrate distributed information and instantiate feelings. According to the valence of the feeling, the large wave feeds back on neuronal synapses, modulating (reinforcing or depressing) cognitive and behavioral functions.

Fidelidade composicional de assembléias de braquiópodes (Rhynconelliformea) na plataforma e talude continental: implicações paleontológicas e geológicas

This paper deals with the Compositional Fidelity of the brachiopods assemblages, dominated by Bouchardia rosea, on the outer shelf and continental slope along São Paulo State. Samples were obtained during the Revizee-Score-Sul-Benthos program. The sampled stations are in sites as depth as 90 to 600 meters, along the outer continental shelf, the shelf break and the top of continental slope. The fidelity estimates were obtained directly from the comparisons between living biota and dead shells, from the same collecting stations. Data come from 66 sampling stations, and the vast majority of the Bouchardia rosea individuals collected (n=2393) were dead (n = 2342, 97.9%). Only 51 individuals were collected alive. When pooling the data from all collecting stations the dead/live frequency is of 2,1% only. The occurrences of Bouchardia rosea shells in siliciclastic bottoms are reduced and living individuals were not found on this type of bottom, at least during the sampling program. These results suggest low compositional fidelity (live-dead) or high compositional mismatch, pointing to a recent decrease in this specie population. The low compositional fidelity of the Bouchardia rosea assemblages in outer shelf sites may be due to changes in seawater temperature, nutrient availability and population history. All these issues must be investigated in the near future

Estudo do fenômeno de instabilidade de estruturas cilíndricas de paredes finas submetidas ao carregamento de pressão externa

Thin walled cylindrical shells are widely used in many areas of industry, including civil, mechanical, nuclear, marine, petroleum and aerospace engineering. The wide application of thin cylindrical shells and the importance of instability phenomenon are the motivation basis to this study, since these factors have a great importance in engineering projects. It is presented a detailed study about the instability of cylindrical shells based on theoretical calculation, which results are compared with finite elements method calculation. The loading and boundary conditions analyzed are based on the most common types verified in real engineering projects and refer respectively to lateral (external) pressure and cylinders with simply supported edges. The calculation based on the finite elements method was executed with ANSYS 13.0 software. The results obtained with this calculation are in good agreement with the analytical theory presented in the technical note NACA No 1341 (BATDORF, 1947) considering a wide range of applicability. On the other hand, the analytical method presented in the book Theory of Elastic Stability (TIMOSHENKO; GERE, 1936) has a very restrict applicability and has presented considerable deviations in a great sort of the analyzed cases

Schinus Terebinthifolius raddi: estudo farmacognóstico e investigação da atividade biológica de extratos e frações

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Aspectos quânticos e clássicos da instabilidade de campos fundamentais em espaços-tempos astrofísicos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Aceitabilidade e qualidade nutricional de beterrabas in natura e pré-processadas submetidas a diferentes métodos de cocção

Pós-graduação em Agronomia (Energia na Agricultura) - FCA