Petrology and geochemistry of the AND-1B Core

Petrologic descriptions will follow a division related to both grain size and lithology like that adopted in Cape Roberts investigation (Cape Roberts Science Team 2000, hdl:10013/epic.28287.d001, and references therein). First, we describe the petrology of the sand fraction of the core. Second, we report the distribution of clasts with diameter larger than 2 millimeter (mm) and the petrology of basement clasts. Third, we focus on the occurrence and petrology of McMurdo Volcanic Group sediments, which represent the largest component in the core. The final section continues with the compositional characterization of bulk sediments by continuous X-ray fluorescence measurement (XRF scan) integrated by carbonate geochemistry and concludes with the porewater geochemistry. All of these data will contribute to infer palaeoclimatic information and to understand provenance history of detritus, changes in depositional environment, and spatial and temporal evolution of magmatism in McMurdo Ice Shelf area.

AMS 14C dating points, isotopic compositions, Mg/Ca ratios and sea surface temperatures of sediment cores GeoB10029-4 and GeoB10038-4

Quantifying the spatial and temporal sea surface temperature (SST) and salinity changes of the Indo-Pacific Warm Pool is essential to understand the role of this region in connection with abrupt climate changes particularly during the last deglaciation. In this study we reconstruct SST and seawater d18O of the tropical eastern Indian Ocean for the past 40,000 years from two sediment cores (GeoB 10029-4, 1°30'S, 100°08'E, and GeoB 10038-4, 5°56'S, 103°15'E) retrieved offshore Sumatra. Our results show that annual mean SSTs increased about 2-3 °C at 19,000 years ago and exhibited southern hemisphere-like timing and pattern during the last deglaciation. Our SST records together with other Mg/Ca-based SST reconstructions around Indonesia do not track the monsoon variation since the last glacial period, as recorded by terrestrial monsoon archives. However, the spatial SST heterogeneity might be a result of changing monsoon intensity that shifts either the annual mean SSTs or the seasonality of G. ruber towards the warmer or the cooler season at different locations. Seawater d18O reconstructions north of the equator suggest fresher surface conditions during the last glacial and track the northern high-latitude climate change during the last deglaciation. In contrast, seawater ?18O records south of the equator do not show a significant difference between the last glacial period and the Holocene, and lack Bølling-Allerød and Younger Dryas periods suggestive of additional controls on annual mean surface hydrology in this part of the Indo-Pacific Warm Pool.

Physical oceanography during METEOR cruise M10/1

During leg 1 of Meteor cruise 10 in March/April 1989 at 18°N, 30°W, the high spatial and temporal resolution of hydrographic CTD-stations indicated that the study site was in a hydrographically complex region in the transition zone between the Canary Current and the North Equatorial Current at the southern boundary of the subtropical gyre. Strong variability was found within the upper 120 m due to interleavings of warmer and saltier subtropical salinity maximum water with colder and less saline upper thermocline water. The interleavings caused unexpected nose-like temperature, salinity, nitrate and oxygen profiles yet not described in the literature. A second variability source was found in the Central Water area, because the study area was situated in the vicinity of the Central Water Boundary dividing North and South Atlantic Central Water. Hydrographic analysis of the study shows that interpretations of biological and chemical data can only be done in conjunction with high resolution CTD-profiling.

Mineral composition and experimental results from XRD analyses of sediments from ODP Leg 190 sites

X-ray diffraction analyses of the clay-sized fraction of sediments from the Nankai Trough and Shikoku Basin (Sites 1173, 1174, and 1177 of the Ocean Drilling Program) reveal spatial and temporal trends in clay minerals and diagenesis. More detrital smectite was transported into the Shikoku Basin during the early-middle Miocene than what we observe today, and smectite input decreased progressively through the late Miocene and Pliocene. Volcanic ash has been altered to dioctahedral smectite in the upper Shikoku Basin facies at Site 1173; the ash alteration front shifts upsection to the outer trench-wedge facies at Site 1174. At greater depths (lower Shikoku Basin facies), smectite alters to illite/smectite mixed-layer clay, but reaction progress is incomplete. Using ambient geothermal conditions, a kinetic model overpredicts the amount of illite in illite/smectite clays by 15%-20% at Site 1174. Numerical simulations come closer to observations if the concentration of potassium in pore water is reduced or the time of burial is shortened. Model results match X-ray diffraction results fairly well at Site 1173. The geothermal gradient at Site 1177 is substantially lower than at Sites 1173 and 1174; consequently, volcanic ash alters to smectite in lower Shikoku Basin deposits but smectite-illite diagenesis has not started. The absolute abundance of smectite in mudstones from Site 1177 is sufficient (30-60 wt%) to influence the strata's shear strength and hydrogeology as they subduct along the Ashizuri Transect.

Satellite-based daily lake areas in the Yangtze Basin, China, 2000-2011

The Yangtze River Basin downstream of China's Three Gorges Dam (TGD) (thereafter referred to as "downstream" basin) hosts the largest cluster of freshwater lakes in East Asia. These lakes are crucial water stocks to local biophysical environments and socioeconomic development. Existing studies document that individual lakes in this region have recently experienced dramatic changes under the context of enduring meteorological drought, continuous population growth, and extensive water regulation since TGD's initial impoundment (i.e., June, 2003). However, spatial and temporal patterns of lake dynamics across the complete downstream Yangtze basin remain poorly characterized. Using daily MODIS imagery and an advanced thematic mapping scheme, this study presents a comprehensive monitoring of area dynamics in the downstream lake system at a 10-day temporal resolution during 2000-2011. The studied lakes constitute ~76% (~11,400 km**2) of the total downstream lake area, including the entire +70 major lakes larger than 20 km**2. The results reveal a decadal net decline in lake inundation area across the downstream Yangtze Basin, with a cumulative decrease of 849 km**2 or 7.4% from 2000 to 2011. Despite an excessive precipitation anomaly in the year 2010, the decreasing trend was tested significant in all seasons. The most substantial decrease in the post-TGD period appears in fall (1.1%/yr), which intriguingly coincides with the TGD water storage season. Regional lake dynamics exhibit contrasting spatial patterns, manifested as evident decrease and increase of aggregated lake areas respectively within and beyond the Yangtze Plain. This contrast suggests a marked vulnerability of lakes in the Yangtze Plain, to not only local meteorological variability but also intensified human water regulations from both the upstream Yangtze main stem (e.g., the TGD) and tributaries (e.g., lakes/reservoirs beyond the Yangtze Plain). The produced lake mapping result and derived lake area dynamics across the downstream Yangtze Basin provides a crucial monitoring basis for continuous investigations of changing mechanisms in the Yangtze lake system.

Photochemical responses of the diatom Skeletonema costatum grown under elevated CO2 concentrations to short-term changes in pH

Variability in pH is a common occurrence in many aquatic environments, due to physical, chemical and biological processes. In coastal waters, lagoons, estuaries and inland waters, pH can change very rapidly (within seconds or hours) in addition to daily and seasonal changes. At the same time, progressive ocean acidification caused by anthropogenic CO2 emissions is superimposed on these spatial and temporal pH changes. Photosynthetic organisms are therefore unavoidably subject to significant pH variations at the cell surface. Whether this will affect their response to long-term ocean acidification is still unknown, nor is it known whether the short-term sensitivity to pH change is affected by the pCO2 to which the cells are acclimated. We posed the latter open question as our experimental hypothesis: Does acclimation to seawater acidification affect the response of phytoplankton to acute pH variations? The diatom Skeletonema costatum, commonly found in coastal and estuarine waters where short-term acute changes in pH frequently occur, was selected to test the hypothesis. Diatoms were grown at both 390 (pH 8.2, low CO2; LC) and 1000 (pH 7.9, high CO2; HC) µatm CO2 for at least 20 generations, and photosynthetic responses to short-term and acute changes in pH (between 8.2 and 7.6) were investigated. The effective quantum yield of LC-grown cells decreased by ca. 70% only when exposed to pH 7.6; this was not observed when exposed to pH 7.9 or 8.2. HC-grown cells did not show significant responses in any pH treatment. Non-photochemical quenching showed opposite trends. In general, our results indicate that while LC-grown cells are rather sensitive to acidification, HC-grown cells are relatively unresponsive in terms of photochemical performance.

High resolution isotope and Mg/Ca record of sediment core GeoB12615-4

The importance of intermediate water masses in climate change and ocean circulation has been emphasized recently. In particular, Southern Ocean Intermediate Waters (SOIW), such as Antarctic Intermediate Water and Subantarctic Mode Water, are thought to have acted as active interhemispheric transmitter of climate anomalies. Here we reconstruct changes in SOIW signature and spatial and temporal evolution based on a 40 kyr time series of oxygen and carbon isotopes as well as planktic Mg/Ca based thermometry from Site GeoB12615-4 in the western Indian Ocean. Our data suggest that SOIW transmitted Antarctic temperature trends to the equatorial Indian Ocean via the "oceanic tunnel" mechanism. Moreover, our results reveal that deglacial SOIW carried a signature of aged Southern Ocean deep water. We find no evidence of increased formation of intermediate waters during the deglaciation.

Surface temperature measurements near Ny-Ålesund, Svalbard, Norway in 2008 with links to data files

The ground surface temperature is one of the key parameters that determine the thermal regime of permafrost soils in arctic regions. Due to remoteness of most permafrost areas, monitoring of the land surface temperature (LST) through remote sensing is desirable. However, suitable satellite platforms such as MODIS provide spatial resolutions, that cannot resolve the considerable small-scale heterogeneity of the surface conditions characteristic for many permafrost areas. This study investigates the spatial variability of summer surface temperatures of high-arctic tundra on Svalbard, Norway. A thermal imaging system mounted on a mast facilitates continuous monitoring of approximately 100 x 100 m of tundra with a wide variability of different surface covers and soil moisture conditions over the entire summer season from the snow melt until fall. The net radiation is found to be a control parameter for the differences in surface temperature between wet and dry areas. Under clear-sky conditions in July, the differences in surface temperature between wet and dry areas reach up to 10K. The spatial differences reduce strongly in weekly averages of the surface temperature, which are relevant for the soil temperature evolution of deeper layers. Nevertheless, a considerable variability remains, with maximum differences between wet and dry areas of 3 to 4K. Furthermore, the pattern of snow patches and snow-free areas during snow melt in July causes even greater differences of more than 10K in the weekly averages. Towards the end of the summer season, the differences in surface temperature gradually diminish. Due to the pronounced spatial variability in July, the accumulated degree-day totals of the snow-free period can differ by more than 60% throughout the study area. The terrestrial observations from the thermal imaging system are compared to measurements of the land surface temperature from the MODIS sensor. During periods with frequent clear-sky conditions and thus a high density of satellite data, weekly averages calculated from the thermal imaging system and from MODIS LST agree within less than 2K. Larger deviations occur when prolonged cloudy periods prevent satellite measurements. Futhermore, the employed MODIS L2 LST data set contains a number of strongly biased measurements, which suggest an admixing of cloud top temperatures. We conclude that a reliable gap filling procedure to moderate the impact of prolonged cloudy periods would be of high value for a future LST-based permafrost monitoring scheme. The occurrence of sustained subpixel variability of the summer surface temperature is a complicating factor, whose impact needs to be assessed further in conjunction with other spatially variable parameters such as the snow cover and soil properties.

Water balance measurements on Samoylov Island during campaign Lena2011

The summer water balance of a typical Siberian polygonal tundra catchment is investigated in order to identify the spatial and temporal dynamics of its main hydrological processes. The results show that, besides precipitation and evapotranspiration, lateral flow considerably influences the site-specific hydrological conditions. The prominent microtopography of the polygonal tundra strongly controls lateral flow and storage behaviour of the investigated catchment. Intact rims of low-centred polygons build hydrological barriers, which release storage water later in summer than polygons with degraded rims and troughs above degraded ice wedges. The barrier function of rims is strongly controlled by soil thaw, which opens new subsurface flow paths and increases subsurface hydrological connectivity. Therefore, soil thaw dynamics determine the magnitude and timing of subsurface outflow and the redistribution of storage within the catchment. Hydraulic conductivities in the elevated polygonal rims sharply decrease with the transition from organic to mineral layers. This interface causes a rapid shallow subsurface drainage of rainwater towards the depressed polygon centres and troughs. The re-release of storage water from the centres through deeper and less conductive layers helps maintain a high water table in the surface drainage network of troughs throughout the summer.

Dissolved organic carbon investigations from the Kara Sea

Based on observations during four scientific expeditions to the Kara Sea and the Siberian rivers Ob and Yenisei we determined the discharge, distribution and characteristics of dissolved organic matter (DOM). Surface concentrations of dissolved organic carbon (DOC) ranged from 151 IlM C in the northern Kara Sea to 939 IlM C in the river Ob. The estimated annual mean DOC concentration in the Yenisei (681 IlM C) was slightly higher than in the Ob (640 IlM C). Dissolved organic nitrogen (DON) concentrations typically varied between 5 and 15 IlM N with higher values in the rivers. Freshwater discharge and DOC concentrations experienced pronounced seasonal variations strongly affecting the spatial and temporal distribution of DOM in the Kara Sea. The largely conservative distribution of DOC and DON along the salinity gradient indicated the predominantly refractory character of riverine DOM. This observation was consistent with laboratory experiments, which showed only minor losses due to flocculation processes and bacterial consumption. Optical properties and relatively high C/N ratios (19 to 51) of DO M suggest that a large fraction of river DOM is of terrestrial origin and that phytoplankton contributed little to DOM on the Kara Sea shelf during the sampling periods. Together, the rivers Ob and Yenisei discharge about 8 Tg DOC yr- I into the Kara Sea. Due to the absence of efficient removal mechanisms in these estuaries the majority of riverine DOM appears to pass the estuarine mixing zone and is transported towards the Arctic Ocean.

Drought risk assessment as changes in the potential stand yield classes and potential forest production for Sitka spruce, Scots pine, and pedunculate oak over the next 80 years in the Great Britain

Probabilistic climate data have become available for the first time through the UK Climate Projections 2009, so that the risk of tree growth change can be quantified. We assess the drought risk spatially and temporally using drought probabilities and tree species vulnerabilities across Britain. We assessed the drought impact on the potential yield class of three major tree species (Picea sitchensis, Pinus sylvestris, and Quercus robur) which presently cover around 59% (400,700 ha) of state-managed forests, across lowland and upland sites. Here we show that drought impacts result mostly in reduced tree growth over the next 80 years when using b1, a1b and a1fi IPCC emissions scenarios. We found a maximum reduction of 94% but also a maximum increase of 56% in potential stand yield class in the 2080s from the baseline climate (1961-1990). Furthermore, potential production over the national forest estate for all three species in the 2080s may decrease due to drought by 42% in the lowlands and 32% in the uplands in comparison to the baseline climate. Our results reveal that potential tree growth and forest production on the national forest estate in Britain is likely to reduce, and indicate where and when adaptation measures are required. Moreover, this paper demonstrates the value of probabilistic climate projections for an important economic and environmental sector.