925 resultados para riduzione selettiva della furfurale sintesi di alcol furfurilico catalizzatori a base di CaO e CaCO3 metanolo come fonte di idrogeno reazione di Hydrogen Transfer


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A model for describing hybrid spectroscopy similar to the diquark model for baryons is presented. Mass and r.m.s. radii are calculated and compared with experimental results.

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Podolsky's higher-order field equations are obtained by generalizing the laws of Podolsky's electrostatics, which follow from Coulomb's generalized law and superposition, to be consistent with special relativity. In addition, it is necessary to take into account the independence of the observed charge of a particle on its speed. It is also shown that the gauge-independent term concerning the Feynman propagator for Podolsky's generalized electrodynamics has a good ultraviolet behaviour at the expense of a negative metric massive ghost which, contrary to what is currently assumed in the literature, is non-tachyonic. A brief discussion on Podolsky's characteristic length is presented as well.

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An analytical approximate method for the Dirac equation with confining power law scalar plus vector potentials, applicable to the problem of the relativistic quark confinement, is presented. The method consists in an improved version of a saddle-point variational approach and it is applied to the fundamental state of massless single quarks for some especial cases of physical interest. Our treatment emphasizes aspects such as the quantum-mechanical relativistic Virial theorem, the saddle-point character of the critical point of the expectation value of the total energy, as well as the Klein paradox and the behaviour of the saddle-point variational energies and wave functions.

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The anelastic relaxation (elastic energy loss and Young modulus) of nearly stoichiometric La2CuO4+delta with LTO structure was measured. Extraordinarily intense effects are present below room temperature in the elastic dynamic susceptibility, indicating relaxational dynamics of a relevant fraction of the lattice. The involved degrees of freedom are identified as rotations of the CuO6 octahedra. Two distinct processes are found at frequencies around 1 kKz: one is observed around 150 K and is characterized by a mean activation energy of 2800 K; the second one occurs below 30 K and is governed by atomic tunnelling. Two explanations are proposed for the faster process: i) formation of fluctuating LTT domains on a scale of few atomic cells; ii) the LTO phase is a dynamical Jahn-Teller phase with all the octahedra tunneling between two LTT-like tilts. In both cases there would be important implications regarding the mechanisms giving rise to charge nanophase separation and strong electron-phonon coupling.

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Applying the principle of analytic extension for generalized functions we derive causal propagators for algebraic non-covariant gauges. The so-generated manifestly causal gluon propagator in the light-cone gauge is used to evaluate two one-loop Feynman integrals which appear in the computation of the three-gluon vertex correction. The result is in agreement with that obtained through the usual prescriptions.

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Recently, the Hamilton-Jacobi formulation for first-order constrained systems has been developed. In such formalism the equations of motion are written as total differential equations in many variables. We generalize the Hamilton-Jacobi formulation for singular systems with second-order Lagrangians and apply this new formulation to Podolsky electrodynamics, comparing with the results obtained through Dirac's method.

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The recipe used to compute the symmetric energy-momentum tensor in the framework of ordinary field theory bears little resemblance to that used in the context of general relativity, if any. We show that if one stal ts fi om the field equations instead of the Lagrangian density, one obtains a unified algorithm for computing the symmetric energy-momentum tensor in the sense that it can be used for both usual field theory and general relativity.

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A spectrum-generating q-algebra, within the framework of SUq(2), as firstly suggested by Iachello, is studied in order to describe the mass spectrum of three generations of quarks and leptons. The SUq(2) quantum group is a q-deformed extension of SU(2), where q = e(alpha) (with alpha real) is the deformation parameter. In this work, the essential use of inequivalent representations of SUq(2) is introduced. The inequivalent representations are labelled by (j, nu(0)), where j = 0, 1/2, 1, ... and nu(0) is a positive real number. A formula for the fermion masses M-m(j, nu(0)), with -j less than or equal to m less than or equal to j is derived. As an example, a possible scheme which corresponds to two triplets (j = 1) associated to up and down quarks is presented here in some detail. They are associated to different values of the deformation parameter, indicating a dependence of the charge Q on the parameter alpha. The masses of the charged leptons are treated in a similar way. The current results show that some mass relations for quarks and leptons found in the literature can be considered as approximations of the equations obtained in the j = 1 representations. The breaking of SUq(2) necessary to describe the Cabibbo-Kobayashi-Maskawa (CKM) flavor mixing is briefly discussed.

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A manifestly covariant treatment of the free quantum eletromagnetic field, in a linear covariant gauge, is implemented employing Schwinger's variational principle and the B-field formalism. It is also discussed the Abelian Proca model as an example of a system without constraints. © Società Italiana di Fisica.

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Pós-graduação em Direito - FCHS