土壤保肥-供肥机理及其调节Ⅰ.棕壤型菜园土的P素保持与供应

对辽宁省北部、中部及南部的棕壤型菜园土１５对肥、瘦地的保Ｐ供Ｐ性能的测定表明，在绝大多数供试土样中，肥地及其各粒级微团聚体的全Ｐ量、Ｐ解吸量及Ｐ解吸率均大于瘦地及其各相应粒级微团聚体的，Ｐ吸附量则相反．不论肥地或瘦地，＜１０μｍ微团聚体均比＞１０μｍ微团聚体具有更大的Ｐ吸附能力．供试菜园土的＜１０μｍ微团聚体亦具有较大的供Ｐ潜势，其Ｐ解吸率比其他农用土壤相同粒级微团聚体的大１个数量级．

易旱地区褐土P、Zn形态转化特点及其与持续农业的关系

采用田间微区试验和分级提取测定的方法研究了褐土中Ｐ、Ｚｎ形态转化问题．发现褐土中Ｃａ２－Ｐ和Ｃａ８－Ｐ是转化最活跃的Ｐ素形态．而且Ｃａ８－Ｐ的流通容量很大，可超过作物需Ｐ量９倍以上；在Ｚｎ的各种形态中转化最活跃的是ＥＸ－Ｚｎ和ＣＡＲＢ－Ｚｎ，其中ＣＡＲＢ－Ｚｎ的流通容量亦很大，可超过作物需Ｚｎ量１９倍以上．Ｃａ８－Ｐ库和ＣＡＲＢ－Ｚｎ库形成了褐土中调控Ｐ、Ｚｎ养分供蓄以适应旱地水分波动的主要机构．合理施肥和培肥土壤以丰富Ｃａ８－Ｐ和ＣＡＲＢ－Ｚｎ库将有利于增强作物抵御干旱能力，提高水分养分利用效率，促使旱地农业持续向高产优质高效方向发展．

杂种樱桃(P.avium×P.pseudocerasus)叶片离体再生体系的建立

以先锋与对樱桃的种间杂交种F8的组培苗为试材进行离体再生,研究建立了F8叶片再生体系,以WPM为基本培养基,附加6-BA及IAA的培养基芽再生效果最好,在1~7 mg/L 6-BA、0.5~3.0 mg/L IAA的浓度组合中,离体叶片均可以再生。其中3.0 mg/L 6-BA+2.0 mg/L IAA组合叶片离体再生效果最好,再生频率可达90%,叶片平均再生芽数可达5.22个。

P(AA-DAC)两性聚电解质水凝胶的合成及性质

以丙烯酸(AA)和丙烯酰氧乙基三甲基氯化铵(DAC)为单体,采用水溶液聚合法制备了P(AA-DAC)聚电解质水凝胶.采用红外光谱和核磁共振等方法对其结构进行了表征.研究了不同组成比的聚电解质水凝胶在去离子水、不同pH值溶液以及不同离子强度盐溶液中的溶胀行为

Two novel triphenylamine-substituted poly(p-phenylenevinylene) derivatives: synthesis, photo- and electroluminescent properties

Two novel triphenylamine-substituted poly(p-phenylenevinylene) derivatives, P1 and P2, have been successfully synthesized through the Witting-Horner reaction. The structures and properties of the monomers and the resulting polymers were characterized by using H-1 NMR, FT-IR, GPC, TGA, UV-vis absorption spectroscopy, cyclic voltammetry (CV) and electroluminescence (EL) spectroscopy

Guest inducing p-sulfonatocalix[4] arene into three-dimensional capsule architecture and a mixed A-B double layer framework

The reactions of sodium p-sulfonatocalix[4]arene (Na5L) and terbium/europium(III) chloride in the presence of pyrazine-N,N'-dioxide (PNNO) in aqueous solutions gave the crystalline complexes 1 and 2. Both structures contain molecular capsules of p-sulfonatocalix[4] arene with PNNO as guest molecules in the cavity of the calix[4]arenes. The molecular capsules are connected through sodium and terbium (or europium) centers forming a three-dimensional framework.

Constructing channel structures based on the assembly of p-sulfonatocalix[4]arene nanocapsules and [M(bpdo)(3)](2+)(M = Cu, Zn)

Novel channel structures based on [M(bpdo)(3)](2+) and p-sulfonatocalix[4]arene nanocapsules have been established; these are sustained exclusively by charge-assisted pi...pi interactions and sorption experiments show the porous materials have selective guest sorption properties.

Self-assembly of p-sulfonatocalix[4]arene and a Ag-hmt coordination polymer into a porous structure

A novel porous material constructed from p-sulfonatocalix[4]arene molecules and a Ag-I coordination polymer has been structurally characterized. The porous supramolecular complex features a bilayer arrangement of p-sulfonatocalix[4]arene molecules linked by a Ag-I-hmt (hmt: hexamethylene- tetramine) coordination polymer through metal-ligand bonding, hydrogen bonding and host-guest interactions.

Molecular weight dependence of phase Behavior of PEO/P(EO-b-DMS) blends: Application of Sanchez-Lacombe lattice fluid theory

Molecular weight dependence of phase separation behavior of the Poly (ethylene oxide) (PEO)/Poly(ethylene oxide-block-dimethylsiloxane) (P(EO-b-DMS)) blends was investigated by both experimental and theoretical methods. The cloud point curves of PEO/P(EO-b-DMS) blends were obtained by turbidity method. Based on Sanchez-Lacombe lattice fluid theory (SLLFT), the adjustable parameter, epsilon*(12)/k (quantifying the interaction energy between different components), was evaluated by fitting the experimental data in phase diagrams. To calculate the spinodals, binodals, and the volume changes of mixing for these blends, three modified combining rules of the scaling parameters for the block copolymer were introduced.

p-p isotype organic heterojunction and ambipolar field-effect transistors

We realized ambipolar transport behavior in field-effect transistors by using p-p isotype heterojunction films as active layers, which consisted of two p-type semiconductor materials, 2, 2'; 7', 2 ''-terphenanthrenyl (Ph3) and vanadyl-phthalocyanine (VOPc). The ambipolar charge transport was attributed to the interfacial electronic structure of Ph3-VOPc isotype heterojunction, and electrons and holes were accumulated at both sides of the narrow band-gap VOPc and the wide band-gap Ph3, respectively, which were confirmed by the capacitance-voltage relationship of metal-oxide-semiconductor diodes. The accumulation thickness of carriers was also obtained by changing the heterojunction active layer thickness. Furthermore, the results indicate that the device performance is relative to interfacial electronic structures.

Preparation and Luminescence Properties of YVO4:Ln and Y(V, P)O-4:Ln (Ln = Eu3+, Sm3+, Dy3+) Nanofibers and Microbelts by Sol-Gel/Electrospinning Process

One-dimensional YVO4:Ln and Y(V, P)O-4:Ln nanofibers and quasi-one-dimensional YVO4:Ln microbelts (Ln = Eu3+, Sm3+, Dy3+) have been prepared by a combination method of sol-gel process and electrospinning. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric and differential thermal analysis (TG-DTA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), photoluminescence (PL), low-voltage cathodoluminescence (CL), and time-resolved emission spectra as well as kinetic decays were used to characterize the resulting samples.