976 resultados para computational chemistry


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An extensive range of conventional, vane-type, passive vortex generators (VGs) are in use for successful applications of flow separation control. In most cases, the VG height is designed with the same thickness as the local boundary layer at the VG position. However, in some applications, these conventional VGs may produce excess residual drag. The so-called low-profile VGs can reduce the parasitic drag associated to this kind of passive control devices. As suggested by many authors, low-profile VGs can provide enough momentum transfer over a region several times their own height for effective flow-separation control with much lower drag. The main objective of this work is to study the variation of the path and the development of the primary vortex generated by a rectangular VG mounted on a flat plate with five different device heights h = delta, h(1) = 0.8 delta, h(2) = 0.6 delta, h(3) = 0.4 delta and h(4) = 0.2 delta, where delta is the local boundary layer thickness. For this purpose, computational simulations have been carried out at Reynolds number Re = 1350 based on the height of the conventional VG h = 0.25m with the angle of attack of the vane to the oncoming flow beta = 18.5 degrees. The results show that the VG scaling significantly affects the vortex trajectory and the peak vorticity generated by the primary vortex.

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The elemental composition of otoliths may provide valuable information for establishing connectivity between fish nursery grounds and adult fish populations. Concentrations of Rb, Mg, Ca, Mn, Sr, Na, K, Sr, Pb, and Ba were determined by using solution-based inductively coupled plasma mass spectrometry in otoliths of young-of-the year tautog (Tautoga onitis) captured in nursery areas along the Rhode Island coast during two consecutive years. Stable oxygen (δ18O) and carbon (δ13C) isotopic ratios in young-of-the year otoliths were also analyzed with isotope ratio mass spectrometry. Chemical signatures differed significantly among the distinct nurseries within Narragansett Bay and the coastal ponds across years. Significant differences were also observed within nurseries from year to year. Classification accuracy to each of the five tautog nursery areas ranged from 85% to 92% across years. Because accurate classification of juvenile tautog nursery sites was achieved, otolith chemistry can potentially be used as a natural habitat tag.

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We examined the potential for water chemistry to affect the width of daily increments in reef fish otoliths using both mensurative and manipulative methods. We found significant differences in the widths of increments in otoliths of the neon damselfish (Pomacentrus coelestis) collected in different habitats at One Tree Island on the Great Barrier Reef. We then used manipulative experiments to determine if natural water masses (ocean water vs. lagoon plume) could produce different incremental widths in otoliths in the absence of potentially confounding factors. Fish exposed to ocean water had significantly wider otolith increments for two of the three experiments. Elemental analyses indicated that Ba/Ca ratios were significantly correlated with increment widths for two of the three experiments and Sr/Ca ratios did not correlate with increment width for any experimental period. Variation in crystal-lattice orientation did not explain differences in increment width between treatments. Differences in water chemistry can affect increment widths in otoliths of reef fishes, potentially confounding patterns previously attributed to growth rate or condition alone.