Deposição e caracterização de filmes de óxido de cobalto por sputtering reativo

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Sistema de gestão ambiental: subsídios para a implantação em uma estação de tratamento de esgoto a partir da análise crítica de estudos ambientais prévios

The process of environmental impact assessment (EIA), in the extent of previous environmental studies, has as one of its functions to provide subsidies to the actions of environmental managment of enterprises. However, the proper estructuring of programs that allows to support this managment does not often occurs. This research sought as one of its objectives to evaluate in which extent the process of EIA can be a subsidie for the EMS, providing basic elements of this system. In addition, more specifically, the research had as one of its objetives the development of subsidies for the implantation of an Environmental Managment System (EMS), based on the model of ISO 14001 (2004), for a sewage treatment plant yet to be constructed in the city of President Venceslau / SP. In order to achieve theses objetives, a discussion was held based on the evaluation of environmental studies available in the library of Cetesb / SMA. Still, for the elaboration of subsidies for the EMS of the treatment plant, the research was focused on the structuring of environmental management program, based on the information contained in its Preliminary Environmental Report (PER). The research had as one of its products, the development of subsidies for the planning and control of the environmental aspects and impacts and for the environmental program of the enterprise, based on the use of environmental indicators. It was concluded, based on the results that, in general, the previous environmental studies analyzed showed little emphasis on the phase of development of structured environmental programs that offer guidelines to achieve the desired results for the environmental performance of the company.

Proposta metodológica para a correção do coeficiente de retorno de esgoto sanitário em unidades com sistemas de aproveitamento de água pluvial

The use of rainwater for non-potable purposes generates a reduction in the consumption of treated water, however, this reduction is not observed in the generation of wastewater, as this is independent of the water source. In Brazil, the pricing on the services of collection and treatment of sewage, in general, is based on the coefficient of return of the sewage disposal system, which has a relation sewer / water proportional to the consumption of treated water measured at the consumer unit. The use of rainwater originating from utilization systems infer on the coefficient, underestimating the volume of wastewater generated. Therefore, this study presents a methodology for setting the coefficient of return. Different roof areas, reservoir volumes and rates of water consumption situations were simulated. The behavior of adjustment of the coefficient of return were also analyzed for the average area per capita roof (m² / inhabitant) of Rio Claro - SP. As a result, it can be seen that the adjustment of the coefficient of return is directly proportional to the increase of the roof areas and the volumes of reservoirs, and inversely proportional to the total water demand. The corrected coefficient of return showed the minimum value of 0.83 and a maximum value of 1.45, this variation corresponds to the maximum ratio between the demands of total water and rainwater, since the exploitation of rain water should be used only for non-potable uses, according to NBR 15527 / 07. To the municipality of Rio Claro - SP was noted an adjustment of the coefficient of return ranging from 0.99 to 6.61

Precificação do biogás produzido por autoprodutores, considerando seu transporte por meio de gasodutos existentes

The expansion of the energy matrix is a matter of great importance since the recent problems facing the country in this sector, such as rationing mobilized in 2001. Moreover, there is also concern with global sustainable development. Brazil is producing about 64 million cubic meters of biogas per day, but only a small percentage of this total is harnessed as an energy resource. Compounders are considered potential, for example, landfill energy (LE) and sewage treatment plants (STP), which can be adapted to produce biogas and market them. The work focuses its studies on biogas produced by these small and medium compounders. Are proposed and studied the following alternatives for the utilization of biogas energy: generation and sale of electricity through the installation of a small power station within the landfill, and purification and marketing of gas, whose price will be a consideration on the price of natural gas, taking into account the percentage of methane present in the biogas. Trade ensures that gas plus a destination ecologically appropriate to it, taking advantage of its energy

Instrumentação eletrônica para experimentação do modelo Bouncer Ball dissipativo

In our experiments, we studied the classical dynamic of a particle in vertical motion subject to a constant gravitational field and the partial shock with an elastic wall with oscillatory motion located below the particle. The motion of the particle was confined to the vertical direction by a glass guide tube, which was initially evacuated, allowing viscous drag forces to be disregarded. The time between impacts, as well as the time between the reference phase of the movement of the base and the moment of impact and the period of oscillation of the base will be acquired by a hardware and software to obtain the phases space to be compared later with the description of the system through mapping discrete variables via the 'particle velocity immediately after shock 'and' phase of the movement of the base at the instant of shock 'obtained by computer simulation. This requires developing an electronic analog system followed by Digital implemented in reconfigurable logic, more specifically a sequential machine able to discriminate the impact with the metal base from the impacts of the glass guide tube, based on the frequency spectrum of the response of the microphone to these different impacts

Otimização da estrutura metalica para um carro alegórico

Carnival is a unique opportunity for the associations demonstrate the community’s annual work and the float is a major component of this celebration, responsible for pitch the samba using allegories and carry important figures. The excess weight of the floats which are mostly manufactured from truck and bus structures requires larger amount of people to push the vehicle in addition to increased efforts on the steering systems, suspension and wheels, raising the probability of breakage and loss of one year work. The objective of this study is to use the concepts of strength of materials combined with computer simulation to obtain a structure that has the lowest possible weight without compromising the safety of transported components and that is also easy to manufacture, drive and store

Aproveitamento energético de resíduos de esgotamento sanitário

This paper presents alternatives for waste energy recovery from the sewage of cities. Through a review of the literature it is observed that the technologies studied are usually turbines, microturbines, and engines adapted to the use of biogas. For project design analyzes the technologies found in some sewage treatment plants in Brazil and the world, compared with those found in the literature. With this study it can be concluded that the most used technologies are microturbines and motor generator sets, which are already implemented in some locations in the USA, Europe and even Brazil. It can also be concluded that the energy recovery of waste from sewage can enable design of wastewater treatment plants thereby contributing to improved quality of life

Aplicação de métodos computacionais no estudo das fases intermetálicas ordenadas pt-sn

Fuel cells are a very promising solution to the problems of power generation and emission of pollutant to the environment, excellent to be used in stationary application and mobile application too. The high cost of production of these devices, mainly due to the use of noble metals as anode, is a major obstacle to massive production and deployment of this technology, however the use of intermetallic phases of platinum combined with other metals less noble has been evaluated as electrodes in order to minimize production costs and still being able to significantly improve the catalytic performance of the anode. The study of intermetallic phases, exclusively done by experimental techniques is not complete and demand that other methods need to be applied to a deeper understanding of the behavior geometric properties and the electronic structure of the material, to this end the use of computer simulation methods, which have proved appropriate for a broader understanding of the geometric and electronic properties of the materials involved, so far not so well understood.. The use of computational methods provides answers to explain the behavior of the materials and allows assessing whether the intermetallic may be a good electrode. In this research project was used the Quantum-ESPRESSO package, based on the DFT theory, which provides the self-consistent field calculations with great precision, calculations of the periodic systems interatomic force, and other post-processing calculations that points to a knowledge of the geometric and electronic properties of materials, which may be related to other properties of them, even the electrocatalytic. The electronic structure is determined from the optimized geometric structure of materials by analyzing the density of states (DOS) projected onto atomic orbital, which determines the influence of the electrocatalytic properties of the material... (Complete abstract click electronic access below)

Modelagem e Simulação Computacional das propriedades estruturais, eletrônicas e constantes elásticas do ZnO

The electronic, structural properties and elastic constants of the wurtzite phase of zinc oxide, ZnO, was investigated using computer simulation at Density Functional Theory level, with B3LYP hybrid functional and Hartree-Fock methodology. The electronic properties as well the band energy was investigated through the analysis of the band structures and density of states (DOS), and the mechanical properties was studied through the calculus of the elastic constants C11, C33, C44, C12 e C13. The results are in good agreement with experimental data found in the literature and in accordance with results obtained by another theoretical methodology

Propostas de Adequação Ambiental para a Cidade da Criança de Presidente Prudente - SP

The environmental issue has been considered of fundamental importance for the well being of the present and future generations and is inserted into the commitment of political parties at federal, state and municipal government programs, into the interests of popular organizations and business planning. The Parque Ecológico Cidade da Criança is one of the most sought after places for visitation at Presidente Prudente – SP. Located outside the Raposo Tavares Highway, next to the exhibition grounds and beside the agricultural school, has more than 30 acres of area with an infrastructure designed for recreation and leisure activities for all ages and has received new investment of the public power. Given the importance of the ecological aspects, the objective of this work is to perform an environmental diagnosis in order to be able to submit proposals for solving the problems encountered and improve the use of the environmental resources. Therefore, the study was divided into three foci: sewage disposal, erosion process and control of the stormwater drainage system. It was checked the discharge of sewage from the restaurant on exposed soil, erosion processes that develop at the camel and llama cages ground and erosion processes resulting from the convergence of the stormwater in the highest region of the park. Based on these studies, proposals of solution were made for each case, having considered the effectiveness of the project

Variação espacial e temporal da qualidade da água de três córregos tributários do Rio Bauru: respostas ao processo de recuperação de nascentes

Este trabalho objetivou analisar a qualidade da água de três córregos tributários do rio Bauru, levando em conta a poluição causada por produtos orgânicos e industriais que vinham sendo descartados nos mesmos e as eventuais melhorias conseqüentes das medidas paliativas assumidas pelo DAE-Bauru, mediante a instalação de interceptores-coletores de águas residuárias ao longo Daqueles corpos de água, até que a Estação de Tratamento de Esgotos do município seja construída e se dê início ao seu funcionamento. O monitoramento destes corpos de água durante o período de estiagem e de cheias proposto nesta pesquisa, incluiu investigações sobre as variáveis químicas e físicas de amostras das águas, obtidas mensalmente em 7 pontos de coleta, localizados a montante e a jusante dos pontos de instalação dos emissários, ao longo dos córregos. As amostras de água foram posteriormente analisadas para fossem obtidas informações sobre a eficácia da instalação dos interceptores com relação ao processo de recuperação da saúde dos corpos aquáticos em questão. Os resultados obtidos mostraram que, de um modo geral, as águas de todos os sistemas estudados ainda sofrem impactos, até porque ainda há aquelas que recebem o esgoto descartado “in natura”. No entanto, como ja era esperado, nos pontos de coleta localizados em segmentos dos córregos nos quais os emissários já foram instalados, o impacto ambiental é menor. Mediante a comparação dos resultados obtidos das análises das características físicas e químicas das águas dos sistemas estudados realizadas durante esta investigação com aqueles obtidos nos mesmos corpos de água, em 2007, pudemos observar melhorias da água em alguns dos pontos de coleta

Avaliação da auto-suficiência energética de reatores anaeróbios no tratamento de esgoto sanitário e de água preta

The purpose of this project is to verify whether anaerobic reactors applied to sewage treatment are energetically self-sufficient. This evaluation can be made by balancing the methane produced through the anaerobic transformation stages (hydrolysis, acidogenesis, acetogenesis and methanogenesis) and the reactor energy consumption requirements. The original project included methanogenic activity tests, which could not be performed due to setbacks in the installation of an analytical instrument. Scientific articles about bench- and full-scale anaerobic reactors were investigated instead. An average substrate-to-methane conversion efficiency of 58,2±18,6% was found for the bench-scale reactors and higher efficiencies (89,2%) were found for the cases which had higher Organic Loading Rates (OLRs) values. The average energy output was 0,013 kWh/Lsewage, value unable to meet the energy needs for the reactor operation, considering equipments normally used such as temperature controller. This balance can become positive if few hypotheses are made, for example (i) to eliminate the use of temperature controller (ii) to alter the operation pattern from continuous to intermittent. Based on energy balance assessment of eight bench-scale reactors, it was observed that the implementation of a system for biogas utilization is not energetically feasible. However, interesting results were found for a full-scale sewage treatment plant, ETE Ouro Verde – Foz do Iguaçu, PR, Brazil. Even though its substrate-tomethane conversion efficiency was about 10% only, the energy balance was quite positive, with energy consumption of 68 kWh/month and energy production of 660 kWh/month. This analysis leads us to conclude that energy recovery from full-scale sewage treatment plants should be practiced by other plants

Caracterização química e estudo térmico de lodos provenientes da estação de tratamento de esgotos de Ribeirão Preto, SP, Brasil

Pós-graduação em Química - IQ

Utilização de resíduos de tratamento de esgoto como suprimento hídrico e nutricional na cultura do girassol

Pós-graduação em Agronomia (Irrigação e Drenagem) - FCA