Determinação de As em amostras orgânicas de interesse ambiental por espectrometria de absorção atômica com atomização eletrotérmica após combustão em bomba de O2

The toxicity of the major As species present in the environment justifies the effort for quantifying the element in environmental organic samples, which can vary from animal and vegetal tissues to coal and industrial residues. This paper comments about the applicability of the O2 bomb digestion, as a general procedure for all environmental organic materials. A rapid and straightforward method is suggested, which consists in burning the sample in the bomb at high O2 pressure, dissolving the vapours in diluted HNO3 and determining As in the resulting solution by atomic absorption spectrometry with electrothermal atomization. The method was applied to certified materials and plant samples.

Contaminação ambiental por compostos organoestânicos

The occurrence and the effects of organotin compounds (OTs) have been studied since a long time, due to their widespread use and deleterious effects. Some OTs are used as pesticides in crops, or as biocides in antifouling paints, applied in the ship hulls to avoid attachment and growth of tube worms, mussels and barnacles. However, "nontarget" organisms may be exposed, resulting in the poisoning of biological system, originating mutations and sentencing species to extinction. In this work we reported a revision study on the history of OTs and the techniques developed for its assessment and control.

Com ha de ser l'economia del coneixement?

Catalunya ha apostat per una política de recerca que cada dia aconsegueix bons resultats. Aquesta setmana s'ha fet públic que 14 investigadors que treballen en centres i universitats catalanes han rebut les prestigioses 'Starting Grants de l'European Research Council'. El resultat és destacable si es considera que tot l'Estat espanyol, amb Catalunya, n'ha rebut 29. Catalunya està per sobre de Dinamarca, Àustria, Finlàndia, Noruega, Portugal, Irlanda, Grècia, Hongria, Turquia, Polònia i Eslovàquia

Israel és un bon exemple de l'economia del coneixement

Antoni Castellà, secretari d'Universitats i Recerca, deia que en aquests moments a Israel el 25% del PIB són noves empreses sorgides de l'àmbit científic i que cal fer una aliança amb Israel per seguir el seu camí i veure com podem aprendre d'ells per fer el mateix salt tecnològic en els propers anys

Inserção do conceito de economia atômica no programa de uma disciplina de química orgânica experimental

In this paper, the atom economy concepts are applied in a series of experiments during an experimental organic chemistry class, to implement "green chemistry" in an undergraduate course.

Algas: da economia nos ambientes aquáticos à bioremediação e à química analítica

Algae constitute a large group of many different organisms, essentially aquatic and able to live in all systems giving them sufficient light and humidity. Some algae species have been used in the evaluation or in the bioremediation of aquatic systems. More recently algae have been suggested as interesting tools in the field of analytical chemistry. In this work the most important aspects related to the different uses of algae are presented with a brief discussion.

Educação ambiental na universidade: construindo possibilidades

Environmental education is a big challenge in this century and the University has an important role to play in it. This paper presents a practical experience of environmental education in the university teaching at the University of Bahia. That experience involves the creation of an interdisciplinary group that has been developing research and teaching activities with interdisciplinary perspectives. The paper also discusses a methodology proposed by this group aiming to include environmental education in science teaching using social and cultural approaches.

Estudio multidisciplinario del ecosistema manglar en la comunidad tradicional de Curral Velho : Estudio sobre la pesca artesanal y análisis de sus diferencias con la acuicultura del camarón

Curral Velho es una comunitat tradicional, situada al nord-est de Brasil, que manté una relació directa amb els ecosistemes que la envolten. La comunitat depèn del estat de conservació del medi natura, ja que obtenen diferents serveis ecositemics. En aquest territori es desenvolupen dos tipus d’economies amb unes bases molt diferents. Una economia tradicional, desenvolupada per la pròpia comunitat, que es basa en la propietat col·lectiva del territori i en optimitzar a llarg termini els beneficis que s’obtenen del medi; y un altre com la camaronicultura, la base de la qual es la obtenció de beneficis a curt termini i amb un territori de propietat privada. Aquesta superposició de models de producció genera impactes ambientals, i un conflicte socio-ambiental entre la comunitat i els que desenvolupen la camaronicultura. L’objectiu es realitzar un estudi econòmic de la pesca artesanal de Curral Velho caracteritzant manera de viure, creant una base de dades sobre pesca artesanal i elaborant indicador de beneficis econòmics generats per la pesca artesanal. Per contextualitzar els resultats es va fer un anàlisis de les dos economies existents a la comunitat. Els resultats obtinguts en primer lloc són que l’economia d’explotació intensiva aporta més guanys per les persones de la comunitat que tenen un relació directa que les que es dediquen a la pesca artesanal, però es important no aturar-se aquí: s’ha de realitzar un anàlisis més profund. Com a conclusió, la activitat pesquera es més rentable a llarg termini ja que els recursos extrets de manera sostenible i així són il·limitats y accessibles a tota la comunitat. A diferència de la camaronicultura, la pesca artesanal no genera desigualtats socials ni vulneracions dels drets humans. Tot el contrari, genera forts vincles entre els individus de la comunitat basats en el treball en equip i l’aprenentatge vivencial e intergeneracional.

Interpretación ambiental de INBioparque, La Finca (Costa Rica)

Este artículo es una síntesis del proyecto realizado en INBio (Instituto Nacional de Biodiversidad), Costa Rica, cuyo objetivo principal fue la mejora de la Interpretación Ambiental de INBioparque, un parque temático de biodiversidad dentro de la institución. INBioparque está situado en Santo Domingo de Heredia, provincia de Heredia, Costa Rica. Éste pretende hacer una pequeña representación de los principales ecosistemas que se encuentran en el país. El parque se divide en diferentes zonas: Bosque del Valle Central, Bosque Húmedo, Bosque Seco, Humedal y Finca. En esta última, la Finca (ecosistema basado en la biodiversidad domesticada) es dónde se ha centrado todo el proyecto, debido a que presentaba una mayor necesidad de mejora en su interpretación ambiental. La Interpretación ambiental traduce el lenguaje técnico de los profesionales a términos e ideas más entendedoras para todos los públicos. Pretende promover una nueva conciencia sobre el valor de la biodiversidad, lograr su conservación y mejorar la calidad de vida del ser humano. El proyecto propone la mejora de la interpretación ambiental a través de las fichas técnicas elaboradas de las diferentes especies vegetales de la Finca, así como la renovación o creación de rótulos explicativos. Se propone también un recorrido guiado y auto guiado para hacer más entendedora la visita, además de algunas actividades y talleres.

Utilização de regressão multivariada para avaliação espectrofotométrica da demanda química de oxigênio em amostras de relevância ambiental

In this work, a partial least squares regression routine was used to develop a multivariate calibration model to predict the chemical oxygen demand (COD) in substrates of environmental relevance (paper effluents and landfill leachates) from UV-Vis spectral data. The calibration models permit the fast determination of the COD with typical relative errors lower by 10% with respect to the conventional methodology.

Impacto ambiental previsto en la explotación de gravas en la zona de concurso medio del riu Fluvià (Girona)

The main environmental impacts related to the gravel pits in the medium course of the Fluvià river have been assessed. In order to compute the global impact and index based on the numerical values of different impacts has been defined. This index is applied to different areas and the results reveal that the environmental impact expected for a gravel pit is high or moderate close to the main streams and low in the rest of the territory

La importància del pati escolar: com els patis escolars poden contribuir a l’educació ambiental

Article que reflexiona sobre la importància del pati escolar, i com aquests poden contribuir a l’educació ambiental dels infants

Diagnóstico ambiental de metais e organoclorados em córregos adjacentes a áreas de cultivo de cana-de-açúcar (Estado de São Paulo, Brasil)

Sugar cane cultivation in the State of São Paulo has expanded in the last years, with an annual production of 200•10(6) t in an area of 2.5• 10(6) hectares. The use of herbicides, pesticides and fertilizers in sugar cane plantations, together with deforestation of riparian vegetation, have caused impacts on the hydric resources of the adjacent areas. The aim of this work is to evaluate the influence of sugar cane plantations on streams in the central region of the State of São Paulo, studying 16 organochlorinated compounds and 7 metals (Cu, Fe, Cd, Zn, Mn, Cr and Ni) found in the sediments of 11 streams. The results show that there is a higher concentration of metals and organochlorinated compounds in streams without riparian vegetation when compared to forested areas.

Uso de lodo de estação de tratamento de água centrifugado em matriz de concreto de cimento portland para reduzir o impacto ambiental

An alternative application of the humid sludge from the Passaúna WTP, located in Curitiba's metropolitan area, is proposed for concrete structures, partially replacing aggregates and cement. For the investigation, a reference concrete and four concrete mixtures with sludge were produced, and from these, two mixtures, containing 4% and 8% of sludge (m/m), were analyzed by different techniques: X ray fluorescence, X ray diffraction, thermo-gravimetric analysis, physicochemical analysis, compressive strength, etc. The properties were evaluated and the results indicate that the mixtures can be applied in different situations as cast structures for construction of concrete walls. Mixtures with more than 4% of sludge are restricted to applications where the workability of the concrete is not required, such as for residential pavements, sidewalks and stepping floors.

Monitoramento atmosférico passivo de SO2, NO2 e O3 em áreas urbanas e de influência industrial como prática de química ambiental para alunos de graduação

This study is a result of undergraduate student participation in the Environmental Chemistry discipline provided by the Chemistry Institute/UFBA. The students were involved in the development of passive samplers, a project of the LAQUAM (Environmental Analytical Chemistry Laboratory). The students' residences and other neighborhoods were used to create a passive sampling network, allowing the measurement of atmospheric levels of pollutants in urban areas and in those under industrial influence. The assembly of the passive samplers, including impregnation of filters and chemical analysis were part of the students' practice tasks. The results were analyzed taking into consideration the Brazilian legislation.