A Comprehensive Discussion of HMBC Pulse Sequences: 4. Establishing Two-Bond Correlations from HMBC and Related Experiments

The utility of the HMBC experiment for structure elucidation is unquestionable, but the nature of the coupling pathways leading to correlations in an HMBC experiment creates the potential for misinterpretation. This misinterpretation potential is intimately linked to the size of the long-range heteronuclear couplings involved, and may become troublesome in those cases of a particularly strong 2JCH correlation that might be mistaken for a 3JCH correlation or a 4JCH correlation of appreciable strength that could be mistaken for a weaker 3JCH correlation. To address these potential avenues of confusion, work from several laboratories has been focused on the development of what might be considered “coupling pathway edited” long-range heteronuclear correlation experiments that are derived from or related to the HMBC experiment. The first example of an effort to address the problems associated with correlation path length was seen in the heteronucleus-detected XCORFE experiment described by Reynolds and co-workers that predated the development of the HMBC experiment. Proton-detected analogs of the HMBC experiment intended to differentiate 2JCH correlations from nJCH correlations where n = 3, 4, include the 2J,3J-HMBC, HMBC-RELAY, H2BC, edited-HMBC, and HAT H2BC experiments. The principles underlying the critical components of each of these experiments are discussed and experimental verification of the results that can be obtained using model compounds are shown. This contribution concludes with a brief discussion of the 1,1-ADEQUATE experiments that provide an alternative means of identifying adjacent protonated and non-protonated carbon correlations by exploiting 1JCC correlations at natural abundance.

Illusions of a ‘Bond’: Tagging cultural products across online platforms

La plupart des études sur l'étiquetage social porte sur une plateforme ou un type de plateforme précis, ce qui limite la portée de leurs résultats. Cette étude explore et compare les pratiques d'étiquetage social de quatre plateformes--Goodreads, un catalogue de bibliothèque publique, Last.fm et WordPress--au moyen d'une étude de cas multiples et emboîtés. Le contenu généré par les utilisateurs, principalement les étiquettes ou "tags", lié au livre Casino royale de Ian Fleming ou à ses produits dérivés ou associés (p. ex. : chanson thème, film, billet de blogue) a été analysé avec une approche qualitative et inductive. L'analyse révèle que le contenu généré par les utilisateurs des quatre plateformes mettait l'emphase sur les événements historiques associés au livre tout en fournissant de nombreux points d'accès plus subjectifs : recommandation, ton, ambiance, opinion, expérience de lecture, d'écoute ou de visionnement. On remarque par ailleurs des différences entre les étiquettes associées au livre et à ses produits dérivés : alors que le contenu généré par les utilisateurs en lien avec le produit d'origine dans les catalogues de bibliothèques et dans Goodreads portait essentiellement sur le livre, les étiquettes attribuées par les utilisateurs aux produits dérivés dans Last.fm (la chanson thème du film) et WordPress (des billets de blogues sur le livre ou le film) renvoyaient souvent à d'autres produits culturels, incluant des livres, de la musique et des films.

In-bond industry : legal and administrative resolutions /

Mode of access: Internet.

Sacramento and San Joaquin drainage district refunding act, Reclamation board act and Reclamation board bond act of the state of California, as in effect on and after July 29, 1927, with all amendments to and including those of 1927.

Mode of access: Internet.

Bond financing and transportation infrastructure: exploring concepts and roles.

Mode of access: Internet.

A bond of sympathy /

"Published in America under the title of Silver bells."

Bonds and the bond market /

Includes index.

An Argument against immediately repealing the laws which treat the nuptial bond as indissoluble /

Mode of access: Internet.

Notice of letting, Specifications, proposal, contract and bond for Susquehanna Water Supply Project, section no. 1, Montebello Raw Water Distribution Center.

"Addendum no. 1", 1958 (6 l.) inserted at end.

Invitation to tender, information for bidders contractor's proposal, contract, bond and specifications. Contract no. P. 1 -

"Bulletins" included in some nos.

Development of a plasticity bond model for reinforced concrete : theory and validation for monotonic applications /

Cover title.

Implementation of a bond model, including dilation, for reinforced materials in a finite element analysis /

Cover title.

Invitation to tender, information for bidders contractor's proposal, contract, bond and specifications. Contract no. 1 -

"Bulletins" included in some nos.

Invitation to tender, information for bidders contractor's proposal, contract, bond and specifications. Contract no. G. 1-

"Bulletins" included in some nos.

Q. Horatius Flacci Scholiis sive notis illustratus a Ioanne Bond.

Mode of access: Internet.