A mechanistic study of electrochemical oxidation processes of (OEP)Mg(II) in the presence of anions

In the presence of F-, OH-, Cl-, electrochemical redox of (OEP)Mg(II) [2,3, 7,8,12,13,17,18 octaethyl-21H, 23H-porphine magnesium (II)] are investigated in DCE/0.1 mol/L solution by cyclic voltammetry and spectroelectrochemistry, In the presence of anions, anions are axially coordinated to (OEP)Mg(II) generate (OEP)Mg(II)Y, the E-1/2 of (OEP)MS(II)Y oxidation are negatively shifted. A chemical reaction following the second oxidation step is observed, the E-1/2 of the reaction product is obtained. Mechanism of (OEP)Mg(II) in the halogen and OH- anions titration process has been proposed.

NMR titration and molecular model MOPAC calculation of protonation processes of two MRI ligands

The protonation process of two DTPA bis(amide) derivatives, DTPA-BDMA and DTPA-BDEA, was studied by using H-1 NMR titration and MOPAC calculation. Their protonation process was proposed in the order of the central amine, the terminal amines, the central carboxyl, the terminal carboxyl, the other terminal carboxyl and central amine. During the protonation of the terminal amine, there existed a large fraction of proton transfer from the central amine to the other terminal amine.

Enhanced redox processes of disulfides with partially N-methylated polyaniline

Partially N-methylated polyaniline (NMPAn) is used instead of polyaniline (PAn) to make a composite with organodisulfides for cathodes of lithium secondary batteries. NMPAn displays a better electrocatalytic effect on the redox processes of organodisulfides than PAn. (C) 1998 Elsevier Science S.A. All rights reserved.

THERMAL-DECOMPOSITION PROCESSES OF SOME ELECTRICALLY CONDUCTING POLYMERS INVESTIGATED BY DIRECT PYROLYSIS MASS-SPECTROMETRY

Thermal decomposition processes of poly(thio-1,4-phenylene) (PPS), polythiophene (PT) and polyaniline (PAn) were investigated by direct pyrolysis EI or CI mass spectrometry (DPMS). They can provide up to heptemer pyrolynates and give some structure properties. The results indicate that the thermal degradation all undergoes in radical decomposition, PPS pyrolyzes into linear and cyclic oligmers, but PT and PAn pyrolyze only into linear oligmers.

Thermal decomposition processes of polyaniline and poly-o-toluidine investigated by direct pyrolysis mass spectrometry

The thermal decomposition of polyaniline(PAn) and poly-o-toluidine(POT) was studied by means of direct pyrolysis mass spectrometry(DM) and MS/MS, The results showed that both benzene-diamine and quinone-diimine units were produced, and the intensities of fragments corresponding to quinone-diimine units increased as the oxidation degrees increased, The mechanism of thermal decomposition of PAn and POT was given for the first time.

ELECTROCHEMICAL AND IN-SITU SPECTROELECTROCHEMICAL STUDY OF (TETRAPHENYLPORPHINATO)MANGANESE(III) PERCHLORATE IN THE PRESENCE OF CHLORIDE ANIONS .2. OXIDATION PROCESSES

An investigation of electrode oxidation processes of (tetra-phenylporphinato) manganese (III) Perchlorate, (TPS)Mn(III)ClO4, was carried out during the titration of chloride anions by conventional cyclic voltammetry, thin-layer cyclic voltammetry and spectroelectrochemistry. It was demonstrated that in the presence of one equivalent amount of Cl-, the first one electron oxidation reaction corresponds to the Mn(III)I cation radical oxidation, and the second one electron oxidation corresponds to the cation radical/dication generation followed by an iso-porphyrin formation reaction, however in the presence of two equivalent amount of Cl-, the first one electron oxidation of Mn(III) gives Mn(IV) porphyrin and the second one electron oxidation generates cation radicals of Mn(IV) followed by an iso-porphyrin formation reactions. Mechanisms of these redox processes are postulated.

ELECTROCHEMICAL AND INSITU SPECTROELECTROCHEMICAL STUDY OF (TETRAPHENYLPORPHINATO)MANGANESE (III) PERCHLORATE IN THE PRESENCE OF CHLORIDE ANIONS .1. REDUCTION PROCESSES

The mechanism of electrochemical redox reactions of (tetra-phenylporphinato) managanese(III) perchlorate, (TPP)Mn(III)ClO4, was studied In the presence of chloride anions in dichloroethane solution. It was demonstrated that Mn(II) or Mn (III) centre can be coordinated with only one chloride anion, this result makes an about 100 mV negative shift of half-wave potential of Mn (III)/Mn (II) reduction. An equilibrium constant of 2.2 x 10(4) was determined for the complexation reaction of Cl- and Mn(III) centre.

MEASUREMENT AND CALCULATION OF SPONTANEOUS EMISSION BRANCHING RATIOS, RELATIVE OSCILLATOR-STRENGTHS, TRANSITION-PROBABILITIES AND LEVEL LIFETIMES FOR ATOMIC URANIUM

We propose a laser induced sensitized fluorescence spectrometry for measuring the spontaneous emission branching ratios o?the transitions from the ten levels 5f36d7s7p-7M7, 5f36d7s7p-7L6, 5f37s27p-5K6, 5f26d27s2 - 5L7, 5f46d7s - 7L6, (17,070cm-1)-5L6, 5f26d27s2-5K6, 6d7s7p-7L5, 5f36d7s7p-7K5 and 5f26d27s2-5I5 to the ground state of atomic uranium (UI) for the first time. Their relative oscillator strengths have been measured by means of hollow cathode discharge (HCD) emission spectrometry. The radiative...

MEASUREMENT OF SPONTANEOUS EMISSION BRANCHING RATIOS IN MO(I) TRANSITIONS BY LASER-INDUCED SENSITIZED FLUORESCENCE

I. TNTRODUCTIONThe emission spectroscopic method is usually used to measure spontaneous emission branching ratios. As emission spectra cannot be detected in atomic beams, the laser-induced fluorescence or ion detection method is often used. When the fluorescence method is used to measure branching ratios, it is usually necessary to detect

A Dicer-1 gene from white shrimp Litopenaeus vannamei: Expression pattern in the processes of immune response and larval development

Dicer is a member of the RNAase III family which catalyzes the cleavage of double-stranded RNA to small interfering RNAs and micro RNAs, and then directs sequence-specific gene silencing. In this paper, the full-length cDNA of Dicer-1 was cloned from white shrimp Litopenaeus vannamei (designated as LvDcr1). It was of 7636 bp, including a poly A tail, a 5' UTR of 136 bp, a 3' UTR of 78 bp, and an open reading frame (ORF) of 7422 bp encoding a putative protein of 2473 amino acids. The predicted amino acid sequence comprised all recognized functional domains found in other Dicer-1 homologues and showed the highest (97.7%) similarity to the Dicer-1 from tiger shrimp Penaeus mondon. Quantitative real-time PCR was employed to investigate the tissue distribution of LvDcr1 mRNA, and its expression in shrimps under virus challenge and larvae at different developmental stages. The LvDcr1 mRNA could be detected in all examined tissues with the highest expression level in hemocyte, and was up-regulated in hemocytes and gills after virus injection. These results indicated that LvDcr1 was involved in antiviral defense in adult shrimp. During the developmental stages from fertilized egg to postlarva VII, LvDcr1 was constitutively expressed at all examined development stages, but the expression level varied significantly. The highest expression level was observed in fertilized eggs and followed a decrease from fertilized egg to nauplius I stage. Then, the higher levels of expression were detected at nauplius V and postlarva stages. LvDcr1 expression regularly increased at the upper phase of nauplius, zoea and mysis stages than their prophase. The different expression of LvDcr1 in the larval stages could provide clues for understanding the early innate immunity in the process of shrimp larval development. (C) 2010 Elsevier Ltd. All rights reserved.

Geomorphology, sedimentary processes and development of the Zenisu deep-sea channel, northern Philippine Sea

The Zenisu deep-sea channel originates on the Izu-Ogasawara island arc, and disappears in the Shikoku Basin of the Philippine Sea. The geomorphology, sedimentary processes, and the development of the Zenisu deep-sea channel were investigated on the basis of swath bathymetry, side-scan sonar imagery, submersible observations, and seismic data. The deep-sea channel can be divided into three segments according to the downslope gradient and channel orientation. They are the Zenisu Canyon, the E-W fan channel, and the trough-axis channel. The sediment fill is characterized by turbidite and debrite deposition and blocky-hummocky avalanche deposits on the flanks of the Zenisu Ridge. In the Zenisu Canyon and the Zenisu deep-sea channel, sediment transport by turbidity currents generates sediment waves (dunes) observed during the Shinkai 6500 dive 371. The development of the Zenisu Canyon is controlled by a N-S shear fault, whereas the trough-axis channel is controlled by basin subsidence associated with the Zenisu Ridge. The E-W fan channel was probably affected by the E-W fault and the basement morphology.