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A produção de sementes de forrageiras tropicais representa um importante segmento da indústria de sementes no Brasil e há a necessidade do estabelecimento de prioridades para aumentar a eficiência do setor. Neste documento estão apresentados os resultados da discussão efetuada pelo grupo de trabalho reunido durante o Workshop "Tecnologia de Sementes de Forrageiras Tropicais: Demandas Estratégicas de Pesquisa", realizado pela Embrapa Gado de Corte em abril de 2008. As demandas de pesquisa discutidas e consideradas prioritárias foram pertinentes a vários aspectos da produção e tecnologia de sementes de forrageiras tropicais, da semeadura ao processamento, bem como ao armazenamento e análises laboratoriais.

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A produção de sementes de forrageiras tropicais representa um importante segmento da indústria de sementes no Brasil e há a necessidade do estabelecimento de prioridades para aumentar a eficiência do setor. Neste documento estão apresentados os resultados da discussão efetuada pelo grupo de trabalho reunido durante o Workshop "Tecnologia de Sementes de Forrageiras Tropicais: Demandas Estratégicas de Pesquisa", realizado pela Embrapa Gado de Corte em abril de 2008. As demandas de pesquisa discutidas e consideradas prioritárias foram pertinentes a vários aspectos da produção e tecnologia de sementes de forrageiras tropicais, da semeadura ao processamento, bem como ao armazenamento e análises laboratoriais.

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2009

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Infrared (IR) spectra of normal, hyperplasia, fibroadenoma and carcinoma tissues of human breast obtained from 96 patients have been determined and analyzed statistically. Several spectral differences were detected in the frequency regions of N-H stretching, amide I, II and III bands: (1) the bands in the region 3000-3600cm-1 shifted to lower frequencies for the carcinomatous tissue; (2) the A(3300)/A(3075) absorbance ratio was significantly higher for the fibroadenoma than for the other types of tissues; (3) the frequency of the a-helix amide I band decreased for the malignant tissue, while the corresponding beta -sheet amide I band frequency increased; (4) the A(1657)/A(1635) and A(1553)/A(1540) absorbance ratios were the highest for fibroadenoma and carcinoma tissues; (5) the A(1680)/A(1657) absorbance ratio decreased significantly in the order of normal > hyperplasia > fibroadenoma > carcinoma; (6) the A(1651)/A(1545) absorbance ratio increased slightly for the fibroadenoma and the carcinoma tissues; (7) the bands at 1204 and 1278 cm(-1), assigned to the vibrational modes of the collagen, did not appear in the original spectra as resolved peaks and were distinctly stronger in the deconvoluted spectra of the carcinoma tissue and (8) the A(1657)/A(1204) and A(1657)/A(1278) absorbance ratios, both yielding information on the relative content of collagen, increased in the order of normal < hyperplasia < carcinoma < fibroadenoma. The said differences imply that the information is useful for the diagnosis of breast cancer and malignant breast abnormalities, and may serve as a basis for further studies on conformational changes in tissue proteins during carcinogenesis. (C) 2001 Elsevier Science B.V. All rights reserved.

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Sessão plenária de abertura; Relatos por estado sobre o comportamento da cultura da soja na safra 2000/01: Bahia, Distrito Federal, Goiás, Mato Grosso, Mato Grosso do Sul, Maranhão, Piauí, Tocantins e Pará, Minas Gerais, Paraná, Rondônia, Roraima, São Paulo; Comissões técnicas: Genética e melhoramento; Nutrição vegetal, fertilidade e biologia do solo; Fitopatologia; Entomologia; Plantas daninhas; Ecologia, Fisiologia e práticas culturais; Economia rural e difusão de tecnologia; Tecnologia de sementes; Sessão plenária final; Regimento interno da Reunião de Pesquisa de Soja da Região Central do Brasil; Resumos das Palestras apresentadas na XXIII Reunião de Pesquisa de Soja da Região Central do Brasil.

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Michael addition of substituted pyrazoles 2 to 1-alkynyl Fischer carbene complexes (CO)(5)M=C(OEt)(CdropCPh) (1) (a, M = Cr and b M = W) afforded (pyrazolyl)alkenyl Fischer carbene complexes (CO)(5)M=C(OEt)(CH=C(R(1)R(2)R(3)pz)Ph) (R(1)R(2)R(3)pz = pyrazolyl) 3 (M = Cr) and 4 (M = W), respectively, with an exclusive (E)-configuration in mild to excellent yields. The reaction of la and 3,5-dimethylpyrazole (2b) was monitored to demonstrate the formation and decomposition of complex 3b by H-1 NMR measurements in CDCl3 at 23degreesC. Complexes 3 and 4 were characterized with H-1, C-13{H-1} NMR, IR spectroscopies and elemental analysis. When the substituted pyrazoles were 3-methylpyrazole (2a) and 3,5-di-tert-butylpyrazole (2d), molecular structures of the corresponding (pyrazolyl)alkenyl Fischer carbene complexes 3a and 4d were characterized by X-ray crystallographic study. (C) 2004 Elsevier Ltd. All rights reserved.

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The desulfurization of thiophene on Raney Ni and rapidly quenched skeletal Ni (RQ Ni) has been studied in ultrahigh vacuum (UHV) by X-ray photoelectron spectroscopy (XPS). The Raney Ni or RQ Ni can be approximated as a hydrogen-preadsorbed polycrystalline Ni-alumina composite. It is found that thiophene molecularly adsorbs on Raney Ni or RQ Ni at 103 K. At 173 K, thiophene on alumina is desorbed, while thiophene in direct contact with the metallic Ni in Raney Ni undergoes C-S bond scission, leading to carbonaceous species most probably in the metallocycle-like configuration and atomic sulfur. On RQ Ni, the temperature for thiophene dissociation is about 100 K higher than that on Raney Ni. The lower reactivity of RQ Ni toward thiophene is tentatively attributed to lattice expansion of Ni crystallites in RQ Ni due to rapid quenching. The existence of alumina and hydrogen may block the further cracking of the metallocycle-like species on Raney Ni and RQ Ni at higher temperatures, which has been the dominant reaction pathway on Ni single crystals. By 473 K, the C Is peak has disappeared, leaving nickel sulfide on the surface.