Síntese, Caracterização Estrutural e Análise do Potencial Catalítico, para a Preparação de Biodiesel, de Niobatos Não Estequiométricos com Estrutura Tungstênio Bronze

Pós-graduação em Química - IBILCE

Fotoassociação caótica no oscilador de Morse

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Equação de Schrödinger não linear com coeficientes modulados

Pós-graduação em Física - FEG

Desenvolvimento de modelos para flavonoides e cumarinas utilizando o campo de força CGenFF

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Karyotype of the invasive species Pterois volitans (Scorpaeniformes: Scorpaenidae) from Margarita Island, Venezuela

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Controle de fotoassociação caótica com campos externos

The objective of the present work was to study the control of the dynamics of diatomic heteronuclear molecules interacting with electric fields created by lasers. Specifically in this work, the molecular photoassociation phenomenon will be analyzed. At this phenomenon, the atom's relative movement is described by a particle that moves in a morse potential well under the influence of an external time dependant force related to the external field. Based on the optimum control theory (OCT), it is presented at the present work laser pulses that alternate a given initial molecular state to a desirable end state, wich in this work was represented by the minimization of a cost functional that indicates how close. To do so, a computational sistem know as Genetic Algorithm (GA) was developed that can be characterizes as an extremelly eficient technique capable of scanning the solutions space and find results close to the optimum solutions

Fabricação e caracterização de diodo Schottky orgânico com arquitetura planar

Usually organic polymeric diodes are made with a semiconductor layer placed between two electrodes in a sandwich-like architecture, where the electrodes are deposited on the surfaces of a polymeric semiconductor film. This methodology leads to two main problems: i) the polymeric film top surface is rough and irregular, resulting in non-uniform electric field into the device; ii) during the deposition of metallic electrode in the top surface polymeric film, by thermal evaporation, occurs the diffusion of metal atoms into the polymeric film, changing the material electronic structure. Thus, the metal-semiconductor junction is not well defined, which is essential for the production of good quality Schottky diode, which exhibits ideality factor close to the unity and low turn-on voltage. In order to avoid these two problems, in the present research was proposed to manufacture an organic diode with the semiconductor polymeric layer deposited over bimetallic (gold and aluminum) interdigitated electrodes. The doping of the active layer was performed by immersing the device in hydrochloric acid solution with pH 2 during different times in order to promote different doping levels of the semiconductor polymer. Was verified that the proposed diode, which exhibits well-defined metal-semiconductor junction, operates as a Schottky diode, with good ideality factor, 10 ± 3, and low turn-on voltage, 1,2 ± 0,2 V, in comparison with conventional organic polymeric diodes. Contrasting with the ideality factor and turn-on voltage, the diode rectification ratio was obtained as 7, a value lower than the expected for a good organic diode. Was also showed that the diode characteristics were dependent on the semiconductor polymer doping level, and that the diode characteristics were optimized with doping promoted by immersion in the acid solution for times longer than 50 s. Furthermore, as was showed that the diodes properties are dependent on the semiconductor...

Propriedades ópticas de nanopartículas de halogenetos de cobre preparadas in situ em filmes híbridos de sílica

The sol-gel process is a technique based on the hydrolysis and polycondensation of metal alkoxides have been investigated as an alternative for the preparation of vitreous or glassceramic materials, for allowing the obtaining of high-purity materials at low temperatures, and to obtain hybrid materials with different compositions. When ORMOSILs are doped with nanoparticles, are called nanocomposites, and its functionality arises when electrons confined in scale three-dimensional structures near zero are excited. In principle, such materials exhibit discrete energy level, with peaks in the absorption spectrum. Therefore, the glasses doped semiconductor nanocrystals are important candidates for the preparation of optical filters with sharp cut-off, and are being exploited commercially for coloring glasses. This study evaluates the optical properties presented by hybrid films of silica doped with copper nanoparticles. The matrix was prepared using the alkoxides 3-glycidoxypropyltrimethoxysilane (GPTS) and tetraethylorthosilicate (TEOS) doped with Cu2O and hydrolyzed under reflux conditions in two different acidic conditions (HCl and HBr). After thermal treatment at temperatures between 100 °C and 170 °C and/or under the action of commercial black light radiation, CuCl and CuBr present in the hybrid film are transformed into nanoparticles of CuCl or CuBr. The UV-VIS absorption identified the absorption bands, and its variation

Estudos teóricos e numéricos de escoamentos com escorregamento

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

O ensino de estrutura da matéria na disciplina de física: uma análise de estruturas conceituais para a modelagem do currículo

Pós-graduação em Educação para a Ciência - FC

Simulação atomística de sistema em nanoescala

Pós-graduação em Física - IGCE

Resposta olfativa de fêmeas de Chrysomya Megacephala (F.) (Diptera: Calliphoridae) frente a posturas prévias e caracterização química dos compostos apolares da superfície de seus ovos

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Síntese do peptídeo acwahxkttks, peptídeo acwahxkttks e seu uso

A presente invenção apresenta a síntese do peptídeo AcWahxKTTKS, onde foi adicionada à “sequência mãe” (KTTKS) uma molécula de ácido capróico, que é um ácido graxo insaturado composto por 6 átomos de carbono, encontrado naturalmente nas gorduras e óleos minerais, para conferir um grau de lipofilicidade ao peptídeo e favorecer na permeabilidade do mesmo na pele. Adicionou-se também o triptofano, que é um aminoácido aromático essencial para a nutrição humana, visando proporcionar fluorescência ao peptídeo e assim quantificá-lo na pele através de um método mais eficiente e sensível. O triptofano foi acetilado para diminuir a interação do peptídeo com a água, a fim de ajudar na penetração do peptídeo na pele. O peptídeo AcWahxKTTKS estimula a síntese de colágeno nos fibroblastos, reduzindo ou eliminando, desta forma, as rugas e linhas de expressão na pele.

Silagens de milho consorciado com forrageira tropical e leguminosa em dietas para terminação de cordeiros

Pós-graduação em Ciência e Tecnologia Animal - FEIS

O espaço-tempo não comutativo em Teoria Quântica de Campos, Matéria Condensada Mole e Física Biológica

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)