Middle Miocene to Quaternary diatom biostratigraphy of DSDP Site 90-594

A diatom biostratigraphy is presented for middle Miocene through Quaternary sediments recovered from the Chatham Rise east of New Zealand's South Island. The upper 590 m of the 639.5-m composite-section Site 594 represents approximately 16 m.y. and is characterized by moderately to very poorly preserved diatoms of antarctic to temperate affinity. Pliocene through Quaternary assemblages are poorly preserved and dominated by antarctic-subantarctic species which provide detailed biostratigraphic control. Recognized are 11 of 14 zones of the middle upper Miocene to Quaternary Neogene Southern Ocean diatom zonation (NSD 7-NSD 20) of Ciesielski (1983; this chapter). Four Neogene Southern Ocean diatom zones (NSD 3-NSD 6) are recognized in the lower middle Miocene to middle upper Miocene of Site 594. Assemblages of this interval have a mixed high-latitude and temperate affinity; however, poor preservation limits correlation to high- and temperate-latitude zonal schemes. Neogene North Pacific diatom zones and subzones of NNPD 3 through NNPD 5 (Barron, in press, b) are correlated to Neogene Southern Ocean diatom zones NSD 3 through NSD 7: the upper portions of the Actinocyclus ingens Zone (NNPD 3) is correlative to the upper Nitzschia maleinterpretaria Zone (NSD 3); the Denticulopsis lauta Zone (NNPD 4) and Subzones a and b are correlative to the lower Coscinodiscus lewisianus Zone (NSD 4); and the D. hustedtü-D. lauta Zone (NNPD 5) and its Subzones a through d encompass the upper C. lewisianus Zone (NSD 4), N. grossepunctata Zone (NSD 5), N. denticuloides Zone (NSD 6), and the lower D. hustedtii-D. lauta Zone (NSD 7). A major disconformity spans the late Gilbert to early Gauss Chron (3.9-2.8 Ma). A second disconformity brackets the Miocene/Pliocene boundary; the section missing covers late Chron 5 and the early Gilbert chron (5.5-4.6 Ma). The remainder of the siliceous-fossil-bearing Miocene sediments at Site 594 appear to be correlative to lower paleomagnetic Chronozone 5 through upper Chronozone 16. Uppermost lower Miocene or lowermost middle Miocene sediments in the basal 50 m of Hole 594A are barren of diatoms.

C1-C7 volatile organic compounds in sediments at DSDP Legs 56-57 Holes

Volatile C1-C7 components in sediments were examined for Japan Trench DSDP Sites 438, 439, 435, 440, 434 and 436, proceeding from west to east. Levels of all components are lowest in the highly fractured sediments of Sites 440 and 434. A number of alkenes, furans, and sulfur compounds were detected in concentrations higher than noted in any other DSDP sediments examined to date. The types, amounts, and specificity of occurrence are similar to those for 1-meter gravity cores we have examined which bear a significant biological imprint. Site 436 shows high levels of saturated and aromatic hydrocarbons, as well as olefins, including traces of dimethycyclopentanes and the highest level of cyclohexene detected in any DSDP sediment we have examined to date. The results from Site 436 were unexpected, considering the low organic-carbon content, absence of biogenic methane, and evidence of an aerobic depositional environment at this site.

Organic compounds at DSDP Hole 90-593

Corg and Norg contents in the acid insoluble mineral fraction were studied in sediments of Site 593. Both decrease systematically from Recent to early Miocene over 425 m of carbonate facies. C/N ratios (7-11) are typically marine and indicate that residual organic matter, bound to clay minerals, was originally scavenged from the marine habitat rather than being of terrigenous origin. Variations of Corg and Norg are almost entirely controlled by rates of sedimentation, which gradually increase from Recent to early Miocene. Preliminary results of carbohydrate distribution indicate that epigenetic and diagenetic processes alter both the concentrations and the ratios of individual monomers with depth. Total carbohydrate concentrations in the samples diminish from 91 µg/g sediment at 18 m sub-bottom depth to 49 µg/g at 335 m. In contrast, sugars in the acid insoluble residue increase with depth, suggesting release of structural polysaccharides and their subsequent association with clay minerals. Ratios of arabinose to fucose, which are about 6:1 in Recent carbonaceous sediments intercepted by sediment traps, vary from 1:1 in the youngest sample to 1:2.5 in the oldest.

Radiolarians from the Southwest Pacific

Radiolarians are very rare in all Leg 90 sites. They are relatively more frequent only in Neogene sediments from Sites 586 and 594, and in Eocene sediments at Site 592. In this chapter radiolarian abundances are recorded as comparative percentages for 92 Neogene morphotypes at Site 586B. Relative abundances only are estimated at Sites 592 and 594, where preservation is poor to moderate. A tentative correlation of radiolarian events at Hole 586B and Site 594 shows that only a few species can be found in both tropical and subantarctic areas. New evolutionary lineages are proposed. 1. Middle Miocene eucyrtids like Eucyrtidium teuscheri group evolved into a widespread species (E. teuscheri teuscheri) ranging from middle Miocene to Holocene and a temperate species (E. teuscheri orthoporus) ranging from middle Miocene to early Pleistocene. 2. Phormostichoartus pitomorphus appears to be a temperate descendant of the cosmopolitan P. fistula and disappears in early Pleistocene time. 3. The discovery of Lamprocyrtis daniellae n.sp. calls into question the lineage L. heteroporos -> L. nigriniae. 4. The evolution of Lamprocyclas maritalis from an ancestor group (L. aff. maritalis) is located in the early part of the Pterocanium prismatium Zone.

Petrography and mineral compositions of gabbros at DSDP Leg 60 Holes

The compositions, mineralogies, and textures of gabbros recovered in polymict breccias in Hole 453 indicate that they are the cumulus assemblages of calc-alkalic crystal fractional on that occurred beneath the West Mariana Ridge. They are among a class of gabbros known only from other calc-alkalic associations (e.g., the Lesser Antilles and the Peninsular Ranges batholith of Southern California) and differ from gabbros of stratiform complexes, ophiolites, and the ocean crust. Particularly abundant in the Hole 453 breccias are olivine-bearing gabbros with extremely calcic Plagioclase (An94-97) but with fairly iron-rich olivines (Fo76-77). Other gabbros contain biotite and amphibole and occur in breccias with fairly high-grade greenschist facies (amphibole-chlorite-stilpnomelane) metabasalts. One unusual gabbro has experienced almost complete subsolidus recrystallization to an assemblage of aluminous magnesio-hornblende, anorthite, and green hercynitic spinel. This reaction, the extremely calcic Plagioclase, the occurrence of biotite and amphibole, and the association with greenschist facies metamorphic rocks suggest that crystallization of the gabbros occurred at elevated P(H2O). Comparisons with other calc-alkalic gabbro suites suggest pressures in excess of 4 kbar (about 12 km depth). The gabbros were exposed by the early stages of opening of the Mariana Trough and imply that considerable uplift may have attended rifting. They were also subjected to hydrothermal alteration after breccia formation, resulting in formation of chlorite, epidote, actinolite, and prehnite. Temperatures of at least 200°C - and probably 350°C - were reached, and most likely could not have been attained without extrusion or intrusion of magmas nearby, even though no such rocks were cored.

Distribution of Cretaceous redeposited benthic foraminifers at DSDP Site 89-585

Cretaceous benthic foraminifers from Site 585 in the East Mariana Basin, western Pacific Ocean, provide an environmental and tectonic history of the Basin and the surrounding seamounts. Age diagnostic species (from a fauna of 155 benthic species identified) range from late Aptian to Maestrichtian in age. Displaced species in sediments derived from the tops and flanks of nearby seamounts were deposited sporadically on the Basin floor well below the carbonate compensation depth (CCD) at abyssal depths of 5000 to 6000 m. These depths, characterized by an indigenous assemblage of benthic foraminifers, recrystallized radiolarians, fish debris, and sponge spicules, existed in the Mariana Basin from late Aptian to the present. Early Albian and older edifice-building volcanism had reached the photic zone with associated shallow-water bank or reef environments. By middle Albian, the dominant source areas subsided to outer-neritic to upper-bathyal depths. Major volcanic activity ceased and fine-grained sediments were deposited by distal turbidites, although intermittent volcanism and the influx of rare neritic material continued until the late Albian. By the Cenomanian to Turonian, upper- to middle-bathyal depths were reached by the dominant source areas, and the sediments recovered from this interval include organic carbon-rich layers. Rare benthic foraminifers from the Coniacian-Santonian interval indicate a continuation of dominantly middle-bathyal source areas. A change in sedimentation during the Campanian-Maestrichtian from older zeolitic claystone to abundant chert in the Campanian, and nannofossil chalk and claystone in the Maestrichtian resulted from migration of the site beneath the equatorial productive zone due to northwestward plate motion. The appearance of rare middle-neritic and upper-bathyal species in the Maestrichtian interval associated with volcanogenic debris gives evidence of the remobilization and downslope transport of pelagic deposits due to thermally induced uplift. Episodic redeposition of shallow-water material during the Aptian-Albian was produced by edifice-building volcanism perhaps combined with eustatic lowering of sea level. The Cenomanian-Turonian pulse coincided with a low global sea-level stand as does the transported material during the Coniacian-Santonian. The Maestrichtian pulse was caused by renewed midplate volcanism that extended over a large area of the central Pacific.

Quaternary isotope stratigraphy of DSDP Hole 90-593 from the Challenegr Plateau, South Tasman Sea

A moderate-resolution isotope stratigraphy (with an average of one sample per 17,500 yr.) derived from the benthic foraminifer Uvigerina (or Cibicides), the planktonic foraminifer Globigerina bulloides, and calcareous nannofossil concentrates is presented for the entire Quaternary (and latest Pliocene) section of mid-upper bathyal calcareous oozes from DSDP Site 593, western Challenger Plateau, south Tasman Sea. Superimposed on a trend of gradually increasing average delta18O values through the Pleistocene, reflecting the progressive buildup of polar ice sheets, is a record of highfrequency but generally low amplitude (0.5-1?) isotope fluctuations in the early Quaternary (1.9-1.0 m.y.), followed by a greatly increased intensity (1.5-2.0 ?) of glacial-interglacial fluctuations during the late Quaternary (< 1.0 m.y.). The standard late Quaternary isotope stages 1 to 24 are mainly resolvable. Significant excursions in both delta18O and delta13C values at various times during the Quaternary are suggested to be due to periodic, fundamental changes in ocean circulation properties over the plateau. For example, intensified upwelling of Antarctic Intermediate Waters during several glacial periods is indicated by the convergence of benthic and planktonic foraminiferal delta18O data, and productivity variations may account for certain delta13C spikes in the record. With increasingly higher resolution analysis this core will provide a useful Quaternary isotope reference section for southern temperate waters in the southwest Pacific, centered on New Zealand.

Benthic foraminiferal communities at DSDP Sites 94-609 to 94-611

Benthic foraminiferal assemblages from northeast Atlantic DSDP Sites 609, 610, and 611 have been interpreted with reference to modern assemblages known to be linked with the overlying bottom-water masses. It is shown that the water masses in the late Miocene to Pleistocene were similar to those of today. The distribution of the water masses changed with time, however. Antarctic Bottom Water ("AABW"), which at present is restricted to the area south of the Azores, reached as far north as the Gibbs Fracture Zone in the early Pliocene. Increased production of North Atlantic Deep Water in the late Pliocene displaced the AABW to the south

Occurrence and abundance of diatoms at DSDP Holes 72-515B and 72-516F

Samples from the upper Oligocene and lower Miocene of Holes 515B (Brazil Basin) and 516F (Rio Grande Rise) were examined for fossil marine diatom content. The preservation of the diatoms was poor and the species diversity low in both holes. However, it was possible to zone portions of the intervals studied using the zonation proposed by Gombos and Ciesielski (1983), which is based, as far as possible, on common and robust species. Thus, the interval in Hole 515B represented by Cores 515B-15 and 515B-16 is assigned to the Coscinodiscus rhombicus Zone and the interval represented by Cores 515B-17 through 515B-44 is assigned to the Rocella gelida Zone. The C. rhombicus Zone is early Miocene in age and the R. gelida Zone is late Oligocene to early Miocene in age. In Hole 516F the interval represented by Cores 516F-6 through 516F-10 is assigned to the R. gelida Zone Gate Oligocene to early Miocene), and the interval represented by Cores 516F-11 through 516F-15 is assigned to the Triceratium groningensis Zone (late Oligocene). Two new fossil diatom taxa are defined herein: Coscinodiscus lewisianus Greville f. concavus n. f. and Rocella semigelida n. sp.

Geochemistry and minerals at DSDP LEg 58 Holes

Leg 58 successfully recovered basalt at Sites 442, 443, and 444, in the Shikoku Basin, and at Site 446 in the Daito Basin. Only at Site 442 did penetration reach unequivocal oceanic layer 2; at the other sites, only off-axis sills and flows were sampled. Petrographic observations indicate that back-arc basalts from the Shikoku Basin, with the exception of the kaersutite-bearing upper sill at Site 444, are mineralogically similar to basalts being erupted at normal mid-ocean ridges. However, the Shikoku Basin basalts are commonly very vesicular, indicating a high volatile content in the magmas. Site 446 in the Daito Basin penetrated a succession of 23 sills which include both kaersutite-bearing and kaersutite-free basalt varieties. A total of 187 samples from the four sites has been analyzed for major and trace elements using X-ray-fluorescence techniques. Chemically, the basalts from Sites 442 and 443 and the lower sill of Site 444 are subalkaline tholeiites and resemble N-type ocean-ridge basalts found along the East Pacific Rise and at 22° N on the Mid-Atlantic Ridge (MAR), although they are not quite as depleted in certain hygromagmatophile (HYG) elements. They do not show any chemical affinities with island-arc tholeiites. The basalts from Site 446 and from the upper sill at Site 444 show alkaline and tholeiitic tendencies, and are enriched in the more-HYG elements; they chemically resemble enriched or E-type basalts and their differentiates found along sections of the MAR (e.g., 45°N) and on ocean islands (e.g., Iceland and the Azores). Most of the intra-site variation may be attributed to crystal settling within individual massive flows and sills, to high-level fractional crystallization in sub-ridge magma chambers, or, where there is evidence of a long period of magmatic quiescence between units, to batch partial melting. However, the basalts from Sites 442 and 443 and from the lower sill at Site 444 cannot easily be related to those from Site 446 and the upper sill at Site 444, and it is possible that the different basalt types were derived from chemically distinct mantle sources. From comparison of the Leg 58 data with those already available for other intra-oceanic back-arc basins, it appears that the mantle sources giving rise to back-arc-basin basalts are chemically as diverse as those for mid-ocean ridges. In addition, the high vesicularity of the Shikoku Basin basalts supports previous observations that the mantle source of back-arc-basin basalts may be contaminated by a hydrous component from the adjacent subduction zone.

Oxygen and carbon isotopes from foraminifers and benthic foraminiferal abundance at DSDP Holes 71-511 and 71-512

An Eocene-Oligocene oxygen and carbon isotope history based on planktonic and benthic foraminifers from Deep Sea Drilling Project Leg 71 cores has been constructed for the Maurice Ewing Bank of the eastern Falkland Plateau, Southwest Atlantic Ocean. Specifically, the cores cover portions of the middle Eocene, upper Eocene, and lower Oligocene. Surface water isotopic temperatures postulated for the middle Eocene at Site 512 fluctuated within about four degrees but generally averaged about 9°C. Bottom isotopic temperatures at Site 512 (water depth, 1846 m) were generally a degree lower than surface water temperatures. Surface water isotopic temperatures at Site 511 initially averaged about 11°C during the late Eocene, but dropped to an average of 7°C in the early Oligocene. Bottom isotopic temperatures at Site 511 (water depth, 2589 m) generally record temperatures between 12.5°C and 8°C, similar to the range in the surface water isotopic temperatures. During the early Oligocene, bottom isotopic temperatures dropped sharply and averaged about 2°C (very close to present-day values). Surface water temperature values also decreased to an average of about 7°C, therefore leading to a significant divergence between surface and bottom water isotopic temperatures during the early Oligocene. Comparisons among Southern Ocean DSDP Sites 511, 512, and 277, and between these and other DSDP sites from central and northern latitudes (Sites 44, 167, 171, 292, 357, 398, 119, and 401) show that much of the Eocene was characterized by relatively warm temperatures until sometime in either the middle Eocene, late Eocene, or early Oligocene. At each site, conspicuous 18O enrichments occur in both the benthic and planktonic foraminifers over a relatively short period of time. Although a general trend toward a climatic deterioration is evident, the density of data points among the various studies is still too sparse to determine either synchrony or time-transgression between the major isotopic events. A close correlation could be made between the Site 511 oxygen isotope temperature curve and paleoclimatic trends derived independently from radiolarian studies. The sharp temperature drop and the divergence between bottom and surface water temperatures during the early Oligocene apparently reflect a major expansion of the antarctic water mass. The migration of the boundary between the subantarctic and antarctic water masses over the site at this time would account in part for the sharp temperature changes. Sharp changes of this nature would not necessarily be noted in other geographic areas, particularly those to the north which have different oceanographic regimes.

Quartz content and mass accumulation rates at DSDP Hole 86-576A

The amount and the accumulation rate of quartz were measured in 33 samples from Hole 576A. The amount and source of mineral aerosol being deposited in the northwest Pacific during the Cenozoic are evaluated using these data. When Hole 576A is compared to a Cenozoic record in the central North Pacific, a strong uniformity in the composition of the mineral aerosol across the North Pacific is seen. The data suggest that Hole 576A entered the influence of the westerlies about 15 m.y. ago and that since that time the rates of sediment deposition have increased. Only the dramatic change in quartz accumulation 2.5 m.y. ago can be clearly related to a climatic event, but a gradual increase in quartz accumulation through the Miocene and early Pliocene is probably a result of increasing Northern Hemisphere aridity and intensified atmospheric activity associated with global cooling during the interval.

Nannoliths and paleobiogeographic census from DSDP Site 56-435

Calcareous nannofossils were encountered at only one of the sites (435) drilled during DSDP Leg 56. Cores from Hole 435A yield fairly diverse early and late Pliocene assemblages. The section shows considerable reworking, however. Three to five biostratigraphic datum events provide a reasonable biochronology. The datums range from about 3.3 Ma in Core 11 to about 1.8 Ma in Core 3. Paleobiogeographic data indicate relatively stable and warm climatic conditions in this area in the early Pliocene, becoming more unstable in the late Pliocene when the cosmopolitan species become dominant.

Zeolite and silica diagenesis and sandstone petrography at DSDP Sites 57-438 and 57-439

We detected authigenic clinoptilolites in two core samples of tuffaceous, siliceous mudstone in the lower Miocene section of Hole 439. They occur as prismatic and tabular crystals as long as 0.03 mm in various voids of dissolved glass shards, radiolarian shells, calcareous foraminifers, and calcareous algae. They are high in alkalies, especially Na, and in silica varieties. There is a slight difference in composition among them. The Si : (Al+ Fe3+) ratio is highest (4.65) in radiolarian voids, intermediate (4.34) in dissolved glass voids, and lowest (4.26) in voids of calcareous organisms. This difference corresponds to the association of authigenic silica minerals revealed by the scanning electron microscope: There are abundant opal-CT lepispheres in radiolarian voids, low cristobalite and some lepispheres in dissolved glass voids, and a lack of silica minerals in the voids of calcareous organisms. Although it contains some silica from biogenic opal and alkalies from trapped sea water, clinoptilolite derives principally from dissolved glass. Although they are scattered in core samples of Quaternary through lower Miocene diatomaceous and siliceous deposits, acidic glass fragments react with interstitial water to form clinoptilolite only at a sub-bottom depth of 935 meters at approximately 25°C. Analcimes occur in sand-sized clasts of altered acidic vitric tuff in the uppermost Oligocene sandstones. The analcimic tuff clasts were probably reworked from the Upper Cretaceous terrain adjacent to Site 439. Low cristobalite and opal-CT are found in tuffaceous, siliceous mudstone of the middle and lower Miocene sections at Sites 438 and 439. Low cristobalite derives from acidic volcanic glass and opal-CT from biogenic silica. Both siliceous organic remains and acidic glass fragments occur in sediments from the Quaternary through lower Miocene sections. However, the shallowest occurrence is at 700 meters subbottom in Hole 438A, where temperature is estimated to be 21°C. The d(101) spacing of opal-CT varies from 4.09 to 4.11 Å and that of low cristobalite from 4.04 to 4.06 Å. Some opal-CT lepispheres are precipitated onto clinoptilolites in the voids of radiolarian shells at a sub-bottom depth of 950 meters in Hole 439. Sandstone interlaminated with Upper Cretaceous shale is chlorite- calcite cemented and feldspathic. Sandstones in the uppermost Oligocene section are lithic graywacke and consist of large amounts of lithic clasts grouped into older sedimentary and weakly metamorphosed rocks, younger sedimentary rocks, and acidic volcanic rocks. The acidic volcanic clasts probably originated from the volcanic high, which supplied the basal conglomerate with dacite gravels. The older sedimentary and weakly metamorphosed rocks and green rock correspond to the lithologies of the lower Mesozoic to upper Paleozoic Sorachi Group, including the chert, limestone, and slate in south-central Hokkaido. However, the angular shape and coarseness of the clasts and the abundance of carbonate rock fragments indicate a nearby provenance, which is probably the southern offshore extension of the Sorachi Group. The younger sedimentary rocks, including mudstone, carbonaceous shale, and analcime-bearing tuff, correspond to the lithologies of the Upper Cretaceous strata in south-central Hokkaido. Their clasts were reworked from the southern offshore extension of the strata. Because of the discontinuity of the zeolite zoning due to burial diagenesis, an overburden several kilometers thick must have been denuded before the deposition of sediments in the early Oligocene.

Clay minerals at DSDP Sites 71-511 and 71-513

The distribution of clay minerals, determined by X-ray diffraction, is given for Jurassic to Holocene sediments recovered at DSDP Sites 511 and 513 in the Southwest Atlantic. These data, plus the lithologic and paleoenvironmental information gathered by the shipboard scientists, are used to subdivide the sedimentary sequence into genetic lithologic facies labeled series, seven for Site 511 and two for Site 513. Sediments of these series reflect the main historical and paleoenvironmental events which other means of study have determined to affect this region; particularly important was the opening of the South Atlantic during the Early Cretaceous.