Description of the fossil manganese nodules found in the Oligocene clay deposits of Moravia, Brno area, Czech Republic

In the green Oligocene clay of Krizanovice (former Krzyzanowicz) the author found numerous black nodules. In the 3-4 centimeter thick black crust of a particular specimen the concentration in MnO2 is evaluated at 46.6% MnO2. The determination was done using the Volhard's method (precipitation of Fe by ZnO and titration with KMnO4). Only the dissoleved part in HCL was analysed. The non soluble residue was essentially a silica precipitate in the form of many gray flakes. The specific gravity of the crust was evaluated at 3.8. In the internal yellow core the amount of manganese is about 2.39% MnO2. Due to the light color it is judged to probably be in the form of Mn2O3.

Radiocarbon data, oxygen isotopic composition in foraminifera, freshwater diatoms data, and salinity estimations from ODP Holes 167-1019C and 167-1019D

Massive discharges of freshwater from the glacial lake Missoula to the northeast Pacific Ocean are thought to have sculpted the Channeled Scablands of eastern Washington and debouched via the Columbia River near 46°N. The dynamics and timing of these events and their impact on northeast Pacific circulation remain uncertain. Here we date marine records of anomalous freshwater inputs to the ocean based on freshwater diatoms, oxygen isotopes in foraminifera, and radiocarbon data. Low-salinity plumes from the Columbia River reduced sea-surface salinities by as much as 6 psu (practical salinity units) more than 400 km away between 16 and 31 cal (calendar) ka B.P. Anomalously high abundances of freshwater diatoms in marine sediments from the region precede generally accepted dates for the existence of glacial Lake Missoula, implying that large flooding or freshwater routing events were common during the advance of the Cordilleran Ice Sheet and that such events require multiple sources.

Geochemical data for drilled powder samples from two fossil Porites corals from Integrated Ocean Drilling Program Expedition 310

Fossil corals are unique archives of past seasonal climate variability, providing vital information about seasonal climate phenomena such as ENSO and monsoons. However, submarine diagenetic processes can potentially obscure the original climate signals and lead to false interpretations. Here we demonstrate the potential of laser ablation ICP-MS to rapidly detect secondary aragonite precipitates in fossil Porites colonies recovered by Integrated Ocean Drilling Program (IODP) Expedition 310 from submerged deglacial reefs off Tahiti. High resolution (100 µm) measurements of coralline B/Ca, Mg/Ca, S/Ca, and U/Ca ratios are used to distinguish areas of pristine skeleton from those afflicted with secondary aragonite. Measurements of coralline Sr/Ca, U/Ca and oxygen isotope ratios, from areas identified as pristine, reveal that the seasonal range of sea surface temperature in the tropical south Pacific during the last deglaciation (14.7 and 11 ka) was similar to that of today.