(Figure 4) Stratigraphic distribution of planktonic foraminifera in DSDP Hole 93-604

During Deep Sea Drilling Project Leg 93, upper Miocene through Quaternary sediments were continuously cored in Hole 604, located on the upper continental rise of the New Jersey transect (western North Atlantic). A detailed biostratigraphic study of these strata has been made using the vertical distribution of planktonic foraminifers. The Quaternary climatic zonation of Ericson and Wollin (1968) has been tentatively delineated and all the Pliocene zones and subzones (sensu Berggren, 1977) have been recognized. The rate of sedimentation was slow during most of the Pliocene but underwent a significant acceleration in the early Pleistocene. Quantitative variations in the distribution of planktonic foraminifers appear to be influenced by various factors, such as hydrodynamic winnowing resulting from the action of bottom currents and surficial thermal conditions caused by climatic changes. Both dissolution intervals and brief increases in the coarser detrital input seem, most of the time, to be correlated with indications of climatic cooling and may correspond to glacial events or cycles. This chapter delineates a precursor stage in the inception of Northern Hemisphere glaciation at 3 Ma and wide-scale Quaternary glacial-interglacial cycles. Data from a detailed study of Hole 604 are briefly compared with the main sedimentary and microfaunal features of contemporaneous series previously drilled along the east American margin in the northwestern Atlantic. One of the striking observations appears to be the intense redistribution of sediments that affected this region in Neogene-Quaternary times.

CaCO3, organic carbon, and nitrogen at DSDP Hole 93-603B

Contents of organic carbon and carbonate carbon were determined on the same set of Cretaceous samples from DSDP Hole 603B in three different laboratories in order to assess the degree of comparability of organic carbon and carbonate values obtained by different labs using the same or different methods. We report the results of analyses for organic carbon using two different CHN analyzers, LECO, and Rock-Eval II and for carbonate carbon by CHN (total C minus C after acidification), the carbonate bomb technique, and CaCO3 calculated on the basis of total calcium obtained from X-ray fluorescence and induction-coupled plasma techniques. In addition, total nitrogen was obtained by two different labs using a CHN analyzer, but different bases for calculation were used. The various techniques for organic carbon analysis yielded comparable results, with the exception of those obtained by one of the CHN analyses of acid-treated samples. The calculation of organic carbon values and comparison on a whole-rock basis is very sensitive to errors in determination of carbonate contents, and this factor explains most, but not all, of the disparities between the data sets. The carbonate bomb technique gives CaCO3 values that correspond well with those calculated from total calcium concentrations (XRF and ICP analyses), whereas the CaCO3 calculated from CHN total carbon minus acid-soluble carbon consistently overestimated CaCO3. Total nitrogen and C/N results from the two different CHN analyses are not comparable and are subject to more error than the factor related to error in estimation of CaCO3.

(Table 1, page 605) Chemistry of concretions from Grand Lake (GL) and Ship Harbour Lake (SH), Nova Scotia and Mosque Lake (ML), Ontario

Studies by optical microscopy, x-ray diffraction, and electron probe techniques of ferromanganese concretions from three Canadian lakes reveal chemical banding of amorphous hydrated iron and manganese oxides. The average ratio of iron to manganese in concretions from these lakes varies from 0.43 to 2.56. The concentrations of cobalt, nickel, copper, and lead are one to two orders of magnitude below those reported for oceanic ferromanganese concretions.

(Table 2) Oxygen and carbon isotope composition of planktonic foraminiferal species from DSDP Holes 93-603B and 93-604, and one benthic species from Hole 93-604

Holes 603C and 604 of DSDP Leg 93 were drilled on the western Atlantic continental rise at water depths of 4633 m and 2364 m, respectively. In Hole 603C, a nearly continuous, undisturbed, and complete section of Pliocene and lower Pleistocene sediments was recovered by hydraulic piston coring; in Hole 604, a section of uppermost Miocene to Pleistocene sediments was incompletely recovered by rotary coring. In order to reconstruct the Pliocene and Pleistocene history of isotopic variations, 139 oxygen and carbon isotope values were determined for planktonic and monospecific benthic foraminifer samples from these holes. Large parts of the Pleistocene history could not, however, be documented because sample intervals were large and sediments at Site 604 were redeposited. Time correlation is based on magnetostratigraphic (Hole 603C) and micropaleontologic (Hole 603C, Site 604) interpretation. Stable isotope analyses were carried out on the planktonic foraminiferal species Globigerinoides ruber, G. obliquus, and Globorotalia inflata from Hole 603C (48 analyses) and from Site 604 (48 analyses); at Site 604, the benthic foraminifer Uvigerina peregrina (43 analyses) was also studied through the section. Age calibration for Hole 603C is based on the magnetostratigraphy of Canninga et al. (1987; doi:10.2973/dsdp.proc.93.130.1987), which uses the time scale of Lowrie and Alvarez (1981).

(Table 1) Clay minerals at DSDP Hole 93-603B

Cretaceous sediments encountered in Hole 603B contain a 17 Å smectite as the principal clay mineral, with lesser amounts of illite, kaolinite, and randomly interstratified illite/smectite (I/S). No evidence of smectite to I/S transformation with depth is seen in the interval between 1040 and 1570 m below the sediment surface. Although the presence of some volcanic ash suggests a volcanic origin for the smectite, the nature of associated organic matter together with prevailing sedimentological models for Cretaceous sedimentation on the lower continental rise argue more strongly for a dominantly terrestrial origin for the clays.

(Table 1) Distribution of Lower Cretaceous calcareous nannofossils at DSDP Hole 93-603B

Upper Berriasian to lower Aptian calcareous nannofossil assemblages have been studied from a siliciclastic deep-sea fan complex and a subjacent limestone sequence drilled beneath the lower continental rise in the western North American Basin, 270 miles (435 km) off Cape Hatteras, North Carolina (USA). Sharp lithologic facies changes and reworking by turbidites complicate the biostratigraphic interpretation, but provide an excellent opportunity to better distinguish "nearshore" from open-ocean nannofossil species, and to investigate the introduction of neritic taxa into the deep-see environment, a phenomenon that appears to have been widespread within the circum-North Atlantic during Neocomian times. Well-preserved assemblages in dark, carbonaceous claystones were probably displaced from the oxygen minimum zone along the upper slope or outer shelf. Neritic, continental margin species prevalent in this facies include the holococcolith Zebrashapka vanhintei n. gen., n. sp., Lithraphidites alatus magnus n. spp., Pickelhaube furtiva n. gen., and a host of nannoconids and micrantholiths. A qualitative evaluation of widely used guide fossils suggests that the triad of proposed markers for the base of Roth's Zone NC3 make their first appearances in the following (ascending) order: Diadorhombus rectus, TUbodiscus verenae, Calcicalathina oblongata. Of these, we chose the nominative species for the zone, T. verenae, to mark its base and to approximate the Berriasian/Valangian boundary. Cyclagelosphaera deflandrei is strongly affected by diagenesis and is therefore not a reliable index species for the base of Zone NC4 near the Valanginian/Hauterivian boundary (the last occurrence of T. verenae is also not suitable there). In addition, Lithraphidites bollii, a form apparently confined to the low latitudes of the Tethyan region, was absent at the more temperate Site 603 and not available as a subzonal marker for the upper Hautervian-lower Barremian (mid-NC4 and mid-NC5, respectively). Cruciellipsis cuvillieri, however, provides a reliable datum just below the Hauterivian/Barremian boundary (base of NC5), despite the potential for reworking in this section. Nannoconids tend to be reworked in this section, and do not provide trustworthy forms to mark the Barremian/Aptian boundary (base of NC6). Hayesites irregularis n. comb, probably does provide a useful first appearance datum within the lower Aptian, if it is not confused with a more birefringent and globular form, Rucinolithus terebrodentarius n. sp. Rhagodiscus angustus is mimicked by a similar form (Zeughrabdotusl pseudoangustus n. sp.), which apparently ranges down to the Hauterivian, thus Lithastrinus floralis provides a more useful first appearance datum for the base of the middle-upper Aptian Rhagodiscus angustus Zone (NC7). Aside from the new taxa mentioned above, the following are also described: Cretarhabdusl delicatus n. sp. and Cyclagelosphaera jiangii n. sp.