Chemical composition of rocks and minerals from the Mid-Atlantic Ridge near 15°20'N

The monograph summarizes results of petrological and geochemical studies of rocks from the ocean floor collected by the authors during expeditions to the Central Atlantic. Detailed work in the Capa Verde transform fault zone gave a large amount of new information about magmatic and hydrothermal systems of the Mid-Atlantic Ridge.

Chemical composition of DSDP and ODP cherts

Rare earth element (REE), major, and trace element abundances and relative fractionations in forty nodular cherts sampled by the Deep Sea Drilling Project (DSDP) and Ocean Drilling Program (ODP) indicate that the REE composition of chert records the interplay between terrigenous sources and scavenging from the local seawater. Major and (non-REE) trace element ratios indicate that the aluminosilicate fraction within the chert is similar to NASC (North American Shale Composite), with average Pacific chert including ~7% NASC-like particles, Indian chert ~11% NASC, Atlantic chert ~17% NASC, and southern high latitude (SHL) chert 53% NASC. Using La as a proxy for sum REE, approximations of excessive La (the amount of La in excess of that supplied by the detrital aluminosilicate fraction) indicate that Pacific chert contains the greatest excessive La (85% of total La) and SHL chert the least (38% of total La). As shown by interelement associations, this excessive La is most likely an adsorbed component onto aluminosilicate and phosphatic phases. Accordingly, chert from the large Pacific Ocean, where deposition occurs relatively removed from significant terrigenous input, records a depositional REE signal dominated by adsorption of dissolved REEs from seawater. Pacific chert Ce/Ce* <<1 and normative La/Yb ~ 0.8-1, resulting from adsorption of local Ce-depleted seawater and preferential adsorption of LREEs from seawater (e.g., normative La/Yb ~0.4), which increases the normative La/Yb ratio recorded in chert. Chert from the Atlantic basin, a moderately sized ocean basin lined by passive margins and with more terrigenous input than the Pacific, records a mix of adsorptive and terrigenous REE signals, with moderately negative Ce anomalies and normative La/Yb ratios intermediate to those of the Pacific and those of terrigenous input. Chert from the SHL region is dominated by the large terrigenous input on the Antarctic passive margin, with inherited Ce/Ce* ~1 and inherited normative La/Yb values of ~1.2-1.4. Ce/Ce* does not vary with age, either throughout the entire data base or within a particular basin. Overall, Ce/Ce* does not correlate with P2O5 concentrations, even though phosphatic phases may be an important REE carrier.

Annual variations in composition of the North Dvina River water

New data on elemental composition of particulate matter from the North Dvina River are presented. In May (period of snowmelt flood) it is similar to the upper layer of the continental crust due to active erosion of crust material in the catchment area. In August (summer low water period) impact of biogenic components increases and elevated concentrations of Cd, Sb, Mn, Zn, Pb, and Cu are observed. At other seasons no significant increase in heavy and rare earth element concentrations is observed.

Climate and total tree cover reconstructions based on the 43.7-kyr fossil pollen record from Khoe (NW Sakhalin Island) and modern climate variables of 236 modern surface pollen sampling sites

A late Quaternary pollen record from northern Sakhalin Island (51.34°N, 142.14°E, 15 m a.s.l.) spanning the last 43.7 ka was used to reconstruct regional climate dynamics and vegetation distribution by using the modern analogue technique (MAT). The long-term trends of the reconstructed mean annual temperature (TANN) and precipitation (PANN), and total tree cover are generally in line with key palaeoclimate records from the North Atlantic region and the Asian monsoon domain. TANN largely follows the fluctuations in solar summer insolation at 55°N. During Marine Isotope Stage (MIS) 3, TANN and PANN were on average 0.2 °C and 700 mm, respectively, thus very similar to late Holocene/modern conditions. Full glacial climate deterioration (TANN = -3.3 °C, PANN = 550 mm) was relatively weak as suggested by the MAT-inferred average climate parameters and tree cover densities. However, error ranges of the climate reconstructions during this interval are relatively large and the last glacial environments in northern Sakhalin could be much colder and drier than suggested by the weighted average values. An anti-phase relationship between mean temperature of the coldest (MTCO) and warmest (MTWA) month is documented during the last glacial period, i.e. MIS 2 and 3, suggesting more continental climate due to sea levels that were lower than present. Warmest and wettest climate conditions have prevailed since the end of the last glaciation with an optimum (TANN = 1.5 °C, PANN = 800 mm) in the middle Holocene interval (ca 8.7-5.2 cal. ka BP). This lags behind the solar insolation peak during the early Holocene. We propose that this is due to continuous Holocene sea level transgression and regional influence of the Tsushima Warm Current, which reached maximum intensity during the middle Holocene. Several short-term climate oscillations are suggested by our reconstruction results and correspond to Northern Hemisphere Heinrich and Dansgaard-Oeschger events, the Bølling-Allerød and the Younger Dryas. The most prominent fluctuation is registered during Heinrich 4 event, which is marked by noticeably colder and drier conditions and the spread of herbaceous taxa.

Geochemistry of DSDP Leg 91 basalts

Basalts recovered from Sites 595 and 596 on Mesozoic crust in the southwest Pacific range from olivine-bearing tholeiites to ferrobasalts. Despite having undergone extensive low-grade alteration, which has raised K and Rb abundances, the basalts have consistent interelement ratios of Ti, Zr, Hf, rare-earth elements, Y, Th, Ik, and Nb. La/Ta (-18), Lan/Ybn (0.6), Ti/Zr (115), Zr/Nb (20), and Th/Hf (0.08) ratios all fall within the range of N-type mid-ocean-ridge basalt. The basalts from Sites 595 and 596 indicate that the Mesozoic Pacific crust was derived from a mantle source by processes similar to those operating at the present-day East Pacific Rise.

Calcareous nannoplankton of DSDP Leg 43 holes

During Leg 43, six holes (Sites 382-387) were drilled in the western part of the North Atlantic Ocean; locations of sites are shown in Figure 1. Lower Cretaceous to Quaternary calcareous nannofossils were found in 127 of 189 cores recovered during the leg. The ages and zonal assignments of these fossiliferous cores based upon light-microscopical observation are given in Table 1. An almost continuous succession of nannofossil assemblages of the lower Maestrichtian to upper Paleocene is present at Site 384. A detailed investigation was conducted on samples at this site, and the evolution of approximately 50 species is documented through almost the entire Paleocene epoch.