Geochemical behaviour of dissolved trace elements in a monsoon-dominated tropical river basin, Southwestern India

The study presents a 3-year time series data on dissolved trace elements and rare earth elements (REEs) in a monsoon-dominated river basin, the Nethravati River in tropical Southwestern India. The river basin lies on the metamorphic transition boundary which separates the Peninsular Gneiss and Southern Granulitic province belonging to Archean and Tertiary-Quaternary period (Western Dharwar Craton). The basin lithology is mainly composed of granite gneiss, charnockite and metasediment. This study highlights the importance of time series data for better estimation of metal fluxes and to understand the geochemical behaviour of metals in a river basin. The dissolved trace elements show seasonality in the river water metal concentrations forming two distinct groups of metals. First group is composed of heavy metals and minor elements that show higher concentrations during dry season and lesser concentrations during the monsoon season. Second group is composed of metals belonging to lanthanides and actinides with higher concentration in the monsoon and lower concentrations during the dry season. Although the metal concentration of both the groups appears to be controlled by the discharge, there are important biogeochemical processes affecting their concentration. This includes redox reactions (for Fe, Mn, As, Mo, Ba and Ce) and pH-mediated adsorption/desorption reactions (for Ni, Co, Cr, Cu and REEs). The abundance of Fe and Mn oxyhydroxides as a result of redox processes could be driving the geochemical redistribution of metals in the river water. There is a Ce anomaly (Ce/Ce*) at different time periods, both negative and positive, in case of dissolved phase, whereas there is positive anomaly in the particulate and bed sediments. The Ce anomaly correlates with the variations in the dissolved oxygen indicating the redistribution of Ce between particulate and dissolved phase under acidic to neutral pH and lower concentrations of dissolved organic carbon. Unlike other tropical and major world rivers, the effect of organic complexation on metal variability is negligible in the Nethravati River water.

Perovskite ceramic nanoparticles in polymer composites for augmenting bone tissue regeneration

There is increasing interest in the use of nanoparticles as fillers in polymer matrices to develop biomaterials which mimic the mechanical, chemical and electrical properties of bone tissue for orthopaedic applications. The objective of this study was to prepare poly(epsilon-caprolactone) (PCL) nanocomposites incorporating three different perovskite ceramic nanoparticles, namely, calcium titanate (CT), strontium titanate (ST) and barium titanate (BT). The tensile strength and modulus of the composites increased with the addition of nanoparticles. Scanning electron microscopy indicated that dispersion of the nanoparticles scaled with the density of the ceramics, which in turn played an important role in determining the enhancement in mechanical properties of the composite. Dielectric spectroscopy revealed improved permittivity and reduced losses in the composites when compared to neat PCL. Nanofibrous scaffolds were fabricated via electrospinning. Induction coupled plasma-optical emission spectroscopy indicated the release of small quantities of Ca+2, Sr+2, Ba+2 ions from the scaffolds. Piezo-force microscopy revealed that BT nanoparticles imparted piezoelectric properties to the scaffolds. In vitro studies revealed that all composites support osteoblast proliferation. Expression of osteogenic genes was enhanced on the nanocomposites in the following order: PCL/CT>PCL/ST>PCL/BT>PCL. This study demonstrates that the use of perovskite nanoparticles could be a promising technique to engineer better polymeric scaffolds for bone tissue engineering.

Ferroelectric instabilities and enhanced piezoelectric response in Ce modified BaTiO3 lead-free ceramics

The crystal structure, ferroelectric, and piezoelectric behaviors of the Ba(Ti1-xCex)O-3 solid solution have been investigated at close composition intervals in the dilute concentration regime. Ce concentration as low as 2 mol. % induces tetragonal-orthorhombic instability and coexistence of the phases, leading to enhanced high-field strain and direct piezoelectric response. Detailed structural analysis revealed tetragonal + orthorhombic phase coexistence for x = 0.02, orthorhombic for 0.03 <= x <= 0.05, and orthorhombic + rhombohedral for 0.06 <= x <= 0.08. The results suggest that Ce-modified BaTiO3 is a potential lead-free piezoelectric material. (C) 2015 AIP Publishing LLC.

Exploring the Crystal Structure Landscape with a Heterosynthon Module: Fluorobenzoic Acid:1,2-Bis(4-pyridyl)ethylene 2:1 Cocrystals

The crystal structure landscape of the 2:1 benzoic acid:dipyridylethylene cocrystal (BA:DPE-I) is explored experimentally with fluoro-substituted benzoic acids and extended with studies employing the Cambridge Structural Database (CSD). The interpretation of the cocrystal landscape is facilitated by considering the kinetically favored and robust acidpyridine heterosynthon as a modular unit. Information based on high-throughput crystallography shows that polymorphs and pseudopolymorphs may belong to the same landscape but arise from different crystallization pathways because of complex and different kinetic features, and secondary synthon preferences. Using the CSD as a guide, the coformer was changed from 1,2-bis(4-pyridyl)ethylene (DPE-I) to 1,2-bis(4-pyridyl)ethane (DPE-II) and this provides an extended interpretation of the BA:DPE-I cocrystal landscape, also highlighting the complexity of the kineticthermodynamic dichotomy during the molecule-to-crystal progression.

MRT Letter: A Unified Accelerated Maximum Likelihood Technique for Widefield, Confocal, and Super-Resolution 4Pi Microscopy

We propose an algorithmic technique for accelerating maximum likelihood (ML) algorithm for image reconstruction in fluorescence microscopy. This is made possible by integrating Biggs-Andrews (BA) method with ML approach. The results on widefield, confocal, and super-resolution 4Pi microscopy reveal substantial improvement in the speed of 3D image reconstruction (the number of iterations has reduced by approximately one-half). Moreover, the quality of reconstruction obtained using accelerated ML closely resembles with nonaccelerated ML method. The proposed technique is a step closer to realize real-time reconstruction in 3D fluorescence microscopy. Microsc. Res. Tech. 78:331-335, 2015. (c) 2015 Wiley Periodicals, Inc.

High thermopower and ultra low thermal conductivity in Cd-based Zintl phase compounds

By combining first principles density functional theory and electronic as well as lattice Boltzmann transport calculations, we unravel the excellent thermoelectric properties of Zintl phase compounds ACd(2)Sb(2) (where, A = Ca, Ba, Sr). The calculated electronic structures of these compounds show charge carrier pockets and heavy light bands near the band edge, which lead to a large power factor. Furthermore, we report large Gruneisen parameters and low phonon group velocity indicating essential strong anharmonicity in these compounds, which resulted in low lattice thermal conductivity. The combination of low thermal conductivity and the excellent transport properties give a high ZT value of similar to 1.4-1.9 in CaCd2Sb2 and BaCd2Sb2 at moderate p and n-type doping. Our results indicate that well optimized Cd-based Zintl phase compounds have the potential to match the performance of conventional thermoelectric materials.

In-doped multifilled n-type skutterudites with ZT=1.8

In this paper we maximize the thermoelectric (TE) figure of merit, ZT, of n-type skutterudites, (In,Sr,Ba,Yb)(y)Co4Sb12, via three different routes: (i) find the optimum fraction of In as fourth filler (ii) check the influence of powder particle, grain, and crystallite size on the TE properties and (iii) check thermal stability. Filled n-type (Sr, Ba, Yb)(y)Co4Sb12 was mixed in three different proportions with In0.4Co4Sb12, ball milled (regular or high-energy (HB) ball milling) and hot-pressed. Particle size analyses and SEM pictures of the broken surfaces of the hot pressed samples document that only HB produces uniform particles/grains with average crystallite sizes similar to 100 nm, proven by transmission electron microscopy. X-ray Rietveld refinements combined with EDX indicate that in all cases indium entered the icosahedral voids of the skutterudite. Temperature dependent physical properties of all three regularly ball-milled samples show that increasing In-content infers an increasing electrical resistivity, increasing Seebeck coefficient but a decreasing total thermal conductivity. Although ZT (823 K) is in the same range as for the sample without In, the ZT values in the whole temperature range are higher and consequently the TE-conversion efficiency, eta is at least 10% higher. Annealing the samples at 600 degrees C for three days shows minor changes in structure and thermoelectric properties, indicating TE stability. The HB sample, due to uniformly small particles, equally sized grains and crystallites, exhibits a high power factor (4.4 mW/m K-2 at 730 K) and a very low thermal conductivity leading to an outstanding high ZT = 1.8 at 823 K (eta(max) = 17.5%). (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Isotopic and geochemical characterization of invader tilapia fishes from water bodies of West Bengal and Karnataka, India

The otoliths (N = 12) of freshwater invasive species tilapia (Tilapia mossambicus) collected from two water bodies located at Kolkata and Bangalore, India, were analyzed for stable isotopes (delta 18O, delta 14C) and major and trace elements in order to assess the suitability of using otoliths as a tracer of aquatic environmental changes. The stable isotope analysis was done using the dual inlet system of a Finnigan-MAT 253 isotope ratio mass spectrometer (Thermo-Fisher, Bremen, Germany). Concentrations of major and trace elements were determined using a Thermo X-Series II quadrupole mass spectrometer. The stable isotope composition in tilapia otolith samples from Bangalore and Kolkata water bodies are quite good agreeing with that of the respective lake/pond and rain water. Elemental composition revealed in a pattern of Ca > Fe > Na > Sr > K > Ba > Cr > Mg > As > Mn > Zn > Co > Cu > Cd > Pb. The otoliths from Kolkata pond water are more enriched in Ba, Zn, Pb, Mn, Se, Cu, Zn, Cd, and Ni whereas Cr and As were found to be higher in otolith samples from Bangalore lake. The enrichment factor (EF) values of Cr were higher for both the sampling location in comparison with other metals, although all the studied metals exhibited EF values >1. The PCA shows clustering of metals in the otolith which are related either with the metabolic and physiological attributes or waterborne source. The study demonstrated the potential of stable isotope techniques to distinguish otolith specimens from varied climatic zone, while elemental composition recorded the quality of water at both the locations. The role of climate driving the quality of water can be understood by detailed and continuous monitoring of otolith specimens in the future. Future method allows reconstruction of climate and water quality from old specimens from field exposures or museum collection.

Stimuli-responsive colorimetric and NIR fluorescence combination probe for selective reporting of cellular hydrogen peroxide

Hydrogen peroxide (H2O2) is a key reactive oxygen species and a messenger in cellular signal transduction apart from playing a vital role in many biological processes in living organisms. In this article, we present phenyl boronic acid-functionalized quinone-cyanine (QCy-BA) in combination with AT-rich DNA (exogenous or endogenous cellular DNA), i.e., QCy-BA subset of DNA as a stimuli-responsive NIR fluorescence probe for measuring in vitro levels of H2O2. In response to cellular H2O2 stimulus, QCy-BA converts into QCy-DT, a one-donor-two-acceptor (D2A) system that exhibits switch-on NIR fluorescence upon binding to the DNA minor groove. Fluorescence studies on the combination probe QCy-BA subset of DNA showed strong NIR fluorescence selectively in the presence of H2O2. Furthermore, glucose oxidase (GOx) assay confirmed the high efficiency of the combination probe QCy-BA subset of DNA for probing H2O2 generated in situ through GOx-mediated glucose oxidation. Quantitative analysis through fluorescence plate reader, flow cytometry and live imaging approaches showed that QCy-BA is a promising probe to detect the normal as well as elevated levels of H2O2 produced by EGF/Nox pathways and post-genotoxic stress in both primary and senescent cells. Overall, QCy-BA, in combination with exogenous or cellular DNA, is a versatile probe to quantify and image H2O2 in normal and disease-associated cells.

A Novel Approach for Multispectral Satellite Image Classification Based on the Bat Algorithm

Among the multiple advantages and applications of remote sensing, one of the most important uses is to solve the problem of crop classification, i.e., differentiating between various crop types. Satellite images are a reliable source for investigating the temporal changes in crop cultivated areas. In this letter, we propose a novel bat algorithm (BA)-based clustering approach for solving crop type classification problems using a multispectral satellite image. The proposed partitional clustering algorithm is used to extract information in the form of optimal cluster centers from training samples. The extracted cluster centers are then validated on test samples. A real-time multispectral satellite image and one benchmark data set from the University of California, Irvine (UCI) repository are used to demonstrate the robustness of the proposed algorithm. The performance of the BA is compared with two other nature-inspired metaheuristic techniques, namely, genetic algorithm and particle swarm optimization. The performance is also compared with the existing hybrid approach such as the BA with K-means. From the results obtained, it can be concluded that the BA can be successfully applied to solve crop type classification problems.

Stabilization of a Tetrahedral (Mn5+O4) Chromophore in Ternary Barium Oxides as a Strategy toward Development of New Turquoise/Green-Colored Pigments

An experimental investigation of the stabilization of the turquoise-colored chrornophore (Mn5+O4) in various oxide hosts, viz., A(3)(VO4)(2) (A = Ba, Sr, Ca), YVO4, and Ba2MO4 (M = Ti, Si), has been carried out. The results reveal that substitution of Mn5+O4 occurs in Ba-3(VO4)(2) forming the entire solid solution series Ba-3(V1-x MnxO4)(2) (0 < x <= 1.0), while with the corresponding strontium derivative, only up to about 10% of Mn5+O4 substitution is possible. Ca-3(VO4)(2) and YVO4 do not stabilize Mn5+O4 at all. With Ba2MO4 (M = Ti, Si), we could prepare only partially substituted materials, Ba2M1-xMn5+O4+x/2 for x up to 0.15, that are turquoise-colored. We rationalize the results that a large stabilization of the O 2p-valence band states occurs in the presence of the electropositive barium that renders the Mn5+ oxidation state accessible in oxoanion compounds containing PO43-, VO43-, etc. By way of proof-of-concept, we synthesized new turquoise-colored Mn5+O4 materials, Ba-5(BO3)(MnO4)(2)Cl and Ba-5(BO3)(PO4)(MnO4)Cl, based on the apatite-Ba-5(PO4)(3)Cl-structure.

Producción de biomasa de Cratylia argentea bajo diferentes densidades de siembra y frecuencias de corte en el trópico seco de Nicaragua

El presente estudio se realizó en la finca "Santa Rosa" propiedad de la Universidad Nacional Agraria, localizada geográficamente a 12°08'15" de latitud Norte y 86°09'36" de longitud Este, en el departamento de Managua, en los meses de octubre 2001 a septiembre 2002, se utilizó un diseño de Bloques completamente al azar, con arreglo en parcelas divididas. Se evaluaron los efectos de tres densidades de siembra (40,000, 20,000 y 10,000 Plantas/ha) y tres frecuencias de corte (8, 12 y 16 semanas) sobre la producción de Biomasa de Cratylia argentea. Las variables evaluadas fueron Materia Fresca Total (MFT), Materia Fresca Fracción Fina (MFFF), Materia Fresca Fracción Gruesa (MFFG), Porcentaje de Materia Seca (PMS), Materia Seca Total (MST), Materia Seca Fracción Fina (MSFF), Altura, Tasa de Crecimiento (TC) y Ceniza. Se realizó análisis de varianza y comparaciones con la Prueba de Tukey utilizando MINITAB, versión 13.0. Los resultados en el análisis de varianza (P<0,05) mostraron que la densidad de siembra de 40,000pl/ba presentó los mayores resultados sobre las variables, MFT (59.93 Ton/ha/Año), MFFF (43.5 Ton/ha/Afio), MFFG (13.34 Ton/ha/Año), MST (14.86 Ton MS ha/Año), MSFF (10.59 Ton MS ha/Año) y TC (52.33 Kg MS ha/día), las densidades de siembra no afectaron las variables altura, TC y PMS, la frecuencia de corte de 16 semanas mostró los mejores resultados para las variables MFT (59.58 Ton/ha/Año), MFFG (15.45 Ton/ha/Año), %MS (28.51 %), MST (16.15 Ton MS ha/Año), MSFF (8.75 Ton MS/ha/Año), altura (147.74 cm), Ceniza (12.92 %) y TC (60.06 kg MS ha/día), excepto para MFFF.

Adaptacion de cuatro lineas de alfalfa forrajera (Medicago sativa L.) a las condiciones climaticas de la Hacienda Las Mercedes, campo y vivero

Con el objeto de evaluar el comportamiento adaptativo de cuatro líneas de alfalfa (Medicago sativa L.) en condiciones de campo y de vivero, se realizó un estudio en la Hacienda Las Mercedes, propiedad de la Universidad Nacional Agraria, ubicada en la ciudad de Managua Km 11 carretera norte, , entrada al CARNIC 2 km al lago. Teniendo su ubicación geográfica en un cuadrante con las siguientes coordenadas: 12°10'14"a 12"08'05" en latitud Norte y 86.10'22" a 86"09'44" longitud Oeste. El estudio se realizó en dos fuses 1) de campo y 2) en vivero. En ambos se determinó el grado de adaptación de cuatro líneas de alfalfa (Medicago sativa L.), tres procedentes de Texas-EE UU (8L418, 105916 y 9818) y una de Sébaco-Nicaragua (l3-A50) donde se ha establecido por más de tres años. El ensayo de campo se estableció en un área que anteriormente fue utilizada para la siembra de sorgo forrajero y el de vivero se realizó en el vivero de la UNA, en la misma finca. Se consideró cada una de las líneas como tratamiento. El Diseño experimental usado para ambas fases fue de bloques completos al azar (BCA), con 4 repeticiones. En campo con parcelas experimentales fueron de 4 m2 (2 m x 2 m), para un área total de 120m2 Se sembraron 6 surcos a una distancia de 30 cm entre surco y 14 plantas por surcos distanciados a 15 cm. Se realizó análisis de varianza utilizando programa SAS versión 99, cuando se encontró diferencias significativas o altamente significativas para tratamientos se realizaron pruebas de medias según Duncan. El terreno se preparó de forma convencional, con una chapea inicial, un paso de arado y gradeo de forma mecanizada, posteriormente se realizó la estructuración del diseño de campo. Las variables evaluadas según las condiciones de campo fueron: germinación, altura de la plantas, daños por plaga y enfermedades y ramificación, en las condiciones de vivero fueron: germinación, sobrevivencia, altura (cm), daños por plagas y enfermedades. Como resultado se obtuvo que 3 de las líneas presentaron buena germinación en condiciones de campo y vivero siendo la de mejor comportamiento la línea 13A-50 con un promedio del 97%. Para altura la línea 9818 presentó el mejor comportamiento en condiciones de campo con rangos de 48cm - 58 cm manteniendo superioridad durante el estudio en comparación con el resto de las líneas evaluadas. En daños por plagas la línea 8L418 la de menor afectación, y la más afectada fue la línea l3A-50. En daños por enfermedades la línea 9818 obtuvo los mayores daños en los niveles de moderado a muy grave y la línea l3A-50 fue la de menor incidencia. Todas las líneas presentaron una ramificación media de 30%, siendo la línea 105916 la de mejor comportamiento. En vivero la línea l3A-50 presentó la mejor altura. La línea 9818 fue la de mejor adaptabilidad en condiciones de campo, seguida de la línea BA-50. Pero en condiciones de vivero la línea 13A-50 fue la de mejor adaptabilidad, seguida de la línea 8L418.en resumen la línea l3A-50 fue la de mejor comportamiento adaptativo.

Pulverized-coal combustion in Wall-Protecting-Jets combustor (WPJC)

A new type of pulverized-coal combustor, called "Wall-Protecting-Jets Combustor" (hereafter, WPJC has been proposed, designed and studied with both CFD (Computational Fluid Dynamics) and experimental methods. The WPJC is based on a novel concept in which all inlet jets are along the combustor wall. Pilot combustion experiments were conducted to investigate the combustion performance of WPJC. Two-phase flows and pulverized-coal combustion were simulated to study the mechanism of),WPJC using the commercial software FLUENT. The results show that the WPJC has many remarkable advantages: wall-protection by the cold jets without the use of refractory materials; low-temperature and three-stage combustion with low NOx emission; negligible ash/slag-deposition; multiple functions with convenient switching between them; effective adjustment of the combustion intensity and the ignition position.