Community Structure in Soil Porous System

Diffusion controls the gaseous transport process in soils when advective transport is almost null. Knowledge of the soil structure and pore connectivity are critical issues to understand and modelling soil aeration, sequestration or emission of greenhouse gasses, volatilization of volatile organic chemicals among other phenomena. In the last decades these issues increased our attention as scientist have realize that soil is one of the most complex materials on the earth, within which many biological, physical and chemical processes that support life and affect climate change take place. A quantitative and explicit characterization of soil structure is difficult because of the complexity of the pore space. This is the main reason why most theoretical approaches to soil porosity are idealizations to simplify this system. In this work, we proposed a more realistic attempt to capture the complexity of the system developing a model that considers the size and location of pores in order to relate them into a network. In the model we interpret porous soils as heterogeneous networks where pores are represented by nodes, characterized by their size and spatial location, and the links representing flows between them. In this work we perform an analysis of the community structure of porous media of soils represented as networks. For different real soils samples, modelled as heterogeneous complex networks, spatial communities of pores have been detected depending on the values of the parameters of the porous soil model used. These types of models are named as Heterogeneous Preferential Attachment (HPA). Developing an exhaustive analysis of the model, analytical solutions are obtained for the degree densities and degree distribution of the pore networks generated by the model in the thermodynamic limit and shown that the networks exhibit similar properties to those observed in other complex networks. With the aim to study in more detail topological properties of these networks, the presence of soil pore community structures is studied. The detection of communities of pores, as groups densely connected with only sparser connections between groups, could contribute to understand the mechanisms of the diffusion phenomena in soils.

Microstructure and mechanical properties of physical vapor deposited Cu/W nanoscale multilayers: Influence of layer thickness and temperature

Based on our previous knowledge on Cu/Nb nanoscale metallic multilayers (NMMs), Cu/WNMMs show a good potential for applications as heat skins in plasma experiments and armors, and it could be expected that the substitution of Nb byWwould increase the strength, particularly at high temperatures. To check this hypothesis, Cu/WNMMs with individual layer thicknesses ranging between 5 and 30 nm were deposited by physical vapour deposition, and their mechanical properties were measured by nanoindentation. The results showed that, contrary to Cu/Nb NMMs, the hardness was independent of the layer thickness and decreased rapidlywith temperature, especially above 200 °C. This behavior was attributed to the growth morphology of theWlayers aswell as the jagged Cu/W interface, both a consequence of the lowW adatom mobility during deposition. Therefore, future efforts on the development of Cu/Wmultilayers should concentrate on optimization of theWdeposition parameters via substrate heating and/or ion assisted deposition to increase the W adatom mobility during deposition.

Study of the foundations, bearing soil and stability of the minaret-tower of Cordobas Mosque

This research in Cordoba's mosque tower main objective was to analyze and characterize the foundations and the underlying soil, calculating the stability of the monument as well as the settlement and deformations performed, using traditional calculation methods and also by finite elements, and to determine differences between both, as well as the stability factor of the Minaret Tower. The works done to study the soil, were drill bores and dynamic penetration tests, classification of samples by size, Atterberg limits, physical and chemical analysis, showing the typical geotechnical composition of the Guadalquivir valley: an alluvial material composed by sand, gravels and silt clays. To study the foundations, inclined bore samples were extracted with 10-65º, showing calcarenite stone ashlars and lime concrete alternating with stone and brick masonry.

Evaluating the Effectiveness of Post Fire Emergency Rehabilitation Treatments on Soil Degradation and Erosion Control in Semi-Arid Mediterranean Areas of the Spanish South East

In this study, we seeded a native plant species and applied a mulch of chopped wood originating from the same burned area to avoid the establishment of invasive species. We evaluated four treatments: (1) seeding, (2) mulch, (3) seeding and mulch, and (4) control. Our objective was to increase plant recovery and to minimize the soil erosion and degradation. The study was conducted in Alicante, Spain in Torremanzanas forest of the semi-arid Mediterranean bioclimatic area after the wildfire of November, 2002. During three years of monitoring, we find that combined treatment: seeding and mulch increased the post fire plant recovery 20% approximately more than the rest of treatments and the control plots. We also found that seven months after treating mulch and seeding and mulch treatments presented a gain of soil: +5.18 to + 5.24 mm while the seeding treatment and control plots presented soil loss rates of: −0.48 to −0.49 mm. In addition, mulch treatment significantly decreased soil compaction to the half, and increased the infiltration capacity to 40 ml.mn−1 more than in plots without mulch, as well as increased the soil respiration to the double compared with no mulch plots. Work in progress confirms the positive effect of chopped wood as mulching treatment with or without seeding on the soil protection against soil erosion, and the amelioration of bio-physical properties after wildfires in the Mediterranean semi-arid burned areas.

Characterization and electrochemical properties of conducting nanocomposites synthesized from p-anisidine and aniline with titanium carbide by chemical oxidative method

A novel polymer/TiC nanocomposites “PPA/TiC, poly(PA-co-ANI)/TiC and PANI/TiC” was successfully synthesized by chemical oxidation polymerization at room temperature using p-anisidine and/or aniline monomers and titanium carbide (TiC) in the presence of hydrochloric acid as a dopant with ammonium persulfate as oxidant. These nanocomposites obtained were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), and thermogravimetric analysis (TGA). XRD indicated the presence of interactions between polymers and TiC nanoparticle and the TGA revealed that the TiC nanoparticles improve the thermal stability of the polymers. The electrical conductivity of nanocomposites is in the range of 0.079–0.91 S cm−1. The electrochemical behavior of the polymers extracted from the nanocomposites has been analyzed by cyclic voltammetry. Good electrochemical response has been observed for polymer films; the observed redox processes indicate that the polymerisation on TiC nanoparticles produces electroactive polymers. These nanocomposite microspheres can potentially used in commercial applications as fillers for antistatic and anticorrosion coatings.

Physical and acoustic sediment properties of sediment cores from the eastern equatorial Atlantic

To reconstruct the deep-water circulation for the last 3.5 Ma from deep-sea sediments of the eastern equatorial Atlantic, sea floor morphology, sub-bottom reflectors and the echo character have been mapped on the basis of 3.5 kHz records and sediment cores. Physical properties of sediments and synthetic seismograms derived from them enable us to decipher reflector sequences in environments of pelagic, current-resuspended and turbidity sedimentation. The individual reflectors originate from carbonate dissolution, hiatus, coarse sand layers and interferences. Those which are related to carbonate dissolution and hiatus provide evidence of water-mass boundaries by their distribution. Five phases of different deep-water circulation can be seen in the record of th elast 3.5 Ma, and these are related to climate history: 1. Between 3.7 Ma and 2.2 Ma a strong deep-water circulation indicates a northward flow of bottom water below 4200 m (AABW = Antarctic-Bottom Water) and a southward flow of deep-water above 4200 m (NADW = North-Atlantic Deep Water). 2. Between 1.6 and 1.4 Ma a southward flow of bottom water below 4500 m and a diminished southward flow above 4500 m can be detected. This water-mass geometry can be interpreted by an expansion of the NADW-masses and a displacement of the AABW-masses during the same time. 3. Since 1.4 Ma a northward flow of a bottom-water current developed again. This current flow created a leeside sediment ridge in the southern part of the Kane Gap and furrows in the northern part of it. 4. Between 400,000 and 200,000 yrs B. P. the oceanic and atmospheric circulation increased. The strengthened oceanic circulation caused and increase in carbonate dissolution, which is documented by a traceable reflector from 2800 m to 4500 m water depth. At the same time an increase of the atmospheric circulation caused a drastic rise in the pelagic sediment accumulation (> 100 %) through an intensification of upwelling. This runs parallel with a higher oceanic productivity in the northern equatorial divergence zone and an enhanced supply of fluvial and probably eolian sediments from the Senegal and Guinea. 5. Before 10,000 yrs B. P. an erosive northward flowing bottom-water current prevailed below 4500 m water depth. After 10,000 yrs B.P. the bottom-water flow was sluggish and non erosive.