Geochemistry, isotopic ratios and aldehyde concentrations of frost flowers, snow and ice near Barrow, Alaska

Frost flowers, intricate featherlike crystals that grow on refreezing sea ice leads, have been implicated in lower atmospheric chemical reactions. Few studies have presented chemical composition information for frost flowers over time and many of the chemical species commonly associated with Polar tropospheric reactions have never been reported for frost flowers. We undertook this study on the sea ice north of Barrow, Alaska to quantify the major ion, stable oxygen and hydrogen isotope, alkalinity, light absorbance by soluble species, organochlorine, and aldehyde composition of seawater, brine, and frost flowers. For many of these chemical species we present the first measurements from brine or frost flowers. Results show that major ion and alkalinity concentrations, stable isotope values, and major chromophore (NO3- and H2O2) concentrations are controlled by fractionation from seawater and brine. The presence of these chemical species in present and future sea ice scenarios is somewhat predictable. However, aldehydes, organochlorine compounds, light absorbing species, and mercury (part 2 of this research and Sherman et al. (2012, doi:10.1029/2011JD016186)) are deposited to frost flowers through less predictable processes that probably involve the atmosphere as a source. The present and future concentrations of these constituents in frost flowers may not be easily incorporated into future sea ice or lower atmospheric chemistry scenarios. Thinning of Arctic sea ice will likely present more open sea ice leads where young ice, brine, and frost flowers form. How these changing ice conditions will affect the interactions between ice, brine, frost flowers and the lower atmosphere is unknown.

(Table 2) Ice, snow and freeboard statistics from measurement transects at 11 ice stations during Aurora Australis cruise SIPEX in 2007

The Sea Ice Physics and Ecosystem experiment (SIPEX) was conducted in the East Antarctic pack ice zone between 115-130°E from 9 September - 11 October, 2007. In situ measurements of sea-ice and snow properties were conducted at 15 ice stations, together with ship-based ASPeCt observations. The ice and snow thickness varied considerably in different regions of the pack ice, with particularly thick ice associated with deformation and a strong slope jet in the southwest of the study region. The mean ice thickness was 0.99 m (1.57 m excluding the northern marginal ice zones), but varied from 0.61 m along the southern leg to 1.80 m along the western leg, with pockets of considerably thicker ice in some regions. Swell was observed on two occasions penetrating more than 330 km south of the ice edge into regions with 80-100% ice concentration. Ice thicknesses calculated from near coincident ICESat laser altimetry (1.74 m) are similar to the in-situ observations in the central pack (1.57 m).

Composition of airborne material from yellow snow fallen in the Russian North

Large amounts of dust responsible for bright colors of atmospheric precipitation in the temperate, subpolar and polar zones of the northern hemisphere have been rarely observed. In the twentieth century and in the beginning of the twenty first century in the Northern European Russia such events were not registered up to March 25-26, 2008. At that time in some parts of the Arkhangel'sk region, Komi Republic, and Nenets Autonomous Area atmospheric precipitation as sleet and rain responsible for sand- and saffron colors of ice crust formation on the snow surface was observed. During detailed mineralogical, geochemical, pollen, diatom and meteorological investigations it was established that semidesert and steppe regions of the Northwest Kazakhstan, Volgograd and Astrakhan' regions, and Kalmykia are the main sources of the yellow dust.

Analyzation of marine snow and fecal pellets collected in sediment trap CBi-2 off Cape Blanc, Mauritania

We analyzed size-specific dry mass, sinking velocity, and apparent diffusivity in field-sampled marine snow, laboratory-made aggregates formed by diatoms or coccolithophorids, and small and large zooplankton fecal pellets with naturally varying content of ballast materials. Apparent diffusivity was measured directly inside aggregates and large (millimeter-long) fecal pellets using microsensors. Large fecal pellets, collected in the coastal upwelling off Cape Blanc, Mauritania, showed the highest volume-specific dry mass and sinking velocities because of a high content of opal, carbonate, and lithogenic material (mostly Saharan dust), which together comprised ~80% of the dry mass. The average solid matter density within these large fecal pellets was 1.7 g cm**-3, whereas their excess density was 0.25 ± 0.07 g cm**-3. Volume-specific dry mass of all sources of aggregates and fecal pellets ranged from 3.8 to 960 µg mm**-3, and average sinking velocities varied between 51 and 732 m d**-1. Porosity was >0.43 and >0.96 within fecal pellets and phytoplankton-derived aggregates, respectively. Averaged values of apparent diffusivity of gases within large fecal pellets and aggregates were 0.74 and 0.95 times that of the free diffusion coefficient in sea water, respectively. Ballast increases sinking velocity and, thus, also potential O2 fluxes to sedimenting aggregates and fecal pellets. Hence, ballast minerals limit the residence time of aggregates in the water column by increasing sinking velocity, but apparent diffusivity and potential oxygen supply within aggregates are high, whereby a large fraction of labile organic carbon can be respired during sedimentation.

Ground-based electromagnetic (EM) and drill-hole ice and snow thickness measurements during Polarstern cruise ARK-XVII/2 in 2001

Late-summer thickness distributions of large ice floes in the Transpolar Drift between Svalbard and the North Pole in 1991, 1996, 1998, and 2001 are compared. They have been derived from drilling and electromagnetic (EM) sounding. Results show a strong interannual variability, with significantly reduced thickness in 1998 and 2001. The mean thickness decreased by 22.5% from 3.11 m in 1991 to 2.41 m in 2001, and the modal thickness by 22% from 2.50 m in 1991 to 1.95 m in 2001. Since modal thickness represents the thickness of level ice, the observed thinning reflects changes in thermodynamic conditions. Together with additional data from the Laptev Sea obtained in 1993, 1995, and 1996, results are in surprising agreement with recently published thickness anomalies retrieved from satellite radar altimetry for Arctic regions south of 81.5°N. This points to a strong sensitivity of radar altimetry data to level ice thickness.

Water supply outlook for Arizona and federal-state-private cooperative snow surveys.

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