Geochemical and mineralogical analyses of clay-rich intervals in ODP Sites 166-1006 and 166-1007

The western flank of the Great Bahama Bank, drilled during ODP Leg 166 at seven sites, represents a prograding carbonate sequence from late Oligocene to Holocene [Eberli et al., Proc. ODP Init. Reports 166 (1997)]. The signatures of the detrital input and of diagenetic alteration are evident in clay enriched intervals from the most distal Sites 1006 and 1007 in the Straits of Florida. Mineralogical and chemical investigations (XRD, TEM, SEM, ICP-MS) run on bulk rocks and on the clay fractions enable the origin and evolution of silicate parageneses to be characterized. Plio-Pleistocene silt and clay interbeds contain detrital clay assemblages comprising chlorite, illite, interstratified illite smectite, smectite, kaolinite and palygorskite. The greater smectite input within late Pliocene units than in Pleistocene oozes may relate either varying source areas or change in paleoclimatic conditions and weathering intensity. The clay intervals from Miocene-upper Oligocene wackestone sections are fairly different, with prevalent smectite in the fine fraction, whose high crystallinity and Mg contents that point towards an authigenic origin. The lower Miocene section, below 1104 mbsf, at depths where compaction features are well developed, is particularly characterized by abundant authigenic Na-K-clinoptilolite filling foraminifer tests. The authigenic smectite and clinoptilolite paragenesis is recorded by the chemical trends, both of the sediment and the interstitial fluid. This diagenetic evolution implies Si- and Mg rich fluids circulating in deeper and older sequences. For lack of any local volcaniclastic input, the genesis of zeolite and the terms of water rock interaction are discussed. The location of the diagenetic front correlates with that of the seismic sequence boundary P2 dated as 23.2 Ma. This correspondence may allow the chronostratigraphic significance of some specific seismic reflections to be reassessed.

Mineralogy at DSDP Leg 78A Holes

This chapter deals with the evolution of clay minerals in Cenozoic sediments from DSDP Sites 541, 542, and 543 east of the Lesser Antilles arc on and near the edge of the Barbados Ridge complex. Throughout the Miocene, smectite exceeds all other minerals at all three sites. From the Pliocene onward, however, illite becomes dominant and chlorite well-represented. Quantitative mineral differences among the three sites are significant up until the top of the Pliocene. But in the Pleistocene, the mineralogical composition becomes exactly the same at all sites. Data from the Caribbean region are used to interpret the results obtained. These involve two supply sources: (1) the adjacent islands that supply smectites and kaolinites, and (2) South America, which is the major source of illite and chlorite. The apparent northward migration of illite and chlorite on the Barbados Ridge complex and the changes reported in the quantitative distribution of the four clay minerals are most probably controlled by northerly currents along the northern coast of South America.

Mineralogy micromorphology, and geochemistry at DSDP Site 89-585

At Site 585 of Deep Sea Drilling Project Leg 89 more than 500 m of volcaniclastic to argillaceous middle-Late Cretaceous sediments were recovered. Analyses by X-ray diffraction (bulk sediment and clay fraction), transmission electron microscopy, molecular and atomic absorption, and electron microprobe were done on Site 585 samples. We identify four successive stages and interpret them as the expression of environments evolving under successive influences: Stage 1, late Aptian to early Albian - subaerial and proximal volcanism, chiefly expressed by the presence of augite, analcite, olivine, celadonite, small and well-shaped transparent trioctahedral saponite, Al hydroxides, Na, Fe, Mg, and various trace elements (Mn, Ni, Cr, Co, Pb, V, Zn, Ti). Stage 2, early to middle Albian - submarine and less proximal volcanic influence, characterized by dioctahedral and hairy Mg-beidellites, a paucity of analcite and pyroxenes, the presence of Mg and K, and local alteration of Mg-smectites to Mg-chlorites. Stage 3, middle Albian to middle Campanian - early marine diagenesis, marked by the development of recrystallization from fleecy smectites to lathed ones (all of alkaline Si-rich Fe-beidellite types), by the development of opal CT and clinoptilolite, and by proximal to distal volcanic influences (Na parallel to Ti, K). Local events consist of the supply of reworked palygorskite during the Albian-Cenomanian, and the recurrence of proximal volcanic activity during the early Campanian. Stage 4, late Campanian to Maestrichtian - development of terrigenous supply resulting from the submersion of topographic barriers; this terrigenous supply is associated with minor diagenetic effects and is marked by a clay diversification (beidellite, illite, kaolinite, palygorskite), the rareness of clay recrystallizations, and the disappearance of volcanic markers.

Mineralogy, grain size composition, bulk carbonate isotopic ratios and ages of ODP Site 182-1128 sediments

This report presents mineralogic and geochemical data from Ocean Drilling Program Leg 182 Site 1128 in the Great Australian Bight. Clay mineralogy is dominated by mixed-layer illite-smectite, followed by minor amounts of kaolinite and illite, with intervals of pure smectite. Carbonate mineralogy is exclusively low-Mg calcite, except for one interval of dolomite in lower Oligocene sediments. Carbonate increases significantly in upper Eocene sediments, decreases through the lower Oligocene, then increases again in the Neogene. Quartz is present as a minor component that covaries inversely with carbonate. High-resolution sampling associated with Chron 13 normal (early Oligocene) reveals high-frequency (~23 k.y.) fluctuations in clay mineralogy and carbonate abundance and a positive oxygen and carbon isotope excursion (in bulk carbonates) related to Antarctic glaciation.

Geology, geochemistry, and mineralogy of sediments from the Trans Indian Ocean Geotraverse

The monograph is devoted to the main results of research on the Trans Indian Ocean Geotraverse from the Maskarene Basin to the north-western margin of Australia. These results were obtained by Russian specialists and together with Indian specialists during 15 years of cooperation in investigation of geological structure and mineral resources of the Indian Ocean. The monograph includes materials on information support of marine geological and geophysical studies, composition and structure of information resources on the Indian Ocean, bathymetry and geomorphology, structure and geological nature of the magnetic field, gravity field, plate tectonics, crustal structure and sedimentary cover, seismic stratigraphy, perspectives for detecting oil and gas, solid minerals, sediment composition, composition and properties of clay minerals, stratigraphy and sediment age, chemical composition of sediments, composition of and prospects for solid minerals.

Biostratigraphy, magnetostratigraphy, granulometry, isotopes and clay mineral composition of ODP Site 188-1165

During Ocean Drilling Program Leg 188 to Prydz Bay, East Antarctica, several of the shipboard scientists formed the High-Resolution Integrated Stratigraphy Committee (HiRISC). The committee was established in order to furnish an integrated data set from the Pliocene portion of Site 1165 as a contribution to the ongoing debate about Pliocene climate and climate evolution in Antarctica. The proxies determined in our various laboratories were the following: magnetostratigraphy and magnetic properties, grain-size distributions (granulometry), near-ultraviolet, visible, and near-infrared spectrophotometry, calcium carbonate content, characteristics of foraminifer, diatom, and radiolarian content, clay mineral composition, and stable isotopes. In addition to the HiRISC samples, other data sets contained in this report are subsets of much larger data sets. We included these subsets in order to provide the reader with a convenient integrated data set of Pliocene-Pleistocene strata from the East Antarctic continental margin. The data are presented in the form of 14 graphs (in addition to the site map). Text and figure captions guide the reader to the original data sets. Some preliminary interpretations are given at the end of the manuscript.

Characteristics and distribution of Neogene turbidites at ODP Site 108-657

Numerous and variable silty-sandy siliciclastic turbidites were observed in Neogene pelagic sediments (late Miocene to Holocene) at Site 657: (1) thick-bedded, coarse-grained and thin-bedded, fine-grained turbidites; and (2) turbidites composed of eolian dune sand and shallow-water bioclasts or of fluvial-sand or mixed sandy component assemblages. The stratigraphic distribution of these turbidites indicates five periods during which climatic conditions and material sources change. Turbidite occurrence prior to 6.2 Ma (late Miocene) is sparse; the deposits contain coarse and fine-grained turbidites with quartz grains of eolian or mixed origin suggesting the existence of arid conditions at about 8.5 and 6.5 Ma. A coarse-grained turbidite of fluvial origin, recording a humid climate, occurs at about 6.2 Ma. During the early Pliocene, turbidites are frequent (15/Ma); they contain only fine-grained sequences comprising material of mixed origin, which indicates a more humid climate perhaps. The late Pliocene starts with rare coarse-grained turbidites of wind-transported sand while the uppermost Pliocene deposits show a higher frequency of fine-grained sequences (10/0.7 Ma) composed mainly of fluvial material. During the early Pleistocene, similar high turbidite frequency was observed (20/1.3 Ma) but with a total lack of eolian supply. During the last 0.7 Ma, the frequency decreases and the sequences are characterized by highly variable sediment components that could be related to strong variations of climatic conditions. The sedimentary characteristics of turbidites are mainly controlled by sediment source and climate. The frequency must be influenced by sea-level variations, by cyclic processes of climatic origin, and possibly by variations in the continental slope morphology. Clay mineral assemblages suggest a south Saharan source of terrigenous material during the late Miocene and the Pliocene and a northwest Saharan source during the Pleistocene.

Mineralogy and geochemistry of aerosols from the Western Pacific

Aerosols collected by net method over the Western Pacific were investigated. Distribution of eolian material, its mineral and chemical compositions are controlled by the climatic and circumcontinental zonalities. It was stated that Fe and Mn were bound with mineral components of aerosols, while trace elements are bound with organogenic matter. Fluxes of aerosols and their components on the ocean surface were determined.

Mineralogy, geochemistry and benthic foraminifera of the Gorrondatxe beach section

A distinctive low-carbonate interval interrupts the continuous limestone-marl alternation of the deep-marine Gorrondatxe section at the early Lutetian (middle Eocene) C21r/C21n Chron transition. The interval is characterized by increased abundance of turbidites and kaolinite, a 3 per mil decline in the bulk d13C record, a >1 per mil decline in benthic foraminiferal d13C followed by a gradual recovery, a distinct deterioration in foraminiferal preservation, high proportions of warm-water planktic foraminifera and opportunistic benthic foraminifera, and reduced trace fossil and benthic foraminiferal diversity, thus recording a significant environmental perturbation. The onset of the perturbation correlates with the C21r-H6 event recently defined in the Atlantic and Pacific oceans, which caused a 2°C warming of the seafloor and increased carbonate dissolution. The perturbation was likely caused by the input of 13C-depleted carbon into the ocean-atmosphere system, thus presenting many of the hallmarks of Paleogene hyperthermal deposits. However, from the available data it is not possible to conclusively state that the event was associated with extreme global warming. Based on our analysis, the perturbation lasted 226 kyr, from 47.44 to 47.214 Ma, and although this duration suggests that the triggering mechanism may have been similar to that of the Paleocene-Eocene Thermal Maximum (PETM), the magnitude of the carbon input and the subsequent environmental perturbation during the early Lutetian event were not as severe as in the PETM.

Clay mineralogy of late Eocene to early Miocene sediments of McMurdo Sound, Antarctica

The clay mineral assemblages of upper Eocene to lower Miocene sediments recovered at the CIROS-1 and MSSTS-1 drill sites on the McMurdo Sound shelf, Antarctica, were analyzed in order to reconstruct the Cenozoic Antarctic paleoclimate and ice dynamics. The assemblages are dominated by smectite and illite, with minor amounts of chlorite and kaolinite. The highest smectite amounts and best smectite crystallinities occur in the upper Eocene part of CIROS-1, below 425-445 mbsf. They indicate that during their deposition, chemical weathering conditions prevailed on the nearby continent. Large parts of East Antarctica were probably ice-free at that time, but some glaciers reached the sea and contributed to the glaciomarine sedimentation. In contrast, only minor total amounts of smectite are present in Oligocene and younger sediments due to the shift to mainly physical weathering on an ice-covered Antarctic continent. However, relative smectite percentages rise to more than 60% during two late Oligocene intervals (ca. 27.5-26.2 and 25.0-24.5 Ma) and during one early Miocene interval starting at ca. 23.3 Ma. These intervals are characterized by ice masses coming probably from the south, where volcanic rocks acted as a source, as also indicated by the composition of the sand and gravel fractions. During the other intervals, the ice came from the west, where the physical erosion of basement rocks and sedimentary rocks of the Beacon Supergroup in the Transantarctic Mountains provided high illite concentrations. Because the two drill sites are only 4 km apart, their clay mineral records can be correlated. This led to a new interpretation of the Oligocene paleomagnetic data of the MSSTS-1 site and to a more detailed lithostratigraphic correlation of the Miocene parts of the cores.

Clay mineralogy on five NBP cores

During 2006, the SHALDRIL program recovered cores of Eocene through Pliocene material at four locations in the northwestern Weddell Sea, each representing a key period in the evolution of the Antarctic Peninsula ice cap. The recovered cores are not continuous, yet they provide a record of climate change with samples from the late Eocene, late Oligocene, middle Miocene, and early Pliocene and represent the only series of samples recovered from the northwestern Weddell Sea and spanning the Cenozoic and the initial growth of the peninsula ice cap. Late Eocene sediments sampled in the James Ross Basin are typically characterized by very dark greenish-gray muddy fine sand with some preserved burrowing and are interpreted to represent a shallow water continental shelf setting. Rare dropstones, primarily of well-cemented sandstones and minor ice-rafted material consisting of angular grains with glacially influenced surface features record the onset of mountain glaciation, the earliest such evidence in the region. The remaining cores were collected on the Joinville Plateau to the north of the James Ross Basin. The late Oligocene sediments consist of dark gray sandy mud with some clay lenses and many burrows, likely representing a distal delta or shelf setting. This core contains only very few and small dropstones, and the individual grains show decreased angularity and fewer glacial surface features relative to late Eocene deposits. The middle Miocene strata are composed of pebbly gray diamicton, representing proximal glacimarine sediments. The lower Pliocene section also contains many ice-rafted pebbles but is dominated by sandy units rather than diamicton and is interpreted to represent a current-winnowed deposit, similar to the modern contour current-influenced sediments of the region.

Eolian deposition on the Ontong Java Plateau

The record of eolian deposition on the Ontong Java Plateau (OJP) since the Oligocene (approximately 33 Ma) has been investigated using dust grain size, dust flux, and dust mineralogy, with the goal of interpreting the paleoclimatology and paleometeorology of the western equatorial Pacific. Studies of modern dust dispersal in the Pacific have indicated that the equatorial regions receive contributions from both the Northern Hemisphere westerly winds and the equatorial easterlies; limited meteorological data suggest that low-altitude westerlies could also transport dust to OJP from proximal sources in the western Pacific. Previous studies have established the characteristics of the grain-size, flux, and mineralogy records of dust deposited in the North Pacific by the mid-latitude westerlies and in the eastern equatorial Pacific by the low-latitude easterlies since the Oligocene. By comparing the OJP records with the well-defined records of the mid-latitude westerlies and the low-latitude easterlies, the importance of multiple sources of dust to OJP can be recognized. OJP dust is composed of quartz, illite, kaolinite/chlorite, plagioclase feldspar, smectite, and heulandite. Mineral abundance profiles and principal components analysis (PCA) of the mineral abundance data have been used to identify assemblages of minerals that covary through all or part of the OJP record. Abundances of quartz, illite, and kaolinite/chlorite covary throughout the interval studied, defining a mineralogical assemblage supplied from Asia. Some plagioclase and smectite were also supplied as part of this assemblage during the late Miocene and Pliocene/Pleistocene, but other source areas have supplied significant amounts of plagioclase, smectite, and heulandite to OJP since the Oligocene. OJP dust is generally coarser than dust deposited by the Northern Hemisphere westerlies or the equatorial easterlies, and it accumulates more rapidly by 1-2 orders of magnitude. These relationships indicate the importance of the local sources on dust deposition at OJP. The grain-size and flux records of OJP dust do not exhibit most of the events observed in the corresponding records of the Northern Hemisphere westerlies or the equatorial easterlies, because these features are masked by the mixing of dust from several sources at OJP. The abundance record of the Asian dust assemblage at OJP, however, does contain most of the features characteristic of dust flux by means of the Northern Hemisphere westerlies, indicating that the paleoclimatic and paleometeorologic signal of a particular source area and wind system can be preserved in areas well beyond the region dominated by that source and those winds. Identifying such a signal requires "unmixing" the various dust assemblages, which can be accomplished by combining grain-size, flux, and mineralogic data.