Optical recording properties of metal-azo dye as recording medium with super-resolution near-field structure

A novel metallized azo dye has been synthesized. The absorption spectra of the thin film and thermal characteristic are measured. Static optical recording properties with and without the Bi mask layer super-resolution near-field structure (Super-RENS) of the metal-azo dye are investigated. The results show that the metal-azo dye film has a broad absorbance band in the region of 450-650 nm and the maximum absorbance wavelength is located at 603 nm. It is also found that the new metallized azo dye occupies excellent thermal stability, initiatory decomposition temperature is at 270 degrees C and the mass loss is about 48% in a narrow temperature region (15 degrees C). The complex refractive index N (N = n + ik) is measured. High refractive index (n = 2.45) and low extinction coefficient (k = 0.2) at the recording wavelength 650nm are attained. Static optical recording tests with and without Super-RENS are carried out using a 650nm semiconductor diode laser with recording power of 7mW and laser pulse duration of 200ns. The AFM images show that the diameter of recording mark on the dye film with the Bi mask layer is reduced about 42%, compared to that of recorded mark on the dye film without Super-RENS. It is indicated that Bi can well performed as a mask layer of the dye recording layer and the metallized azo dye can be a promising candidate for recording media with the super-resolution near-field structure.

Thiophene-fluorene derivatives with high three-photon absorption activities and their application to optical power limiting

The three-photon absorption (3PA) properties of two thiophene-fluorene derivatives (abbreviated as MOTFTBr and ATFTBr) have been determined by using a Q-switched Nd:YAG laser pumped wish 38ps pulses at 1064nm in DMF. The measured 3PA cross-sections are 152x10(-78)cm(6)s(2) and 139x10(-78)cm(6)s(2), respectively. The optimized structures were obtained by AM1 calculations and the results indicate that these two molecules show nonplanar structures, and attaching different donors has different effects on the molecular structure. The charge density distributions during the excitation were also systematically studied by using AM1 method. In addition, an obvious optical power limiting effect induced by 3PA has been demonstrated for both derivatives.

一种新的芴类衍生物的三光子吸收诱导荧光和光限幅效应研究

通过对新合成的芴的一种具有对称性衍生物4-2-（7-（4-氨基苯乙烯基）-9，9-二（2-乙基己基）-9H-芴-2-）乙烯基）苯胺（BASF）的DMF溶液的研究，发现其具有很强三光子吸收频率上转换荧光发射特性，实验测出上转换荧光的波长范围是456-775nm，在510nm处的荧光强度与入射光强的三次方成正比．在0．03mol／L的浓度下就有明显的三光子吸收诱导的光限幅效应．非线性吸收系数和吸收截面分别为y=4．34×10^20 cm^3／W^2和σ3=2．4×10^-39 cm^6／W^2．

超大功率二维半导体激光列阵并路自适应稳模技术

半导体列阵量子效率高,输出波长范围涵盖570～1600nm,工作寿命可达数百万小时,叠层列阵可提供超高功率激光输出,在工业、医学等很多领域具有非常广阔的应用前景。但列阵在自由运行时,各发光单元发出的光是不相干的,输出质量差,采用1/4Talbot外腔镜耦合技术,列阵实现了空间锁相最高阶超模,然而唯有基超模远场分布是中心单瓣结构,输出接近衍射极限。为得到最小谱宽、最小发散角、最大功率密度输出,必须将外腔镜倾斜β=λ/2d(λ为工作波长,d为列阵周期),这使得仅有基超模光能成像于发光单元内而被允许振荡。应用此

Cr~(2+):ZnSe的激光输出和调谐性能

Cr~(2+):ZnSe具有很宽的吸收带和发射带,是中红外波段优秀的可调谐激光材料。从吸收光谱、发射光谱以及角度调谐输出对Cr~(2+):ZnSe晶体的激光输出性能进行了研究。采用真空高温扩散法制备Cr~(2+):ZnSe晶体.获得了高浓度的Cr~(2+)离子掺杂的厚1.7 mm,直径10 mm的薄片ZnSe晶体。使用中心波长2.05μm,最大输出功率8 W的Tm离子掺杂的光纤激光器抽运,使用平凹腔结构搭建谐振腔,获得了最大平均功率1.034 W,中心波长2.367μm,线宽10 nm的连续激光输出。利用角度调谐的方法,对Cr:ZnSe晶体的调谐性能进行了研究,在100 nm范围内获得了调谐输出。

改善高功率激光二极管阵列光束质量的一种新方法

根据波导模理论,推导了高功率激光二极管阵列的远场分布,根据其分布特点,设计了一种离轴外腔.运用这种外腔,在工作电流为17A时,光束的束宽积从自由运转时的1100mm.mrad减小到128mm.mrad,二极管阵列的光束质量提高了8.5倍左右,输出功率约为自由运转时的75%.

LD 侧面抽运Nd :YAG陶瓷激光器运转条件下归一化热参数优化理论及实验研究

The suppressing effect of laser extraction on the non-radiation transition process is taken into account when the heat model of gain media is developed. Based on the developed heat model, the heat generation in the operating LD side-pumped Nd: YAG ceramic lasers is quantified through using the normalized heating parameter, which can be deduced from the experimental results of the slope efficiency and the absorbed pumping power of the gain media. The main factors which influence on the heat generation are investigated by studying the normalized heating parameter, and the results show that the changes of the laser extraction efficiency, the beam overlap efficiency and the Nd3+ concentration will result in obvious variations of the normalized heating parameter. In this work, the laser extraction efficiency increases to 0.905 by the optimization of the transmission of the output coupling, and the normalized heating parameter decrease to 0.474, correspondingly.

Cr^4＋：YAG被动调QNd：YAG陶瓷激光器的研究

介绍了近几年迅速发展的一种新型激光介质——透明Nd：YAG多晶陶瓷的发展状况，对比分析了多晶陶瓷与单晶的光谱特性、激光特性和连续实验研究情况。并对钛宝石激光器调谐至808nm，端面抽运Nd：YAG陶瓷被动调Q全固态激光器的脉冲运转进行了较为详细的理论分析和实验研究。采用初始透射率为90％的Cr^4＋：YAG可饱和吸收晶体，被动调Q的阈值功率为119mW，当端面抽运功率为465mW时，获得波长为1064nm，脉宽为16ns，重复频率为18．18kHz，单脉冲能量为3．4μJ，平均输出功率为61mW的稳定调Q

高功率板条激光器的研究进展

板条激光器，特别是LD抽运的板条激光器，作为高功率同体激光器的一个重要发展方向，在军用和工业应用等领域有着较好的应用前景。综述了板条激光器的抽运、冷却方式以及谐振腔设计方面的进展，并对其应用前景进行展望。

半导体激光直接倍频的488nm蓝光激光器

利用波导型准相位匹配周期极化反转铌酸锂（PPLN）晶体直接倍频波长为976nm的连续半导体激光二极管，在最佳晶体工作温度（28℃）下，获得了波长为488nm的连续蓝光输出，最大输出功率大于20mW。所用的晶体尺寸为8mm×1．4mm×1mm，波导截面为4．5μm×3．5μm，极化周期为5．2μm。研究了波导型周期极化反转铌酸锂晶体的倍频效率与温度的关系，与普通的周期极化反转铌酸锂相比，倍频效率与温度关系的敏感度较低。同时，由于晶体可以在室温下工作，简化了加温与温控部件，提高了整机的工作效率。在此实验的基础

部分端面抽运的Nd：YVO4板条固体激光器

利用自制高功率激光二极管（LD）列阵堆和波导整形抽运耦合系统，将抽运光耦合至Nd：YVO4板条晶体，平平腔运转得到了1.064μm的偏振激光输出。在最大抽运功率为84W时，透过率为10％的输出腔镜得到了31W的激光功率输出，光一光效率37％，斜效率45％，板条晶体两个方向的输出光束质量差别较大。为了进一步提高光束质量，使用柱面镜混合腔结构，在最大抽运功率为86W时，得到了19．3W的1064nm激光输出，测得的非稳腔和稳腔两个方向的M^2因子分别为1.4和1．7。

大功率线阵激光二极管侧面抽运Nd：YAG激光器特性研究

对激光二极管（LD）抽运固体激光器中大功率线阵激光二极管三向对称侧面抽运的漫反射腔结构进行了研究。激光器使用Nd：YAG作为激光晶体，电光器件材料为KD^＊P晶体，漫反射体为陶瓷材料。实验表明，抽运光的利用率和均匀性有较大提高。在重复频率为10Hz下，实现了脉冲宽度8ns，最大平均功率为近2W的1064nm红外激光输出，激光器的效率有显著提高。

钛宝石激光器端面抽运Nd：YAG陶瓷激光器热沉积理论和实验研究

通过热沉积系数研究在激光提取条件下掺杂原子分数为1.0%的Nd：YAG陶瓷激光器中热沉积问题.热沉积系数定义为热沉积功率与激光器输出功率之比.在理论分析基础上,通过测量激光器斜率效率来间接测定热沉积系数,实验测定的热沉积系数值为0.63.建立激光提取条件下Nd：YAG陶瓷发热模型,讨论了影响热沉积系数的主要因素.结果表明：热沉积系数对Nd：YAG陶瓷的辐射量子效率、交叠效率以及激光提取效率的变化非常敏感.为有效减少介质内热沉积,在激光器优化设计中交叠效率和激光提取效率是需要着重考虑的参数.所得结果可为进一

部分端面抽运板条激光器腔镜倾斜问题研究

部分端面抽运的板条激光器是一种新型固体激光器．配合混合腔可以实现在大功率下保持高光束质量的激光振荡输出。谐振腔的腔镜倾斜是影响激光器输出特性的重要因素，快速傅里叶方法是一种快捷有效的计算方法，利用此方法模拟了腔镜倾斜对近场相位分布和远场光强分布的影响，并分析了光束质量的变化。理论分析表明，腔镜的小角度倾斜对近场相位影响较大，但对远场光强空间分布影响不大；随着倾斜角度不断增大，远场发散角和光束腰宽度也增大，光束质量虽然存在恶化的趋势，但光束质量因子肝值仍然较小，离轴非稳腔仍能保持高光束质量的输出。

板条激光放大器中寄生振荡的研究

寄生振荡的存在使得放大器在信号光到达之前消耗了大量的反转粒子数,降低了放大器的激光增益和储能效率,严重地影响了激光放大器的性能,尤其对高功率激光放大器。在理论分析和实验研究的基础上,以Nd∶YAG晶体板条为例,用8条半导体激光阵列对晶体进行双侧抽运,研究了高功率激光放大器的寄生振荡现象,分析了板条晶体寄生振荡产生的原因,并详细比较了晶体在不同的抽运功率和表面处理下的放大效果,得到了2倍的单程放大,当输入能量为140 mJ时,获得了278 mJ的激光输出。