Stable chlorine isotopes in pore waters from DSDP Hole 79-546 and ODP Hole 131-808C

Stable Cl isotope ratios, measured in marine pore waters associated with the Barbados and Nankai subduction zones, extend significantly (to ~-8 per mil) the range of d37Cl values reported for natural waters. These relatively large negative values, together with geologic and chemical evidence from Barbados and Nankai and recent laboratory data showing that hydrous silicate minerals (i.e., those with structural OH sites) are enriched up to 7.5 per mil in 37Cl relative to seawater, strongly suggest that the isotopic composition of Cl in pore waters from subduction zones reflects diagenetic and metamorphic dehydration and transformation reactions. These reactions involve clays and/or other hydrous silicate phases at depth in the fluid source regions. Chlorine therefore cannot be considered geochemically conservative in these systems. The uptake of Cl by hydrous phases provides a mechanism by which Cl can be cycled into the mantle through subduction zones. Thus, stable Cl isotopes should help in determining the extent to which Cl and companion excess volatiles like H2O and CO2 cycle between the crust and mantle.

Investigation of Bacteria in coastal waters of King George Island

We determined the numbers of free-living and associated (aggregated or bonded with particles) bacteria in the coastal water of King George Island at an offshore (St. 1) and a nearshore station (St. 2) as a function of physico-chemical parameters. Water sampIes were collected between March and October at St. 1 and between April and October at St. 2. Direct counts of total bacteria varied from 0.53*10**8 to 5.02*10**8 cells/l. Associated microorganisms accounted for 5 to 20 % of the total number of bacteria. Strong Spearman and Pearson correlations were observed (R = 0.82; P = 0.001) between the numbers of free-living and associated bacteria at St. 1. These two groups of bacteria were nearly evenly distributed in the horizontal transects from inshore to offshore waters at depths of 1-10 m in Ardley Cove. There were no substantial differences in the numbers of either free-living or associated bacteria in vertical transects too. Their number at St. 1, but not at St. 2, correlated significantly with all tested environmental parameters (salinity, temperature, solar radiation, nitrate, phosphate and chlorophyll a concentrations), except nitrite concentrations in water. The most probable reason for these correlations is that a common seasonal trend is characteristic of most tested parameters during the March to October period.

Contaminant concentrations in ivory gull (Pagophila eburnea) eggs from Svalbard and the Russian Arctic (2006-2007)

We found high levels of contaminants, in particular organochlorines, in eggs of the ivory gull Pagophila eburnea, a high Arctic seabird species threatened by climate change and contaminants. An 80% decline in the ivory gull breeding population in the Canadian Arctic the last two decades has been documented. Because of the dependence of the ivory gull on sea ice and its high trophic position, suggested environmental threats are climate change and contaminants. The present study investigated contaminant levels (organochlorines, brominated flame retardants, perfluorinated alkyl substances, and mercury) in ivory gull eggs from four colonies in the Norwegian Svalbard) and Russian Arctic (Franz Josef Land and Severnaya Zemlya). The contaminant levels presented here are among the highest reported in Arctic seabird species, and we identify this as an important stressor in a species already at risk due to environmental change.