Supramolecular Organization of Dye Molecules in Zeolite L Channels: Synthesis, Properties, and Composite Materials

Sequential insertion of different dyes into the 1D channels of zeolite L (ZL) leads to supramolecular sandwich structures and allows the formation of sophisticated antenna composites for light harvesting, transport, and trapping. The synthesis and properties of dye molecules, host materials, composites, and composites embedded in polymer matrices, including two- and three-color antenna systems, are described. Perylene diimide (PDI) dyes are an important class of chromophores and are of great interest for the synthesis of artificial antenna systems. They are especially well suited to advancing our understanding of the structure–transport relationship in ZL because their core fits tightly through the 12-ring channel opening. The substituents at both ends of the PDIs can be varied to a large extent without influencing their electronic absorption and fluorescence spectra. The intercalation/insertion of 17 PDIs, 2 terrylenes, and 1 quaterrylene into ZL are compared and their interactions with the inner surface of the ZL nanochannels discussed. ZL crystals of about 500 nm in size have been used because they meet the criteria that must be respected for the preparation of antenna composites for light harvesting, transport, and trapping. The photostability of dyes is considerably improved by inserting them into the ZL channels because the guests are protected by being confined. Plugging the channel entrances, so that the guests cannot escape into the environment is a prerequisite for achieving long-term stability of composites embedded in an organic matrix. Successful methods to achieve this goal are described. Finally, the embedding of dye–ZL composites in polymer matrices, while maintaining optical transparency, is reported. These results facilitate the rational design of advanced dye–zeolite composite materials and provide powerful tools for further developing and understanding artificial antenna systems, which are among the most fascinating subjects of current photochemistry and photophysics.

Remote Monitoring of Fish in Small Streams: A Unified Approach Using Pit Tags

Accurate assessments of fish populations are often limited by re-observation or recapture events. Since the early 1990s, passive integrated transponders (PIT tags) have been used to understand the biology of many fish species. Until recently, PIT applications in small streams have been limited to physical recapture events. To maximize recapture probability, we constructed PIT antenna arrays in small streams to remotely detect individual fish. Experiences from two different laboratories (three case studies) allowed us to develop a unified approach to applying PIT technology for enhancing data assessments. Information on equipment, its installation, tag considerations, and array construction is provided. Theoretical and practical definitions are introduced to standardize metrics for assessing detection efficiency. We demonstrate how certain conditions (stream discharge, vibration, and ambient radio frequency noise) affect the detection efficiency and suggest that by monitoring these conditions, expectations of efficiency can be modified. We emphasize the importance of consistently estimating detection efficiency for fisheries applications.

Sediment volume variations inferred from DGPS measurements within Bossons glacier proglacial area (Mont-Blanc massif, France)

This dataset presents Differential Global Positioning System data (DGPS) acquired within the Bossons glacier proglacial area. Bossons glacier is a rapidly retreating glacier and its proglacial area is deglaciated for ~30 years. Bossons stream is one of the outlets of the subglacial drainage system. It starts as a 800 m steep cascade reach, then flows through an area with gentler slope : the Plan des Eaux (PdE). PdE is a 300 m long, 50 m wide proglacial alluvial plain with an increasing channel mobility in the downstream direction but decreasing slope gradient and incision. As it may act a sediment trap, studying periglacial and proglacial erosion processes in the Bossons catchment requires to quantify PdE sediment volume evolution. A several meter-sized block located within Bossons proglacial area was set up as GPS base : its location was measured by one antenna (Topcon Hyper Pro) by performing 600 consecutive measurements throughout one day. A second antenna (Topcon Hyper Pro) was then used to measure XYZ location of points in the proglacial area with a ~2 m grid. Radio communication between the two antennas allowed differential calculations to be automatically carried out on field using the Topcon FC-250 hand controller. This methodology yields 3 cm XY and 1.5 cm Z uncertainties. DGPS data have been acquired through 10 campaigns from 2004 to 2014; campaigns from 2004 to 2008 cover a smaller area than those from 2010 to 2014. Digital Elevation Model (DEM) have been interpolated from DGPS data and difference between two DEMs yields deposited and eroded volume within PdE. Maps of PdE volume variation between two campaigns show that incision mainly occurs in the upper and lower sections where as deposition dominates in the middle section. Deposition, denudation and net rate (deposition rate - denudation rate) are calculated by normalizing volumes by DEM areas. Deposition dominates results with a mean net rate of 29 mm/yr. However, strong inter-annual variability exists and some years are dominated by denudation : -36 mm/yr and -100 mm/yr for 2006 and 2011, respectively. Nonetheless, oldest campaigns (2004 to 2008) were carried out on the lower part part of the alluvial plain and ruling them out to keep only complete DEM (2010 to 2014) yields a mean net rate of ~15 mm/yr. This results is coherent with field observations of both strong deposition (e.g. flood deposits) and strong erosion (e.g. 30 cm incision) evidences. Bossons glacier proglacial area is thus dynamic with year-to-year geormorphological changes but may leans toward increasing its mean elevation through a deposition dominated system.

Long-term environmental time series of continuously collected data in hydroelectric reservoirs in Brazil

Long-term environmental time series of continuously collected data are fundamental to identify and classify pulses and determine their role in aquatic systems. This paper presents a web based archive for limnological and meteorological data collected by integrated system for environmental monitoring (SIMA). The environmental parameters that are measured by SIMA are: chlorophyll-a (µg/L), water surface temperature (ºC), water column temperature by a thermistor string (ºC), turbidity (NTU), pH, dissolved oxygen concentration (mg/L), electric conductivity (µS/cm), wind speed (m/s) and direction (º), relative humidity (%), short wave radiation (W/m**2), barometric pressure (hPa). The data are collected in preprogrammed time interval (1 hour) and are transmitted by satellite in quasi-real time for any user in a range of 2500 km from the acquisition point. So far 11 hydroelectric reservoirs being monitored using the SIMA buoy. A basic statistics (mean and standard deviation) for some parameters and an example of time series were displayed. The main observed problem are divided into sensors and satellite. The sensors problems is due to the environmental characteristics of each water body. In acid waters the sensors of water quality rapidly degrade, and the collected data are invalid. Another problem is the infestation of periphyton in the sensor. SIMA buoy makes the parameters readings every hour, or 24 readings per day. However, not always received all readings because the system requires satellites passing over the buoy antenna to complete the transfer and due to the satellite constellation position, some locations inland are not met as often as necessary to complete all transmissions. This is the more often causes for lack in the time series.

Plume-top altitude time-series during May 2011 volcanic eruption of Grímsvötn, Iceland

Plume-top altitude time series of the volcanic plume during the eruption of Grímsvötn in Iceland 21-28 May 2011. The altitude was estimated from weather radar echo top data from two weather radars, Keflavik and Klaustur. Keflavik radar is a fixed position C-band weather radar close to Keflavik International Airport, at 64°01.583'N, 22°38.150'W. The height of the antenna is 47 m a.s.l. and the distance to Grímsvötn volcano is 257 km. Klaustur radar is a mobile X-band weather radar located close to Kirkjubaejarklaustur, at 63°46.500'N, 17°57.817'W. The height of the antenna is also 47 m a.s.l. and the distance to Grímsvötn volcano is 75 km.

14 ground-penetrating radar lines of Area 5 - Periglacial outwash plain from Potter Cove, King George Island, Antarctic Peninsula

During a field campaign in the Austral spring 2012 the sedimentary architecture of a periglacial flood plain at the northeastern coast of Potter Peninsula (Area 5) was revealed using ground-penetrating radar (GPR, Geophysical Survey Systems, Inc. SIR-3000). 14 profiles were collected using a mono-static 200 MHz antenna operated in common offset mode. Trace increment was set to 0.05 m. A differential global-positioning system (dGPS, Leica GS09) was used to obtain topographical information along the GPR lines. GPR data are provided in RADAN-Format, dGPS coordinates are provided in ascii format; projection is UTM (WGS 84, zone 21S).

31 ground-penetrating radar lines of Area 3 - Beach ridge plain (high wave energy) from Maxwell Bay, King George Island, Antarctic Peninsula

During a field campaign in the Austral spring 2012 the sedimentary architecture of a polar gravel-beach system at the southern coast of Potter Peninsula (Area 3) was revealed using ground-penetrating radar (GPR, Geophysical Survey Systems, Inc. SIR-3000). 31 profiles were collected using a mono-static 200 MHz antenna operated in common offset mode. Trace increment was set to 0.05 m. A differential global-positioning system (dGPS, Leica GS09) was used to obtain topographical information along the GPR lines. GPR data are provided in RADAN-Format, dGPS coordinates are provided in ascii format; projection is UTM (WGS 84, zone 21S).

Radar profiles from South Shetland Islands/Western Antarctic Peninsula

The sedimentary architecture of polar gravel-beach ridges is presented and it is shown that ridge internal geometries reflect past wave-climate conditions. Ground-penetrating radar (GPR) data obtained along the coasts of Potter Peninsula (King George Island) show that beach ridges unconformably overlie the prograding strand plain. Development of individual ridges is seen to result from multiple storms in periods of increased storm-wave impact on the coast. Strand-plain progradation, by contrast, is the result of swash sedimentation at the beach-face under persistent calm conditions. The sedimentary architecture of beach ridges in sheltered parts of the coast is characterized by seaward-dipping prograding beds, being the result of swash deposition under stormy conditions, or aggrading beds formed by wave overtopping. By contrast, ridges exposed to high-energy waves are composed of seaward- as well as landward-dipping strata, bundled by numerous erosional unconformities. These erosional unconformities are the result of sediment starvation or partial reworking of ridge material during exceptional strong storms. The number of individual ridges which are preserved from a given time interval varies along the coast depending on the morphodynamic setting: sheltered coasts are characterized by numerous small ridges, whereas fewer but larger ridges develop on exposed beaches. The frequency of ridge building ranges from decades in the low-energy settings up to 1600 years under high-energy conditions. Beach ridges in the study area cluster at 9.5, 7.5, 5.5, and below 3.5 m above the present-day storm beach. Based on radiocarbon data, this is interpreted to reflect distinct periods of increased storminess and/or shortened annual sea-ice coverage in the area of the South Shetland Islands for the times around 4.3, c. 3.1, 1.9 ka cal BP, and after 0.65 ka cal BP. Ages further indicate that even ridges at higher elevations can be subject to later reactivation and reworking. A careful investigation of the stratigraphic architecture is therefore essential prior to sampling for dating purposes.

Phycoerythrin concentration during POLARSTERN cruises ANT-XXIV/4, ANT-XXV/1, and ANT-XXVI/4

Phycobiliproteins are a family of water-soluble pigment proteins that play an important role as accessory or antenna pigments and absorb in the green part of the light spectrum poorly used by chlorophyll a. The phycoerythrins (PEs) are one of four types of phycobiliproteins that are generally distinguished based on their absorption properties. As PEs are water soluble, they are generally not captured with conventional pigment analysis. Here we present a statistical model based on in situ measurements of three transatlantic cruises which allows us to derive relative PE concentration from standardized hyperspectral underwater radiance measurements (Lu). The model relies on Empirical Orthogonal Function (EOF) analysis of Lu spectra and, subsequently, a Generalized Linear Model with measured PE concentrations as the response variable and EOF loadings as predictor variables. The method is used to predict relative PE concentrations throughout the water column and to calculate integrated PE estimates based on those profiles.

47 ground-penetrating radar lines of Area 4 - Gravel spit system from Potter Cove, King George Island, Antarctic Peninsula

During two field campaigns (Austral springs 2011 and 2012) the sedimentary architecture of a polar gravel-spit system at the northern coast of Potter Peninsula (Area 4) was revealed using ground-penetrating radar (GPR, Geophysical Survey Systems, Inc. SIR-3000). 47 profiles were collected using a mono-static 200 MHz antenna operated in common offset mode. Trace increment was set to 0.05 m. A differential global-positioning system (dGPS, Leica GS09) was used to obtain topographical information along the GPR lines. GPR data are provided in RADAN-Format, dGPS coordinates are provided in ascii format; projection is UTM (WGS 84, zone 21S).

Ground-penetrating radar (GPR) point measurements of ice thickness in Austria

Glacier thickness is an important factor in the course of glacier retreat in a warming climate. Thiese study data presents the results (point data) of GPR surveys on 66 Austrian mountain glaciers carried out between 1995 and 2014. The glacier areas range from 0.001 to 18.4 km**2, and their ice thickness has been surveyed with an average density of 36 points/km**2 . The glacier areas and surface elevations refer to the second Austrian glacier inventory (mapped between 1996 and 2002). According to the glacier state recorded in the second glacier inventory, the 64 glaciers cover an area of 223.3±3.6 km**3. Maps of glacier thickness have been calculated by Fischer and Kuhn (2013) with a mean thickness of 50±3 m and contain an glacier volume of 11.9±1.1 km**3. The mean maximum ice thickness is 119±5 m. The ice thickness measurements have been carried out with the transmitter of Narod and Clarke (1994) combined with restively loaded dipole antennas (Wu and King, 1965; Rose and Vickers, 1974) at central wavelengths of 6.5 (30 m antenna length) and 4.0 MHz (50 m antenna length). The signal was recorded trace by trace with an oscilloscope. 168 m/µs as used by Haeberli et al. (1982), Bauder (2001), and Narod and Clarke (1994), the signal velocity in air is assumed to be 300 m/µs. Details on the method can be are found in Fischer and Kuhn (2013), as well as Span et al. (2005) and Fischer et al. (2007).

21 ground-penetrating radar lines of Area 1 - Beach ridge plain (low wave energy) from Potter Cove, King George Island, Antarctic Peninsula

During two field campaigns (Austral springs 2011 and 2012) the sedimentary architecture of a polar gravel-beach system at the western coast of Potter Peninsula (Area 1) was revealed using ground-penetrating radar (GPR, Geophysical Survey Systems, Inc. SIR-3000). 21 profiles were collected using a mono-static 200 MHz antenna operated in common offset mode. Trace increment was set to 0.05 m. A differential global-positioning system (dGPS, Leica GS09) was used to obtain topographical information along the GPR lines. GPR data are provided in RADAN-Format, dGPS coordinates are provided in ascii format; projection is UTM (WGS 84, zone 21S).

49 ground-penetrating radar lines of Area 2 - Gravel cuspate spit with gravel beach ridges from Potter Cove, King George Island, Antarctic Peninsula

During two field campaigns (Austral springs 2011 and 2012) the sedimentary architecture of a polar gravel-beach system at the southwestern coast of Potter Peninsula (Area 2) was revealed using ground-penetrating radar (GPR, Geophysical Survey Systems, Inc. SIR-3000). 49 profiles were collected using a mono-static 200 MHz antenna operated in common offset mode. Trace increment was set to 0.05 m. A differential global-positioning system (dGPS, Leica GS09) was used to obtain topographical information along the GPR lines. GPR data are provided in RADAN-Format, dGPS coordinates are provided in ascii format; projection is UTM (WGS 84, zone 21S).

Development of Efficient Techniques for the Analysis and Design of Antennas in Dual-Reflectarray Configuration

This thesis contributes to the analysis and design of printed reflectarray antennas. The main part of the work is focused on the analysis of dual offset antennas comprising two reflectarray surfaces, one of them acts as sub-reflector and the second one acts as mainreflector. These configurations introduce additional complexity in several aspects respect to conventional dual offset reflectors, however they present a lot of degrees of freedom that can be used to improve the electrical performance of the antenna. The thesis is organized in four parts: the development of an analysis technique for dualreflectarray antennas, a preliminary validation of such methodology using equivalent reflector systems as reference antennas, a more rigorous validation of the software tool by manufacturing and testing a dual-reflectarray antenna demonstrator and the practical design of dual-reflectarray systems for some applications that show the potential of these kind of configurations to scan the beam and to generate contoured beams. In the first part, a general tool has been implemented to analyze high gain antennas which are constructed of two flat reflectarray structures. The classic reflectarray analysis based on MoM under local periodicity assumption is used for both sub and main reflectarrays, taking into account the incident angle on each reflectarray element. The incident field on the main reflectarray is computed taking into account the field radiated by all the elements on the sub-reflectarray.. Two approaches have been developed, one which employs a simple approximation to reduce the computer run time, and the other which does not, but offers in many cases, improved accuracy. The approximation is based on computing the reflected field on each element on the main reflectarray only once for all the fields radiated by the sub-reflectarray elements, assuming that the response will be the same because the only difference is a small variation on the angle of incidence. This approximation is very accurate when the reflectarray elements on the main reflectarray show a relatively small sensitivity to the angle of incidence. An extension of the analysis technique has been implemented to study dual-reflectarray antennas comprising a main reflectarray printed on a parabolic surface, or in general in a curved surface. In many applications of dual-reflectarray configurations, the reflectarray elements are in the near field of the feed-horn. To consider the near field radiated by the horn, the incident field on each reflectarray element is computed using a spherical mode expansion. In this region, the angles of incidence are moderately wide, and they are considered in the analysis of the reflectarray to better calculate the actual incident field on the sub-reflectarray elements. This technique increases the accuracy for the prediction of co- and cross-polar patterns and antenna gain respect to the case of using ideal feed models. In the second part, as a preliminary validation, the proposed analysis method has been used to design a dual-reflectarray antenna that emulates previous dual-reflector antennas in Ku and W-bands including a reflectarray as subreflector. The results for the dualreflectarray antenna compare very well with those of the parabolic reflector and reflectarray subreflector; radiation patterns, antenna gain and efficiency are practically the same when the main parabolic reflector is substituted by a flat reflectarray. The results show that the gain is only reduced by a few tenths of a dB as a result of the ohmic losses in the reflectarray. The phase adjustment on two surfaces provided by the dual-reflectarray configuration can be used to improve the antenna performance in some applications requiring multiple beams, beam scanning or shaped beams. Third, a very challenging dual-reflectarray antenna demonstrator has been designed, manufactured and tested for a more rigorous validation of the analysis technique presented. The proposed antenna configuration has the feed, the sub-reflectarray and the main-reflectarray in the near field one to each other, so that the conventional far field approximations are not suitable for the analysis of such antenna. This geometry is used as benchmarking for the proposed analysis tool in very stringent conditions. Some aspects of the proposed analysis technique that allow improving the accuracy of the analysis are also discussed. These improvements include a novel method to reduce the inherent cross polarization which is introduced mainly from grounded patch arrays. It has been checked that cross polarization in offset reflectarrays can be significantly reduced by properly adjusting the patch dimensions in the reflectarray in order to produce an overall cancellation of the cross-polarization. The dimensions of the patches are adjusted in order not only to provide the required phase-distribution to shape the beam, but also to exploit the crosses by zero of the cross-polarization components. The last part of the thesis deals with direct applications of the technique described. The technique presented is directly applicable to the design of contoured beam antennas for DBS applications, where the requirements of cross-polarisation are very stringent. The beam shaping is achieved by synthesithing the phase distribution on the main reflectarray while the sub-reflectarray emulates an equivalent hyperbolic subreflector. Dual-reflectarray antennas present also the ability to scan the beam over small angles about boresight. Two possible architectures for a Ku-band antenna are also described based on a dual planar reflectarray configuration that provides electronic beam scanning in a limited angular range. In the first architecture, the beam scanning is achieved by introducing a phase-control in the elements of the sub-reflectarray and the mainreflectarray is passive. A second alternative is also studied, in which the beam scanning is produced using 1-bit control on the main reflectarray, while a passive subreflectarray is designed to provide a large focal distance within a compact configuration. The system aims to develop a solution for bi-directional satellite links for emergency communications. In both proposed architectures, the objective is to provide a compact optics and simplicity to be folded and deployed.