969 resultados para Photochemical reactors


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Pós-graduação em Microbiologia Agropecuária - FCAV

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Pós-graduação em Química - IBILCE

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Water and soil pollution caused by the waste from the swine production causes severe environmental impacts in producing areas. An efficient alternative to reduce these impacts can be the use of high-rate anaerobic reactors. In this work, it was evaluated the effect of the swine wastewater with total suspended solids concentrations around 6.000 mg.L-1 in the anaerobic baffled reactor with three compartments. The volume of the first compartment was 210 L and of the second and third ones of 160 L. The anaerobic baffled reactor was submitted at hydraulic detention times of 56, 28 and 18 hours and to organic load rates of 5.0 to 10.1 g total COD (L.d)(-1). The highest total COD removals, of 42 to 68%, and volumetric methane productions, of 0.261 to 0.454 L CH4 (L reactor d)(-1), occurred in the second compartment.

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The antibiotics sulfamethoxazole (SMTX) and ciprofloxacin (CIP) are commonly used in human and veterinary medicine, which explains their occurrence in wastewater. Anaerobic reactors are low-cost, simple and suitable technology to wastewater treatment, but there is a lack of studies related to the removal efficiency of antibiotics. To overcome this knowledge gap, the objective of this study was to evaluate the removal kinetics of SMTX and CIP using a horizontal-flow anaerobic immobilized biomass reactor. Two different concentrations were evaluated, for SMTX 20 and 40 μg L(-1); for CIP 2.0 and 5.0 μg L(-1). The affluent and effluent analysis was carried out in liquid chromatography/tandem mass spectrometry (LC-MS/MS) with the sample preparation procedure using an off-line solid-phase extraction. This method was developed, validated and successfully applied for monitoring the affluent and effluent samples. The removal efficiency found for both antibiotics at the two concentrations studied was 97%. Chemical oxygen demand (COD) exhibited kinetic constants that were different from that observed for the antibiotics, indicating the absence of co-metabolism. Also, though the antibiotic concentration was increased, there was no inhibitory effect in the removal of COD and antibiotics.

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)