Carbon and nitrogen content of marine pore waters

We have developed sampling methods and an analytical system to determine the concentration of dissolved organic C (DOC) in marine pore waters. Our analytical approach is a modification of recently developed high-temperature, Pt-catalyzed oxidation methods; it uses Chromatographic trapping of the DOC-derived CO2 followed by reduction to CH4 and flame ionization detection. Sampling experiments with nearshore sediments indicate that pore-water separation by whole-core squeezing causes artificially elevated DOC concentrations, while pore-water recovery by sectioning and centrifugation does not appear to introduce DOC artifacts. Results from a set of northwestern Atlantic continental slope cores suggest that net DOC production accounts for >50% of the organic C that is recycled at the sediment-water interface.

Abundance of calcareous nannofossils in ODP Hole 121-752B (Table 1)

A biostratigraphically complete Cretaceous/Tertiary boundary was recovered during Ocean Drilling Program Leg 121. The boundary, cored in ODP Hole 752B on Broken Ridge, is the most expanded deep-sea section yet recovered by ODP/DSDP. The initial Danian subzone, CP la, spans nearly 5 m and the underlying uppermost Maestrichtian Nephrolithus frequens Zone extends 50 m below the boundary. The paleolatitude of Broken Ridge at Cretaceous/Tertiary time is estimated at 50°-55°S which includes this site among the latest in a series of complete or near complete high southern latitude Cretaceous/Tertiary boundary sections recovered by ODP (Leg 113 Site 690 and Leg 119 Site 738). The boundary at Site 752 lies at the base of a thick (6-6.5 m) volcanic ash unit composed of multiple ash layers which overlies indurated Maestrichtian chalks. Magnetostratigraphy indicates that the boundary lies within Subchron 29R, which is the case for all other known complete sections for which the polarity has been determined. Anomalous abundances of the trace element iridium are present at the boundary. A second iridium peak, 80 cm above the boundary, corresponds to an increase in redeposited Cretaceous nannofossils. The nannofossil succession is similar to that found at previously studied austral high-latitude ODP drill sites with few differences due to the more northerly location of this site. Individual nannofossil species were counted and placed into three categories. A plot of the percent abundance of Cretaceous, Tertiary, and 'survivor' groups illustrates the rapid replacement of the Cretaceous nannoflora by 'survivor' forms beginning at the boundary and the dominance of this latter group through the initial Danian biozone. This 'survivor' or opportunistic assemblage is then rapidly replaced by newly evolved Tertiary taxa. The assemblage of the uppermost Maestrichtian is biased toward dissolution-resistant forms such as Micula decussata. In those few intervals where preservation is good, the dissolution susceptible species, Prediscosphaera stoveri, is more prevalent and overall diversity of the assemblage is higher. The 'survivor' assemblage is dominated by Zygodiscus sigmoides and Thoracosphaera. The Tertiary assemblage consists of rare Biantholithus sparsus, the first of this group to appear. It is followed several meters upsection by Cruciplacolithus primus. Cruciplacolithus tenuis and small Prinsius spp. dominate the assemblage beginning at about 5 m above the boundary.

Stable isotopic composition and carbonate concentrations of sediments of the Cretaceous/Paleogene boundary in the Antarctic

Stable isotopic records across the Cretaceous/Paleogene (K/P) boundary in Maud Rise Holes 689B and 690C indicate that significant climatic changes occurred during the latest Cretaceous, beginning approximately 500 k.y. prior to the mass extinction event and the enrichment of iridium at the K/P boundary (66.4 Ma). An oxygen isotopic decrease of ~0.7 per mil - ~1.0 per mil is recorded in the Late Cretaceous planktonic and benthic foraminifers between 66.9 and 66.6 Ma. The negative isotope excursion was followed by a positive excursion of similar magnitude between 66.6 Ma (latest Cretaceous) and ~66.3 Ma (earliest Paleocene). No other isotopic excursions of this magnitude are recorded in the planktonic and benthic microfossil records 1.0 m.y prior to, and for 2.0 m.y following the mass extinction event at the K/P boundary. The magnitude and duration of these isotopic excursions were similar to those at the Paleocene/Eocene and Eocene/Oligocene boundaries. A major d13C excursion occurred 200 k.y. prior to the boundary, involving a positive shift in planktonic and benthic d13C of ~0.5 per mil - 0.75 per mil. Similar changes observed in other deep-sea sequences indicate that this reflected a global change in d13C of the oceanic total dissolved carbon (TDC) reservoir. The magnitude of this inferred carbon reservoir change and its association with high latitude surface-water temperature changes recorded in the d18O records implies that it was linked to global climate change through feedback loops in the carbon cycle. At the K/P boundary, the surface-to-deep water d13C gradient is reduced by approximately 0.6 per mil - ~0.2 per mil. However, unlike sequences elsewhere, the planktonic-benthic d13C gradient (Delta d13C) was not eliminated in the Antarctic. The surface-to-deep water gradient was re-established gradually during the 400 k.y. following the mass extinction. Full recovery of the Delta d13C occurred by ~60.0 Ma. In addition to the reduced vertical d13C gradient across the K/P boundary, there was a negative excursion in both planktonic and benthic d13C beginning approximately 100 k.y. after the boundary (66.3 Ma). This excursion resulted in benthic d13C values in the early Paleogene that were similar to those in the pre-K/P boundary intervals. This negative shift appears to reflect a change in the d13C of the oceanic TDC reservoir shift that may have resulted from reduced carbon burial and/or increased carbon flux to the oceans. Any model that attempts to explain the demise of the oceanic plankton at the end of the Cretaceous should consider the oceanic environmental changes that were occurring prior to the massive extinction event.

Geochemistry of silicate melt inclusions from ODP Holes 137-504B and 140-504B

Geochemical data from plagioclase-hosted silicate melt inclusions from Leg 140, Hole 504B diabase dikes are reported. Hand-picked plagioclase grains were heated to 1260°-1280°C to remelt the glass inclusions and to infer trapping temperatures. The samples were then polished to expose the inclusions, which were analyzed by electron and ion microprobes. Inclusion compositions are mainly in equilibrium with the host plagioclase and are more depleted in incompatible elements than the host rock. Simple crystal-liquid equilibrium calculations show that the melt inclusions could have been in equilibrium with depleted abyssal peridotite diopsides, whereas whole-rock basalt compositions generally could not have been. The melt inclusions are significantly more depleted than normal (N-type) mid-ocean-ridge basalt (MORB) and are consistent with being produced by 8%-16% incremental or open-system melting with 2% residual porosity in the peridotite source. These magmas were formed during pressure-release melting of the mantle over a range of depths between 30 and 15 km.

Analysis of coastal sediment transport processes from Wrightsville Beach to Fort Fisher, North Carolina /

A comprehensive engineering analysis of the coastal sediment transport processes along a 42-kilometer segment of the North Carolina shoreline from Wrightsville Beach to Fort Fisher is presented. Included in the analysis is an interpretation of the littoral processes, longshore transport, and the behavior and success of beach nourishment projects at Wrightsville Beach and Carolina Beach, North Carolina. The historical position of the MLW, MSL, and MHW contours, relative to a fixed base line, is plotted for the period between 1964 and 1975. An equivalent volumetric erosion or accretion between successive surveys is determined by multiplying the average excursion distance of the contours by a constant of proportionality. The plots of excursion distance versus time for the MLW, MSL, and MHW contours also show the time response of the beach fills. This response is described by a mathematical function. The alongshore components of wave-induced energy flux are also determined within the study area through wave refraction analysis. This information, together with the information on volumetric change, is used in a sediment budget analysis to determine the coefficient of alongshore sediment transport and the inlet trapping characteristics. (Author).

The wilderness trapper,

Mode of access: Internet.

Bats and bat exclusion.

"5/04"--Colophon.

Fur harvest survey.

Federal aid in Wildlife Restoration Act project no. W-49-R, W-99-R.

Fur hunter/trapper survey.

Cover title.

Illinois trapper survey report.

Title from cover.

Results of the Illinois trapper survey.

Cover title.

Trapper harvest survey.

Latest issue consulted: 1990/91.

Les ruses innocentes : dans lesquelles se voit comment on prend les oyseaux passagers, & les non passagers : & de plusieurs fortes de bestes à quatre pieds. Avec les plus beaux secrets de la pesche dans les riuieres & dans les estangs. Et la maniere de faire tous les rets & filets qu'on peut s'imaginer. Le tout diuise en cinq liures, auec les figures demonstratiues ... /

Title page in red and black.

Honey-- guidelines for efficient production /

"May 1975"