Pressure field in the cathode-anode region of a high-power klystron amplifier

The pressure field of a high-power klystron amplifier in the cathode and anode region was investigated. The investigation was performed using a 1.3 GHz, 100 A and 240 kV high-power klystron with five reentrant coaxial cavities, assembled in cylindrical drift tube 1.2 m long. The diffusion equation in mathematical model was also solved by using a 3-D finite element method code, in order to obtain pressure profile in region of interest. The results show that density profile of molecules between cathode-anode region was determined, where cathode pressure is approximately 10% higher than anode pressure.

Uso de métodos químicos para obtener polvos cerámicos del sistema (Sn, Ti)O2

The (Sn,Ti)O2, system has a great interest due to its technological applications such as gas sensor and varistor. Although the thermodynamic properties and the kinetics of spinoidal decomposition in this system have been extensively studied, the general properties and applications of SnO2 - TiO2 binary compositions have been not investigated yet in depth. On the other hand, little work has been done to optimize the synthesis methods to obtain (Sn,Ti)O2 cerallmic powders, with pre - determinate physical and chemical characteristics. In this work the ceramic powders has been obtained by coprecipitation and polymeric precursor (Pechini) methods. The different physical chemistry phenomena that occurred during the synthesis were discussed. The (Sn,Ti)O2, ceramic powders were characterized with X- ray diffraction (XRD), thermal analysis (DTA/TG) and scanning electron microscopy (SEM). The knowledge about of steps and variables of synthesis process acquired with development of this work, we permited to obtain (Sn, Ti)O2, nanometers particles to low temperatures: to 450°C for coprecipitation method and to 600°C for Pechini method. The spinodal decomposition that ocurr to 900°C was discussed also.

As rochas intrusivas da Formação Serra Geral na Porção leste da Bacia do Paraná no Estado de São Paulo: Aspectos petrográficos e geoquímicos - Resultados preliminares

The purpose of this paper is to present preliminary aspects of the petrography and chemistry of intrusive rocks (sills and dykes) from the eastern portion of the Parana Basin in the State of Säo Paulo. Data from 80 samples of the region show a subaphyric and subophitic nature and have plagioclase (25-50%), augite (3-39%), pigeonite (0-10%) and magnetite (4-20%) as an essential minerals. Apatite and quartz are present as accessory minerals. The geochemical data of intrusive rocks show a basic to intermediate composition (48% < SiO 2 < 56%) and a high Ti nature (TiO 2 > 2%). Based on the minor and trace composition of the intrusive rocks, two different magma types were recognized, named Paranapanema and Pitanga. The spatial distribution of these magma types is not alleatory in the studied region. The intrusive rocks of Pitanga magma type are displayed in the Campinas-Paulinia region, while the Paranapanema magma type cover a large region above that one, between Rio Claro and Cajuru. Furthermore, the chemical composition of the lava flows of the Serra Geral Formation, sampled in this work, reveals a magma of Urubici type. So, the intrusive rocks of the eastern portion of the of State Säo Paulo are not the extension of the lava flows, or they aren't a portions which don't reach the surface.

Photodegradation of soluble and emulsive cutting fluids using TiO 2 as catalyst

This paper describes results of the photo-degradation of three types of soluble and emulsive cutting fluids in an aqueous medium, using TiO2 as catalyst in suspension and UV radiation. The TiO2 proved to be an effective catalyst for the degradation of the cutting fluids investigated. The degradation rate depends on pH and nature of the fluids. The best performance of catalyst was observed at pH 8.0 for all the fluids when most of 70% of the organic load was decomposed. ©2006 Sociedade Brasileira de Química.

Installation of a getter vacuum pump in cathode-anode region of a high-power klystron amplifier - Propose and feasible

The possibility to install a getter vacuum pump and its feasible in the anode of a high-power klystron amplifier is investigated in order to decrease of the pressure in the gun and consequently increasing its lifetime. The study is conducted using a 1.3 GHz, 100 A and 240 kV high-power klystron with five reentrant coaxial cavities, assembled in a cylindrical drift tube 1.2 m long. This work takes into account the specific conductance of components of gun and all important gas sources, like the degassing of the drift tube, the cavity walls, the cathode, the anode, and the collector, as well the position and pumping speed of the getter vacuum pump in anode region. © 2006 IEEE.

Mechanochemical synthesis of Bi4Ti3O12

Our efforts were directed to the preparation of bismuth titanate - Bi 4e;Ti3O12 (BIT) by mechanically assisted synthesis. The mechanical activation was applied to prepare bismuth titanate, Bi4e;Ti3O12, from bismuth oxide, Bi 2O3, and titanium oxide, TiO2 (in an anatase crystal form). Mechanochemical synthesis was performed in a planetary ball mill in air atmosphere. Bismuth titanate ceramics was obtained by sintering at 1000° C The formation of Bi4e;Ti3O12 in the sintered samples was confirmed by X-ray diffraction analysis. Scanning electron microscopy, SEM, was used to study the particle size and powder morphology. The obtained results indicate that Bi4e;Ti3O12 from the powder synthesized by high-energy ball milling exhibits good sinterability, showing advantage of the mechanochemical process over conventional solid-state reaction.

A study of the effect of overshooting deep convection on the water content of the TTL and lower stratosphere from Cloud Resolving Model simulations

Simulations of overshooting, tropical deep convection using a Cloud Resolving Model with bulk microphysics are presented in order to examine the effect on the water content of the TTL (Tropical Tropopause Layer) and lower stratosphere. This case study is a subproject of the HIBISCUS (Impact of tropical convection on the upper troposphere and lower stratosphere at global scale) campaign, which took place in Bauru, Brazil (22° S, 49° W), from the end of January to early March 2004. Comparisons between 2-D and 3-D simulations suggest that the use of 3-D dynamics is vital in order to capture the mixing between the overshoot and the stratospheric air, which caused evaporation of ice and resulted in an overall moistening of the lower stratosphere. In contrast, a dehydrating effect was predicted by the 2-D simulation due to the extra time, allowed by the lack of mixing, for the ice transported to the region to precipitate out of the overshoot air. Three different strengths of convection are simulated in 3-D by applying successively lower heating rates (used to initiate the convection) in the boundary layer. Moistening is produced in all cases, indicating that convective vigour is not a factor in whether moistening or dehydration is produced by clouds that penetrate the tropopause, since the weakest case only just did so. An estimate of the moistening effect of these clouds on an air parcel traversing a convective region is made based on the domain mean simulated moistening and the frequency of convective events observed by the IPMet (Instituto de Pesquisas Meteorológicas, Universidade Estadual Paulista) radar (S-band type at 2.8 Ghz) to have the same 10 dBZ echo top height as those simulated. These suggest a fairly significant mean moistening of 0.26, 0.13 and 0.05 ppmv in the strongest, medium and weakest cases, respectively, for heights between 16 and 17 km. Since the cold point and WMO (World Meteorological Organization) tropopause in this region lies at ∼ 15.9 km, this is likely to represent direct stratospheric moistening. Much more moistening is predicted for the 15-16 km height range with increases of 0.85-2.8 ppmv predicted. However, it would be required that this air is lofted through the tropopause via the Brewer Dobson circulation in order for it to have a stratospheric effect. Whether this is likely is uncertain and, in addition, the dehydration of air as it passes through the cold trap and the number of times that trajectories sample convective regions needs to be taken into account to gauge the overall stratospheric effect. Nevertheless, the results suggest a potentially significant role for convection in determining the stratospheric water content. Sensitivity tests exploring the impact of increased aerosol numbers in the boundary layer suggest that a corresponding rise in cloud droplet numbers at cloud base would increase the number concentrations of the ice crystals transported to the TTL, which had the effect of reducing the fall speeds of the ice and causing a ∼13% rise in the mean vapour increase in both the 15-16 and 16-17 km height ranges, respectively, when compared to the control case. Increases in the total water were much larger, being 34% and 132% higher for the same height ranges, but it is unclear whether the extra ice will be able to evaporate before precipitating from the region. These results suggest a possible impact of natural and anthropogenic aerosols on how convective clouds affect stratospheric moisture levels.

Effect of scandium on the structural and photocatalytic properties of titanium dioxide thin films

Pure and scandium doped-TiO2 thin films were prepared by the sol-gel process and coated by dip coating. The effects of scandium on the phase formation, optical properties and photoactivity of the TiO2 thin films were investigated. The lattice parameters and the crystallinity of the anatase phase, characterized by the Rietveld method, demonstrated that scandium doping affected the structural parameters and crystallinity of the films, modifying the absorption edge. A direct correlation was found between band gap energy and photodegradation efficiency, with lower values of band gap energy augmenting this efficiency. Moreover, a significant improvement in the catalyst's photodegradation efficiency was attained with a scandium concentration of 5.0 mol%. © 2007 Springer Science+Business Media, LLC.

Heating rate and temperature effects on the BaTiO3 formation by thermal decomposition of (Ba,Ti) organic precursors during the Pechini process

Different thermal treatments for the synthesis of BaTiO3 powder obtained through the Pechini method were studied. The synthesis of BaTiO3 starts at 150 °C by the thermal dehydration of organic precursors. The usual inevitable formation of barium carbonate during the thermal decomposition of the precursor could be retarded at lower calcination temperatures and optimized heating rates. The organic precursors were treated at temperatures between 200 and 400 °C. Then, the samples were calcined at 700 and 800 °C for 4 and 2 h, respectively. The resulting ceramic powders were characterized by gravimetric and differential thermal analyses, X-ray powder diffraction and infrared spectroscopy. It was found that depending on the heating rate and final temperature of the thermal treatment, high amounts of BaCO3 and TiO2 could be present due to the high concentration of organics in the final calcination step. © 2007 Elsevier B.V. All rights reserved.

Heterogeneous photocatalytic treatment of organic dyes in air and aqueous media

This review focuses on the heterogeneous photocatalytic treatment of organic dyes in air and water. Representative studies spanning approximately three decades are included in this review. These studies have mostly used titanium dioxide (TiO2) as the inorganic semiconductor photocatalyst of choice for decolorizing and decomposing the organic dye to mineralized products. Other semiconductors such as ZnO, CdS, WO3, and Fe2O3 have also been used, albeit to a much smaller extent. The topics covered include historical aspects, dark adsorption of the dye on the semiconductor surface and its role in the subsequent photoreaction, semiconductor preparation details, photoreactor configurations, photooxidation kinetics/mechanisms and comparison with other Advanced Oxidation Processes (e.g., UV/H2O2, ozonation, UV/O3, Fenton and photo-Fenton reactions), visible light-induced dye decomposition by sensitization mechanism, reaction intermediates and toxicity issues, and real-world process scenarios. © 2008 Elsevier B.V. All rights reserved.

Litogeoquímica E aspectos Petrogenéticos dos basaltos da Província Magmática do Paraná na porção centro-norte do Estado de São Paulo

The petrographic and geochemical characterization of flood basalts of Serra Geral Formation are here presented. The investigated areas are situated in four different regions of São Paulo state: Jaú, Ribeirão Preto, Franca and Fernandópolis. They represent almost the total area of outcrops of basalts in the São Paulo State. The petrographical data reveals that these rocks are constituted mainly by plagioclase (30-40%), pyroxenes, augite and pigeonita (20-30%) and magnetite (5-15%), and show a intergranular texture and its varieties intersertal, hialophitic and pilotaxitic. The geochemical data show a basic and tholeiitic affinity of the studied basalts, with high-Ti content (TiO2 > 1.8%), typical of the northern region of Paraná Basin. Three different magma-types were recognized: Paranapanema, Urubici and Pitanga. The first magma-type is concentrated in the Fernandópolis region, the second in the Franca region, and the Pitanga occurs in the Ribeirão Preto and Jaú regions. The distribution patterns of these magma-types and the detailed study of geochemical data showed that they are, probably, generated by a melting of a continental lithospheric mantle.

Geologia e litogeoquímica da formação serra geral nos estados de mato grosso e mato grosso do sul

The basalts of the Formação Serra Geral in Parana Basin in the Mato Grosso do Sul and Mato Grosso states cover an area of 180,000 km2. They rest on the Botucatu sandstones and they are recovered by the sedimentary rocks of Bauru and Caiuá Groups. The mineralogical composition of these rocks are plagioclase (40%-55%), clinopyroxenes (19%-40%; augite and pigeonite), opaque minerals (2%-10%; magnetite and ilmenite) and olivine (1.5%). Geochemical data show two different types of basalts, named ATi-Pitanga (2.6% < TiO2 < 4.2%; 396 ppm < Sr < 438 ppm) and BTi-Ribeira (1.7% TiO2 <2.4%, 246 ppm < Sr < 286 ppm). In general, ATi-Pitanga have gently higher La/Yb(n) (6,1 ± 1,5ppm) than those BTi-Ribeira (5.6 ± 1,7ppm). The geochemical differences between ATi-Pitanga and BTi-Ribeira probably are related to different degrees of partial melt of a same mantle source, or to different mantle sources. The field relations show that BTi-Ribeira is displaced towards the north-western margin of the Paraná Basin and the thickness of lava flows increases towards the Paraná Graben, suggesting that ATi-Pitaga overlies BTi-Ribeira.

Polishing of water treated by a biological process with heterogeneous photocatalysis

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Bandgap voltage reference with low susceptibility to electromagnetic interference (EMI)

In this paper, the susceptibility of a current-mode bandgap voltage reference to electromagnetic interference (EMI) superimposed to the power supply is investigated by simulation. Designed for AMS 0.35 CMOS process, the circuit provides a stable voltage reference in the temperature range of -40-150°C. When EMI disturbances are present, the circuit exhibits only 6.7 mV of offset for interfering signals in the frequency range of 150 kHz-1 GHz. © 2011 ACM.