加速器高频D电路Q值的计算与测量

介绍了回旋加速器高频单D型盒D电路Q值的计算与测量方法。重点对Q值的理论计算进行推导,并对计算原理进行说明。然后对计算结果和测量结果进行比较。得出的计算和测量结果基本吻合。误差产生的主要原因是计算过程中的近似和短路片接触电阻的取值,其中短路片接触电阻是一个重要因素,在设计腔体时应引起足够的重视。

额济纳天然绿洲景观演化驱动因子分析

额济纳天然绿洲位于我国西北干旱内陆河流域黑河流域下游 ,近年来 ,随着黑河中、上游地区下泄地表径流量的减少 ,额济纳天然绿洲景观退化严重。基于研究区近十几年来的景观演化总体特征 ,分别从气候因素、水文因素、人类干扰因素等几个主要的景观变化驱动因子入手 ,探讨其演化机制、揭示其演化规律。研究结果表明 :黑河流域中、上游下泄地表径流量的锐减而导致研究区地下水水位下降、地下水矿化度升高以及水质恶化是额济纳天然绿洲景观发生退化的根本原因 ,绿洲人类活动强度的增加、绿洲关键区域的超载和过牧以及蒸发度指数的升高、湿润系数的下降均加剧了研究区景观退化的程度。

美国的土壤侵蚀与防治

<正> 美国是世界农业大国,除遇特大自然灾害外,农业生产一直保持长期稳定发展的态势.1990年谷物的生产量达到3.13亿t,预测到2000年谷物产量可达4.53亿t,1985～2000年谷物平均增长速度为1.8%.美国的农业生产之所以能取得如此辉煌的成就有多种原因,其中政府重视土壤保护是最主要的原因之一.80年代初期,美国的农业科学家皮门特尔就曾向全世界发出警告,指出土壤侵蚀已成为全世界第一号环境问题,呼吁人们注意土壤侵蚀给农业生产带来的严重危害.而当时的美国同样面临着土壤侵蚀的严峻形势.深入的研究表明,土壤侵蚀恶性发展的根本原因不在气候变异、水旱等自然灾害,造成土壤侵蚀的根本原因来自人类对自然界的干扰,其中包括不合理的土地利用、滥砍滥伐、破坏森

基于县域要素的三江源地区旅游扶贫模式探讨

随着我国旅游业的兴起,人们越来越认识到旅游在消除贫困上的潜力和能力,然而,要让旅游真正朝着有利于消除贫困的方向发展,必须对旅游的发展方式加以调整,因地制宜地选择旅游扶贫的模式。本文构建了三江源地区各县贫困程度和旅游资源禀赋评价指标体系,定量测度了各评价区的贫困度和旅游资源禀赋综合得分,并采用四象限法划分出资高贫低、双高、双低、资低贫高4种旅游扶贫类型区,在此基础上,提出适用于整个三江源地区的旅游扶贫基本模式为政府主导模式,以及各类型区的旅游扶贫辅助模式,即资高贫低区的政企合作模式,双高区的项目推动模式,双

A versatile color tuning strategy for iridium(III) and platinum(II) electrophosphors by shifting the charge-transfer states with an electron-deficient core

By fusing an electron-deficient ring system with the phenyl ring of a 2-phenylpyridine (ppy)-type ligand, a new and synthetically versatile strategy for the phosphorescence color tuning of cyclometalated iridium(III) and platinum(II) metallophosphors has been established. Two robust red electrophosphors with enhanced electron-injection/electron-transporting features were prepared by using an electron-trapping fluoren-9-one chromophore in the ligand design. The thermal, photophysical, redox and electrophosphorescent properties of these complexes are reported. These exciting results can be attributed to a switch of the metal-to-ligand charge-transfer (MLCT) character of the transition from the pyridyl groups in the traditional Ir-III or Pt-II ppy-type complexes to the electron-deficient ring core, and the spectral assignments corroborate well with the electrochemical data as well as the timedependent density functional theory (TD-DFT) calculations. The electron-withdrawing character of the fused ring results in much more stable MLCT states, inducing a substantial red-shift of the triplet emission energy from yellow to red for the Ir-III complex and even green to red for the PtII counterpart.

THE SYNTHESES CHARACTERIZATION AND CRYSTAL-STRUCTURE OF RARE-EARTH COMPLEXES WITH L-PROLIN

The complexes of Ln(L-Pro)s(H2O)2(ClO4)3(Ln = Pr, Nd and Er. L-Pro = L-Proline) were synthesized and characterized by elemental analysis, IR. spectra and thermal analysis. The singal crystal Pr2(L-Pro)6(H2O)4(ClO4)6 Was also obtained. The crystal belongs to monoclinic, P2(1), a = 0.9879 (3) nm, b = 2.1883 (4) nm, c = 1.3393 (2)nm, beta = 91.23(2)-degrees, V = 2.895(1) nm3, Z = 2. R = 0.035 for 5032 observed reflections. The coordination polyhedron of Pr(III) ion comprises six oxygen atoms from L-Pro molecules and two water molecules. Each L-Pro molecule coordinates to two Pr(III) ions through its carboxyl group which serves as a bridging bidentate ligand to form onedimensional chain structure.

稀土与L-脯氨酸配合物的合成、表征及晶体结构

本文合成了通式为Ln(L-Pro)_3(H_2O)_2(ClO_4)_3(Ln=Pr、Nd、Er,L-Pro=L-脯氨酸)的固体配合物.元素分析、红外光谱、热分析对配合物进行了表征.培养了镨脯氨酸配合物的单晶,X射线四圓衍射确定了晶体的结构.晶体属于单斜晶系、空间群P2_1,α=0.9879(3),b=2.1883(4),c=1.3393(2)nm,β=91.23(2)°,V=2.895(1)nm~3,Z=2.晶体中每一个镨原子与来自6个L-脯氨酸羧基上的6个氧原子和2个结晶水分子键合,形成了一个八配位的稍有畸变的三角十二面体.每一个L-脯氨酸分子以羧基双齿方式与两个镨离子配位,形成了一个无限长的链状结构.

ELECTROCHEMICAL-BEHAVIOR OF YTTRIUM ION IN LICL-KCL-NACL EUTECTIC MELT

The electrochemical reduction of yttrium ion on a molybdenum electrode in a LiCl-KCl-NaCl eutectic melt at 723 K was found to be almost reversible and to proceed by a one-step three electron reaction. The diffusion coefficient D of the Y(III) ion was measured to be (3.3 +/- 0.4) x 10(-6) cm2 s-1 by cyclic voltammetry, (5.0 +/- 0.9) x 10(-6) cm2 s-1 by the rotating disk electrode method, and (7.1 +/- 0.7) x 10(-6) cm2 s-1 by chronopotentiometry. The D values obtained by the latter two methods are in fairly good agreement with each other. The rather low D value obtained by cyclic voltammetry might be attributed to the fact that yttrium metal can dissolve slightly in the chloride melt. The standard potential of Y(III)/Y(0) couple was determined to be (-3.174 +/- 0.006) V (vs. Cl2/Cl-) by open-circuit potentiometry, (-3.15 +/- 0.02) V (vs. Cl2/Cl-) by the rotating disk electrode method and (-3.16 +/- 0.02) V (vs. Cl2/Cl) by chronopotentiometry. These three values are in good agreement with each other. Several types of Ni-Y intermetallic compounds were found to be formed on a nickel electrode.

A comparative study of thermolysis characteristics and kinetics of seaweeds and fir wood

Thermal analysis and thermolysis kinetics of three kinds of seaweeds and fir wood (M. glyptostriboides Huet Cheng), a kind of typical land plant, had been conducted. The results showed that thermal stability follows the order of Grateloupia filicina < Ulva lactuca < Dictyopteris divaricata < fir wood. A notable difference on heat flow between seaweeds and fir wood during thermolysis was that the former were mainly connected with exothermic processes at relatively lower temperature regimes. while the latter was connected with an apparent endotherm at a relatively higher temperature regime followed by a maximum exothermic peak. This suggested that the heat coupling might be realized if co-thermolysis of seaweeds and fir wood were carried out. The main devolatilization phase of each seaweed could be described by Avrami-Erofeev equation, which indicated that thermolysis of seaweeds follows the mechanism of random nucleation and nuclei growth, whereas that of fir wood by Z-L-T equation and its thermolysis mechanism was three-dimensional diffusion. The activation energies calculated for both seaweeds and fir wood increase as conversion increases. However, those for the former have wider distribution. (c) 2006 Elsevier Ltd. All rights reserved.

Sesquiterpenes from the red alga Laurencia tristicha

Seven new sesquiterpenes (1-7), together with seven known sesquiterpenes, aplysin (8), aplysinol (9), gossonorol (10), 7,10-epoxy-ar-bisabol-11-ol (11), 10-epi-7,10-epoxy-ar-bisabol-11-ol (12), johnstonol (13), and laurebiphenyl (14), have been isolated from the red alga Laurencia tristicha. The structures of new compounds were established as laur-11-en-2,10-diol (1), laur-11-en-10-ol (2), laur-11-en-1,10-diol (3), 4-bromo-1,10-epoxylaur-11-ene (4), cyclolauren-2-ol (5), laurentristich-4-ol (6), and ar-bisabol-9-en-7,11-diol (7) by means of spectroscopic methods including IR, HRMS, and ID and 21) NMR techniques. Compound 6 possessed a novel rearranged skeleton. All compounds were tested against several human cancer cell lines including lung adenocarcinoma (A549), stomach cancer (BGC-823), hepatoma (Bel 7402), colon cancer (HCT-8), and HELA cell lines. Laurebiphenyl (14) showed moderate cytotoxicity against all tested cell lines, with IC50 values of 1.68, 1.22, 1.91, 1.77, and 1.61 mu g/mL, respectively. Other compounds were inactive (IC50 > 10 mu g/mL).