970 resultados para Armed Services Vocational Aptitude Battery.


Relevância:

20.00% 20.00%

Publicador:

Resumo:

Background The application of polyethylenimine (PEI) in gene delivery has been severely limited by significant cytotoxicity that results from a nondegradable methylene backbone and high cationic charge density. It is therefore necessary to develop novel biodegradable PEI derivates for low-toxic, highly efficient gene delivery.Methods A series of novel cationic copolymers with various charge density were designed and synthesized by grafting different kinds of oligoethylenimine (OEI) onto a determinate multi-armed poly(L-glutamic acid) backbone. The molecular structures of multi-armed poly(L-glutamic acid)-graft-OEI (MP-g-OEI) copolymers were characterized using nuclear magnetic resonance, viscosimetry and gel permeation chromatography. Moreover, the MP-g-OEI/DNA complexes were measured by a gel retardation assay, dynamic light scattering and atomic force microscopy to determine DNA binding ability, particle size, zeta potential, complex formation and shape, respectively. MP-g-OEI copolymers were also evaluated in Chinese hamster ovary and human embryonic kidney-293 cells for their cytotoxicity and transfection efficiency.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

The La0.85MgxNi4.5Co0.35Al0.15 (0.05less than or equal toxless than or equal to0.35) system compounds have been prepared by are melting method under Ar atmosphere. X-ray diffraction (XRD) analysis reveals that the as-prepared alloys have different lattice parameters and cell volumes. The electrochemical properties of these alloys have been studied through the charge-discharge recycle testing at different temperatures and discharge currents. It is found that the La0.85Mg0.25Ni4.5Co0.35Al0.(15) alloy electrode is capable of performing high-rate discharge. Moreover, it has very excellent electrochemical properties as negative electrode materials in Ni-MH battery at low temperature, even at -40degreesC.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

Highly ordered honeycomb-like macroporous films were obtained via self-assembly of a two-armed polymer with a crown ether core under controlled conditions. A possible mechanism is speculated, primarily based on the strong affinity between the crown ether cores. The pore size and arrangement are sensitive to the solvent evaporation rate and the solution concentration. Upon spontaneous drying, the pore diameter (D) depends on the concentration (c) by a relation of D=518c(-0.610).

Relevância:

20.00% 20.00%

Publicador:

Resumo:

Silver nanoparticles were synthesized by the use of a two-armed polymer with a crown ether core [poly(styrene)]-dibenzo-18-crown-6-[poly(styrene)] based on the flexibility of the polymer chains and the complex effect of crown ether with Ag+ and Ag. The size of silver nanoparticles could be tailored by controlling the initial concentrations of the polymer and Ag+, and the molecular weight of the polymer. The emission of silver nanoparticles was blue-shifted, and the intensity of the photoluminescence of silver nanoparticles stabilized by the polymer was significantly increased due to the complex effect between the crown ether embedded in the polymer and the silver nanoparticles.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

Biodegradable, amphiphilic, four-armed poly(epsilon-caprolactone)-block-poly(ethylene oxide) (PCL-b-PEO) copolymers were synthesized by ring-opening polymerization of ethylene oxide in the presence of four-armed poly(epsilon-caprolactone) (PCL) with terminal OH groups with diethylzinc (ZnEt2) as a catalyst. The chemical structure of PCL-b-PEO copolymer was confirmed by H-1 NMR and C-13 NMR. The hydroxyl end groups of the four-armed PC L were successfully substituted by PEO blocks in the copolymer. The monomodal profile of molecular weight distribution by gel permeation chromatography provided further evidence for the four-armed architecture of the copolymer. Physicochemical properties of the four-armed block copolymers differed from their starting four-armed PCL precursor. The melting points were between those of PCL precursor and linear poly(ethylene glycol). The length of the outer PEO blocks exhibited an obvious effect on the crystallizability of the block copolymer. The degree of swelling of the four-armed block copolymer increased with PEO length and PEO content.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

A simple, productive and low-cost route has been developed to synthesize multi-armed CdTe nanorods using myristic acid (MA) as a complex agent. The yield of this approach can reach 75%. The dimension of the multi-armed nanorods can be controlled by tuning the molar ratios of Cd/Te and Cd/MA; the diameter can be changed from 2 to 7 nm while the length from 15 to 60 nm. The hexagonal structure was confirmed in x-ray diffraction analysis. However, it was assumed that one crystal is composed of the dominant hexagonal structure along with a cubic structure in the core.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

A two-armed polymer with a crown ether core self-assembles to produce macroporous films with pores perpendicularly reaching through the film down to the substrate. A possible assembling mechanism is discussed. The pore size can be conveniently adjusted by changing the solution concentration. These through-hole macroporous films provide a template for fabricating an array of Cu nanoparticle aggregates.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

The size-armed polystyrenes and poly-(methyl methacrylate)s with a triphenylene core showed different self-assembling patterns, isolated cylinders for polySt on mico and highly ordered cylindrical pores for polyMMA on a silicon water. With a decrease of polymer concentration in tetrahydrofuran (HHF), the size and height of cylinders decreased for polySt, but fur polyMMA, the size and depth of the cylindrical pores increased. Slow evaporation of the solvent and a low molecular weight favored the formation of regular patterns.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

Electrochemical properties of rare earth AB(3)-type hydrogen storage alloys as negative electrode material and a polymer instead of 6 M KOH aqueous solution as solid state electrolyte in MH-Ni battery have been investigated at room temperature and 28degreesC first time. The partial replacement of Ni by Al and Mn elements increases the specific capacity and cycle stability of the alloy.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

X-ray and electrochemical studies of spinel-related manganese chromium oxides, LiCrxMn2-xO4 (0 less-than-or-equal-to x less-than-or-equal-to 1) were carried out in a lithium nonaqueous cell. X-ray diffraction spectra indicated that the substitution of manganese in LiMn2O4 by trivalent transition metals (Cr3+) cause the linear decrease of lattice parameter with the x in the LiCrMn2-xO4. Some discharge-capacity loss was obtained due to the lattice contraction of LiCrMn2-xO4, but it has a better rechargeability than LiMn2O4. Cyclic voltammetry and electrochemical impedance experiments have shown that the excellent rechargeability of LiCrxMn2-xO4 may be attributed to the good reversibility of the change in its crystal structure for the insertion and extraction of lithium ions.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

随着网络技术、特别是Internet技术的发展,分布式系统的高睦能、高可靠性、高灵敏度、可扩展性和系统透明性使得基于分布式系统的应用越来越广泛。在分布式坏境下,信息系统的集成是必须认真考虑的问题。研究如何集成和统一访问分布的、异构的数据资源,实现各种数据的转换、交流与共享;以及如何建立一个开放、可扩展和异构兼容的新一代信息管理系统成为当今网络应用的重要研究方向。本文针对建立月球探测数据管理和集成系统的数据集成与操作集成两方面的内容,重点分析和研究了数据存储管理和系统集成技术,结合月球探测数据管理的应用集成需求与特点提出了基于XML技术的数据存储与管理和基于Web Service技术的系统集成方案。并利用XML/WebService技术基于Net平台开发了一个月球探测数据管理与集成系统实例。研究内容主要包括以下四个方面: (1)基于XML的数据模型与数据库存储。利用XML的自描述性、独立于平台和应用、半结构化,机器可处理、可扩展性以及便于网络传输和广泛支持的特性,实现了基于关系数据库的XML数据存储。对系统中的结构化和非结构化数据信息、都进行了XML标记定义,实现了信息存储和查询的小粒度,增强了数据的表示、查询、插入和删除等数据处理能力和效率。同时,利用XML作为月球探测数据交换和信息传输的格式,也为实现与异构系统数据的互操作提供了理想的角军决方案。(2)基于WebServices的分布式信息系统集成的体系结构。在对XML、SOAP、WSDL和UDDI关键技术和标准规范进行研究与探讨基础上,针对绕月探测数据管理的需求提出了基于XML/Web Service的三层分布式结构模型。分别是表示层、应用逻辑层、服务端数据层。实现了系统功能的可迁移性和可装配性、各层间传输过程中数据流的XML化、接口定义的动态性。与传统技术开发的耦合的分布式应用系统相比,系统在跨平台性、可配置性、可伸缩性、可维护性等方面都有了大幅度的提高。(3)基于,NET平台系统的开发与实现。深入分析和研究了Mic1’osoft.NET平台的核心技术与整体技术框架,在VisLla1Sttldio.NET开发环境中利用C#、ASP.NET、ADO.NET基于关系型数据库Oracle9i开发实现了统一身份认证系统和月球探测数据管理与集成系统。统一身份认证系统是一个通用的统一用户身份认证管理系统,包括用户管理、身份验证、实体管理、日志监控和消息、管理等功能,达到了一次登录,所有系统共用的目的。月球探测数据管理与集成系统包括数据管理、信息发布、系统管理、综合查询和应用集成五大功能模块,相对于原来的紧祸合的应用系统而言,系统的开发效率、重用性、祸合度、灵活性和自适 应性都有了很大的提高。(4)基于XML/WebServices的动态系统集成。分析了传统分布式对象模型在异构环境集成的弊端,基于XML、SOAP和WSDL等技术规范基础上,实现了统一身份认证系统、月球探测数据管理与集成系统、小空间碎片数据库系统以及其它语言开发的应用系统的信息集成、实现了资源时空的有效整合。通过这些集成应用实例,充分体现和说明了Web Services技术在应用系统集成方面的优越性。本研究的成果,也将为地球化学研究领域涉及海量数据的处理、管理和系统集成提供示范实例,推动地球化学数据的融合和综合应用。

Relevância:

20.00% 20.00%

Publicador:

Resumo:

Aims. To explore parents and professionals’ experience of family assessment in health visiting (public health nursing), with a focus on the Lothian Child Concern Model (LCCM). Background. Health visitors (HVs) currently assess families as requiring core, additional or intensive support, and offer support at a corresponding level. The majority of families are assessed as core and receive no pro-active support beyond the early days. Previous assessment tools, consisting of checklists, have been criticised as being ineffective in identifying a range of health needs and unacceptable to parents and HVs. The LCCM model was developed and introduced in the study area to promote a partnership approach with parents and assess strengths as well as difficulties in parents’ capacity to care for their child. Methods. Qualitative methods were used. Ten mothers and twelve HVs took part in individual semi-structured interviews. Results. Most mothers were aware of the assessment process but some felt that they were not involved in the decision making process. Explaining the assessment process to parents is problematic and not all HVs do so. The assessment process was stressful for some mothers. HVs find the model useful for structuring and documenting the assessment process. Many believe that most families benefit from some support, using public health approaches. Families are often assessed as core because there are insufficient resources to support all those who meet the criteria of the additional category, and managers assess caseloads in terms of families with child protection concerns. Conclusions. The study findings support the concept of “progressive universalism” which provides a continuum of intensity of support to families, depending on need. Mothers would like better partnership working with HVs. Relevance to clinical practice. The study endorses proposed policy changes to re-establish the public health role of HVs and to lower the threshold for families to qualify for support.

Relevância:

20.00% 20.00%

Publicador:

Resumo:

The aim of this study is to investigate the impact of interconnectedness between a long-term savings and investments provider, Independent Financial Advisers (IFAs) and customers. Ritter’s (2000) framework of the effect of interconnectedness was used to analyse this triadic relationship. Conceptual studies of triadic business relationships are scarce in marketing and organisational research (Blakenburg & Johanson, 1992; Havila, Johnson & Thilenius, 2004; Ritter, 2000). However, the applicability of a triadic relationship has been tested in a number of case studies (Andersson & Mattsson, 2004; Cunningham & Pyatt, 1989; Jaaskelainen, Kuivalainen & Saarenketo, 2000; Narayandas, 2002; Odorici & Corrado, 2004; Pardo & Salle, 1994; Trimachi, 2002). This study was conducted in collaboration with one of the UK’s largest long-term savings and investments providers. A substantial proportion of the provider’s business is conducted through IFAs and thus their significance as a major stakeholder. Indeed, the majority of sales in the long-term savings and investments industry in the UK are realised through IFAs. Academic studies (Gough, 2005; Gough & Nurullah, 2009) have indicated that IFAs are the strongest distribution channel in the industry. Thus, by analysing the impact of the interconnectedness in this relationship, a strategy that can increase the relationship performance can be proposed. However, to the best of the authors’ knowledge, a study that investigates the effect of the interconnectedness in this triadic relationship has not been established. In addition, the regulatory environment which continues to face change such as the recent implementation of Retail Distribution Review (RDR) on 1st January 2013 will make the relationship more rather than less complex.