Tab. 1: Mineralogical composition and chemical analyses of major and trace elements of Ameghino Formation rocks

As a result of a petrographical, mineralogical and geochemical characterization of the Ameghino Formation mudstones (Upper Jurassic- Lower Cretaceous, Antarctic Peninsula), "epiclastic" radiolaria-rich and mixed (radiolaria-rich + tuff) mudstone types were recognized. Contents of clastic material in the mudstones generally increase with younger paleontological age, but local exceptions to this trend have been found. The anoxic environment of the lower part of the sequence changes to more oxidizing conditions towards the top, in transition to the Hauterivian - Barrêmian conglomerates. Element to element correlations show good agreement with the normal differentiation trends of volcanic (andesite-rhyolite) rocks, suggesting that the overall sequence is mainly volcanic in origin with various grade of reworking. For example, the radiolaria-rich mudstone matrix could have been originated from very fine touffaceous suspensions deposited very slowly after the main fall of the tuffs. However, in the upper part of the sequence, some epiclastic supply is revealed by petrographic evidence and illite crystallinity index. The clay mineral association (illite, chlorite and illite-smectite mixed layers) is mainly of diagenetic origin in the stratigraphically lower sections. Low percentages of expandable layers in the illite-smectite mixed layers, as well as the general mineralogical association, suggest a late mesodiagenetic stage, and together with geological evidence, a relatively deep burial (> 1000 m - probably > 2500 m) and temperatures exceeding 100°C.

Foraminifers from DSDP Leg 87 holes

Leg 87 investigated two sites in the Nankai Trough, off southeastern Japan, and one in the Japan Trench, off northeastern Japan. Several holes at the Nankai Trough sites penetrated mostly Quaternary interbedded sandy turbidites and hemipelagic mud. Foraminifers are common only in certain turbidite sands because both sites are at or just below the carbonate compensation depth. The planktonic assemblages from these sandy layers consist of mixed cool-temperate and warm-water species, and include both solution-resistant and solution-prone species. The benthic assemblages from these same layers are composed of mixtures of shelf to abyssal species. The northward-flowing Kuroshio is important in producing the mixed planktonic faunas, whereas turbidity currents are the primary agents in mixing benthic faunas and in the rapid burial of both planktonic and benthic foraminifers, which protects them from solution. Interbedded hemipelagic muds are barren or contain sparse faunas. Hole 582B penetrated through the trench-fill deposits into hemipelagic sediments that originated in the Shikoku Basin. These muds contain a dissolution facies of solution-resistant planktonic species, partially dissolved tests, and deep bathyal benthic species. Drilling at Site 584, on the landward midslope of the Japan Trench, penetrated a section of dominantly diatomaceous mudstone. This section contains a meager Pliocene calcareous fauna in its upper third and a nearly monospecific assemblage of Martinottiella communis in the lower two-thirds. Diatom biostratigraphy indicates that this change in assemblages occurs near the Miocene/Pliocene boundary. Similar biofacies changes are observed in neighboring sections drilled during Legs 56 and 57. The change from agglutinated to calcareous faunas is probably related to a relative drop in the carbonate compensation depth at the end of the Miocene.

Organic geochemistry and sedimentology of lower to mid-Cretaceous at DSDP Leg 77 Holes

Analyses of 40 carbonate core samples - 27 from Site 535, 12 from Site 540, and 1 from Site 538A - have confirmed many of the findings of the Shipboard Scientific Party. The samples, all but one Early to mid-Cretaceous in age (Berriasian to Cenomanian), reflect sequences of cyclically anoxic and oxic depositional environments. They are moderately to very dark colored, dominantly planar-parallel, laminated lime mudstones. Most show the effects of intense mechanical compaction. Visual kerogen characteristics and conventional Rock-Eval parameters indicate that these deep basinal carbonates contain varying mixtures of thermally immature kerogen derived from both marine and terrigenous precursors. However, variations in kerogen chemistry are evident upon analysis of the pyrolysis mass spectral data in conjunction with the other geochemical analyses. Particularly diagnostic is the reduction index, Rl, a measure of H2S produced during pyrolysis. Total organic carbon, TOC, ranges from 0.6 to 6.6%, with an overall average of 2.4%. Average TOCs for these fine-grained mudstones are: late Eocene 2.5% (1 sample), Cenomanian 2.2% (6), Albian 2.0% (10), Aptian 1.3% (1), Barremian-Hauterivian 2.8% (11), late Valanginian 4.8% (3), Berriasian-early Valanginian 1.6% (7). Most of the carbonates have source-potential ratings of fair to very good of predominantly oil-prone to mixed kerogen, with only a few gas-prone samples. The ratings correlate well with the inferred depositional environments, i.e., whether oxic or anoxic. Several new organic-geochemical parameters, especially Rl, based on pyrolysis mass spectrometry of powdered whole-rock samples, support this view. Tar from fractures in laminated to bioturbated limestones of Unit IV (late Valanginian) at 535-58-4, 19-20 cm (530 m sub-bottom) appears to be mature, biodegraded, and of migrated rather than on site indigenous origin.

Mineral composition of sediments from ODP Leg 190 sites and DSDP Hole 31-297

This data report documents the acquisition of two new sets of normalization factors for semiquantitative X-ray diffraction analyses. One set of factors is for bulk sediment powders, and the other applies to oriented aggregates of clay-sized fractions (<2 µm). We analyzed mixtures of standard minerals with known weight percentages of each component and solved for the normalization factors using matrix singular value decomposition. The components in bulk powders include total clay minerals (a mixture of smectite, illite, and chlorite), quartz, plagioclase, and calcite. For clay-sized fractions, the minerals are smectite, illite, chlorite, and quartz. We tested the utility of the method by analyzing natural mudstone specimens from Site 297 of the Deep Sea Drilling Project, which is located in the Shikoku Basin south of Site 1177 of the Ocean Drilling Program (Ashizuri transect).

Distribution and abundance of nannofossils in DSDP Site 89-585

Late Aptian through middle Eocene nannofossil assemblages were recovered from a continuously cored section at Site 585. Poorly preserved assemblages of low diversity were observed in samples taken throughout both upper Aptian and/or lower Albian sandstone and mudstone and middle Cenomanian to lower Turonian claystone at the base of this section. A 70-m interval barren of nannofossils separates these poorly preserved assemblages from those recovered from an upper Campanian chalk farther uphole. This chalk marks the most significant change in carbonate deposition at this site, and deposition of interbedded zeolitic claystone and sediment of varied nannofossil content proceeded without major interruption until the early Paleocene (Fasciculithus tympaniformis Zone, CP4). A middle Eocene chalk (dated by nannofossils) unconformably overlies lower Paleocene sediment in both Holes 585 and 585A. Only a few interbeds of zeolitic claystone are present within 100 m of nannofossil-rich sediment above this unconformity. This entire interval is cautiously assigned to the Discoaster sublodoensis Zone (CP 12), which indicates a sedimentation rate almost an order of magnitude higher than expected from normal pelagic sedimentation. The most obvious feature of the assemblages examined from these cores is the amount of reworked material. Rare Nannoconus elongatus and Braarudosphaera sp. in several upper Campanian to middle Eocene samples demonstrate the contribution of pelagic material from upslope and, along with other reworked species throughout the Upper Cretaceous samples examined, provide evidence contradictory to an excursion of the calcium compensation depth to deep basinal settings in the western Pacific during the Campanian-Maestrichtian time (Thierstein, 1979). The overwhelming dominance of reworked species in all middle Eocene samples examined and the persistence of these assemblages throughout such a large thickness of sediment suggest that currents that redeposited material intensified at this time and may be associated with the formation of the lower Paleocene/middle Eocene unconformity at this site. A single surface core of calcareous ooze taken from Hole 585A dated as early Pleistocene contains abundant and well-preserved late Miocene and Pliocene species.

(Table T1) Composition of clay minerals from ODP Leg 204 sediments

This report describes the results of semiquantitative analysis of clay mineral composition by X-ray diffraction. The samples consist of hemipelagic mud and mudstone cored from Hydrate Ridge during Leg 204 of the Ocean Drilling Program. We analyzed oriented aggregates of the clay-sized fractions (<2 µm) to estimate relative percentages of smectite, illite, and chlorite (+ kaolinite). For the most part, stratigraphic variations in clay mineral composition are modest and there are no significant differences among the seven sites that were included in the study. On average, early Pleistocene to Holocene trench slope and slope basin deposits contain 29% smectite, 31% illite, and 40% chlorite (+ kaolinite). Late Pliocene to early Pleistocene strata from the underlying accretionary prism contain moderately larger proportions of smectite with average values of 38% smectite, 27% illite, and 35% chlorite (+ kaolinite). There is no evidence of clay mineral diagenesis at the depths sampled. The expandability of smectite is, on average, equal to 64%, and there are no systematic variations in expandability as a function of burial depth or depositional age. The absence of clay mineral diagenesis is consistent with the relatively shallow sample depths and corresponding maximum temperatures of only 24°-33°C.

Triassic redbeds in the Malaguide Complex (Betic Cordillera — Spain): petrography, geochemistry and geodynamic implications

Sandstone petrography and mudstone mineralogy and geochemistry of Triassic mudstones and sandstones from continental redbeds of the Malaguide Complex (Betic Cordillera, southern Spain) provide useful information on provenance, palaeoclimate and geodynamics during the early stages of the Pangea break-up, and on their diagenetic evolution. The sandstones are quartzarenites to sub-litharenites, with minor lithic fragments and rare feldspars. The mudstone samples show a PAAS like elemental distribution. The samples likely record recycling processes from their metasedimentary basement rocks that significantly affected the weathering indices, and monitors cumulative effects, including a first cycle of weathering at the source rocks. Sandstone composition and chemical–mineralogical features of mudstones record a provenance derived from continental block and recycled orogen that were weathered under warm and episodically wet climate. Source areas were located towards the east of the present-day Malaguide outcrops, and were formed by fairly silicic rock types, made up mainly of Palaezoic metasedimentary rocks, similar to those of the Paleozoic underlying series, with subordinate contributions from magmatic–metamorphic sources, and a rare supply from mafic metavolcanic rocks. Clay-mineral distribution of mudstones is dominated by illite and illite/smectite mixed-layer that result from differences in provenance, weathering, and burial/temperature history. Illite crystallinity values, illitization of kaolinite, occurrence of typical authigenic minerals and apatite fission-track studies, coupled with a subsidence analysis of the whole Malaguide succession suggest burial depths of at least 4–6 km with temperatures of 140–160 °C, typical of the burial diagenetic stage, and confirm the Middle Miocene exhumation of the Betic Internal Domain tectonic stack topped by the Malaguide Complex.

The Battlefield Palette, lower half

Sculpture, Egyptian, Naqada III; H: 7 23/32 in.; grey mudstone

Stratigrafia fisica ed analisi di facies dei depositi torbiditici della Formazione delle Arenarie del Monte Cervarola tra la Val Secchia e la Val Scoltenna (Aquitaniano-Burdigaliano, Appennino Settentrionale)

The Cervarola Sandstones Formation (CSF), Aquitanian-Burdigalian in age, was deposited in an elongate, NW-stretched foredeep basin formed in front of the growing Northern Apennines orogenic wedge. The stratigraphic succession of the CSF, in the same way of other Apennine foredeep deposits, records the progressive closure of the basin due to the propagation of thrust fronts toward north-east, i.e. toward the outer and shallower foreland ramp. This process produce a complex foredeep characterized by synsedimentary structural highs and depocenters that can strongly influence the lateral and vertical turbidite facies distribution. Of consequence the main aim of this work is to describe and discuss this influence on the basis of a new high-resolution stratigraphic framework performed by measuring ten stratigraphic logs, for a total thickness of about 2000m, between the Secchia and Scoltenna Valleys (30km apart). In particular, the relationship between the turbidite sedimentation and the ongoing tectonic activity during the foredeep evolution has been describe through various stratigraphic cross sections oriented parallel and perpendicular to the main tectonic structures. On the basis of the high resolution physical stratigraphy of the studied succession, we propose a facies tract and an evolutionary model for the Cervarola Sandstones in the studied area. Thanks to these results and the analogies with others foredeep deposits of the northern Apennines, such as the Marnoso-arenacea Formation, the Cervarola basin has been interpreted as a highly confined foredeep controlled by an intense synsedimentary tectonic activity. The most important evidences supporting this hypothesis are: 1) the upward increase, in the studied stratigraphic succession (about 1000m thick), of sandstone/mudstone ratio, grain sizes and Ophiomorpha-type trace fossils testifying the high degree of flow deceleration related to the progressive closure and uplift of the foredeep. 2) the occurrence in the upper part of the stratigraphic succession of coarse-grained massive sandstones overlain by tractive structures such as megaripples and traction carpets passing downcurrent into fine-grained laminated contained-reflected beds. This facies tract is interpreted as related to deceleration and decoupling of bipartite flows with the deposition of the basal dense flows and bypass of the upper turbulent flows. 3) the widespread occurrence of contained reflected beds related to morphological obstacles created by tectonic structures parallel and perpendicular to the basin axis (see for example the Pievepelago line). 4) occurrence of intra-formational slumps, constituted by highly deformed portion of fine-grained succession, indicating a syn-sedimentary tectonic activity of the tectonic structures able to destabilize the margins of the basin. These types of deposits increase towards the upper part of the stratigraphic succession (see points 1 and 2) 5) the impressive lateral facies changes between intrabasinal topographic highs characterized by fine-grained and thin sandstone beds and marlstones and depocenters characterized by thick to very thick coarse-grained massive sandstones. 6) the common occurrence of amalgamation surfaces, flow impact structures and mud-draped scours related to sudden deceleration of the turbidite flows induced by the structurally-controlled confinement and morphological irregularities. In conclusion, the CSF has many analogies with the facies associations occurring in other tectonically-controlled foredeeps such as those of Marnoso-arenacea Formation (northern Italy) and Annot Sandstones (southern France) showing how thrust fronts and transversal structures moving towards the foreland, were able to produce a segmented foredeep that can strongly influence the turbidity current deposition.

Triassic stratigraphy and sedimentology in central England

The Triassic rocks of Central England consist of three major stratigraphic units: Sherwood Sandstone Group, Mercia Mudstone Group, and Penarth Group. The lower part of the Sherwood Sandstone Group represented by the Kidderminster, Cannock Chase, and Polesworth Formations represents pebbly braided river deposits carried by a major fluvial system flowing to the North-Northwest. The upper part of the Sherwood Sandstone Group includes the Wildmoor and Bromsgrove Sandstone Formations, the deposits of a sandy alluvial system. The Mercia Mudstone Group represents quiet-water deposits of marginal palya type which were subjected to occasional marine flooding. The overlying Penarth Group represent shallow marine and lagoonal environment associated with the Rhaetian marine transgression. The mineralogy of the Triassic sandstones indicates that the main source was from medium to low rank metamorphic rocks with additional supplies from igneous and metamorphic rocks. The study of size-composition trends shows that the climate was semiarid in early Triassic time and became more humid later. The Triassic sandstones show a variety of diagenetic features typical of continental red beds; these include: 1. the dissolution of unstable ferromagnesian silicates, 2. the replacement of detrital grains by clay, 3. the pseudomorphism of biotite by haematite, and 4. the formation of a suite of authigenic minerals including quartz, illite, mixed-layer illite-montmorillonite, kaolinite, k-feldspar, haematite, titanium oxide and later carbonate cement. Palaeomagnetic studies of selected samples show that the magnetization is muticomponent with the various components being carried by different textural phases of haematite.