Annotated record of the detailed examination of Mn deposits from R/V Atlantis - Cruise 151 (Dec. 1947) in the Atlantic Ocean

One of the objectives of WHOI Atlantis Cruise 151, covering the period from 7 December 1947 to 18 June 1948, was to obtain as complete a sampling of the sea bottom of the Meditterranean and Aegean Seas as was compatible with the remainder of the scientific program. It was furthermore planned to make concurrent bottom photographs as a means for studying the correlation between bottom sediments and the morphology of the sea floor. The photographs also held the possibility of determining the presence of bottom fauna. The underwater camera used for this work was loaned to us by Dr. Maurice Ewing of Columbia University. As it was fitted with a one foot long coring tube at the base of its pole a majority of the bottom samples were obtained by the camera itself. On the way to Gibraltar, several bottom photos were taken in the Atlantic ocean. One of them was the deepest underwater photograph ever taken at the tima (3026 fathoms) showing a cluster of objects, some as much as 5 inches across on a clay bottom. These appeared to be manganese nodules, judging from their rounded and bulbous shape, especially the potato-like form of some of them. A core sample obtained at the same spot with a corer attached to the camera stand contained abundant manganese grains.

Annotated record of the detailed examination of Mn deposits from WAHINE Expedition stations

The cores described in this report were taken on the WAHINE Expedition in February to March 1965 by the Scripps Institution of Oceanography from the R/V Spencer F. Baird. A total of 54 cores and dredges were recovered and are available at Scripps for sampling and study.

Annotated record of the detailed examination of Mn deposits from R/V Tokaidaigaku Maru II Cruise GDP-11 stations

The eleventh research cruise of Japanese Geodynamics Project in the West Pacific was carried out by the R/V Tokaidaigaku-maru II in August, 1974. During this cruise, in which the authors participated, many traverses of echo sounding and seismic reflection profiling and frequent sampling of bottom sediments were undertaken.

Annotated record and illustrations of Mn nodules retrieved during cruise KH-73-4 of the R/V Hakuho Maru and cruises GH76-1 and GH77-1 of the R/V Hakurei Maru

Deep sea manganese nodules from the Central Pacific Basin are mainly composed of 10Å manganite and d-MnO2 Two zones equivalent to the minerals are evidently distinguishable according to their optical properties. Microscopic and microprobe analyses revealed quite different chemical compositions and textnral characteristics of the two zones. These different feature of the two zones of nodules suggest the different conditions under which they were formed. Concentrations of 11 metal elements in the zones and inter-element relationships show that the 10Å manganite zone is a monomineralic oxide phase containing a large amount of manganese and minor amounts of useful metals, and that the d-MnO2 zone which is apparently homogeneous under the microscope is a mixture of three or more different minerals. The chemical characteristics of the two zones can explain the variation of bulk composition of deep sea manganese nodules and inter-element relationships previously reported, suggesting that the bulk compositions are attributable to the mixing of the 10Å manganite and d-MnO2 zones in various ratios. Characteristic morphology and surface structure of some types of nodules and their relationships to chemistry are also attribut able to the textural and chemical features of the above mentioned two phases. Synthesis of hydrated manganese oxides was carried out in terms of the formation of manganese minerals in the ocean. The primary product which is an equivalent to d-MnO2 was precipitated from Mn 2+ -bearing alkaline solution under oxigenated condition by air bubbling at one atmospheric pressure and room temperature. The primary product was converted to a l0Å manganite equivalent by contact with Ni 2+, Cu 2++ or CO2+ chloride solutions. This reaction caused the decrease of Ni2+, Cu2+ or CO2+ concentrations and the increase of Na+ concentration in the solution. The reaction also proceeded even in diluted solutions of nickel chloride and resulted in a complete removal of Ni2+ from the solution. Reaction products were exclusively 10Å manganite equivalents and their chemical compositions were very similar to those of 10Å manganite in manganese nodules. The maximum value of(Cu+Ni+Co)/Mn ratio of 10Å manganite zones in manganese nodules is 0.16, and the Ni/Mn ratio of synthetic 10Å manganite ranges from 0.15 to 0.18 with the average of 0.167.

Annotated record and chemical composition of ferromanganese concretions and crusts sampled from the lakes and streams of Norway

The main objective of the project was to develop a geochemical method for exploration of ores associated with granitic rocks. Fe and Mn oxidates were sampled in streambeds and lakes from 129 localities in Southeastern Norway. 65 of these localities are situated in the northern Oslo Graben. The samples were examined mineralogically and chemically by a variety of methods. Geochemical maps of the element content in oxidates show regional distribution patterns for several elements. Sampling and analysis of oxidates can be used in exploration for mineralizations such as the Skrukkelia Mo-deposit in the northern Oslo Graben. New anomalies (especially for Zn and W) have been detected. Appendix I contains a description of samples, chemical and mineralogical determinations performed on the samples, backscattered electron image-, X-ray image- and scanning electron image pictures of the oxidate preparates. Appendix II contains spectral plots, point analysis with the microprobe, X-ray diffractograms, analytical results, correlation coefficient matrix, scatterplots, frequency distributions and information on data storage. Appendix III containS maps of the element content in oxidates.

Annotated record of the detailed examination of Mn deposits recovered from dredges and cores from VEMA 16 Expedition stations

The cores and dredges described in this report were taken during the Vema 16 Expedition from October 1959 until September 1960 by the Lamont Geological Observatory, Columbia University from the R/V Vema. An approximate total of 300 cores, dredges and camera stations were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.

Annotated record of the detailed examination of ferromanganese concretions from the Bothnia Gulf, the Baltic Sea and the Barents sea collected by Boström, K. and Ingri, J. (Technical University of Lulea)

The collection of ferromanganese nodules at Naturhistoriska Riksmuseet, Stockholm, Sweden has been donated by Pr. Boström, K. and Ingri, J. from the Technical University of Lulea. They have been collected in the Bothnia Gulf, the Baltic Sea anfd the Barents sea from 1976 until 1985. In 1997 it is was put to the care custody of the Laboratory for Isotope Geology (LIG) of NRM. As part of the Access Project at LIG, Curt Boman has gone through the collection and established a database with detailed information about the samples it contains. Ferromanganese nodules typically display a rounded shape and are formed by redox processes at the interface between the seabed sediment and water. In addition to iron and manganese they also contain other metal elements. Nodules chemical composition reflects the substances found in the sediment to which they are associated. Since the nodules grow continuously, they reflect changes in the sedimentary environment chemistry on a yearly basis, which makes them very interesting as environmental archives. The nodules can be found locally in large quantities and due to their metal content they are also economically interesting as a source of raw materials.

Annotated record of the detailed examination of Mn deposits from SCAN Expedition stations

The cores described on the following pages were obtained on the Scripps Institution of Oceanography SCAN Expedition during March 1969 to February 1970 aboard R/V Argo. The primary purpose of the expedition was to conduct geological surveys of prospective drilling sites for the Deep Sea Drilling Project. A total of 106 locations in the Pacific Ocean were geologically sampled, usually by coring but, on occasion, by dredging. The following descriptions are of all the cores taken on SCAN which are available at Scripps for sampling and study.

Annotated record of the detailed examination of Mn deposits from COCOTOW Expedition stations

The cores and dredges described in this report were taken on the COCOTOW Expedition in September until December 1974 by the Scripps Institution of Oceanography from the R/V Spencer F. Baird. A total of 75 cores and dredges were recovered and are available at Scripps for sampling and study.

Annotated record of the detailed examination of Mn deposits from the R/V Thomas Washington ROUNDABOUT Cruise stations

The cores described are taken during the R/V Thomas Washington ROUNDABOUT Cruise from May 1988 until March 1989 by the Scripps Institute of Oceanography. A total of 159 cores and dredges were recovered and are available at Scripps Institute of Oceanography for sampling and study.

Annotated record of the detailed examination of Mn deposits from SOUTHTOW Expedition stations (R/V Thomas Washington)

The cores described in this report were taken on the SOUTHTOW Expedition in June 1972 to January 1973 by the Scripps Institution of Oceanography from the R/V Thomas Washington. A total of 105 cores and dredges were recovered and are available at Scripps for sampling and study.

Annotated record of the detailed examination of Mn deposits from the TRIPOD Expedition stations

The cores and dredges described in this report were taken on the TRIPOD Expedition from November until December 1966 by the Scripps Institution of Oceanography from the R/V Argo. A total of 38 cores and dredges were recovered and are available at Scripps for sampling and study.

Annotated record of the detailed examination of Mn deposits from R/V Velero IV Cruise 404 stations

The geographical, physical and biological aspects of the submarine canyons of the continental shelf off the coast of southern California have been described in earlier parts of this volume. Isopods were collected in 10 of the 15 canyons. Many benthic species were obtained since the specimens were obtained with a Campbell grab bottom sampler operated from the Hancock Foundation research vessel Velero IV.

Annotated record of the detailed examination of Mn deposits from the Snellius II - Cruise 4 stations in the vicinity of the island of Misool, Eastern Indonesia

The chemical analyses of ferromanganese encrustations found on the seabed west of Misool, eastern Indonesia, indicate that these deposits formed in a way different from that of world-wide occurring manganese nodules. Ferromanganese coated pebbles and fragments that were found in the deeper parts of the study area probably originate from nearby ridges. The ferromanganese crust on the upper part of a dolomite fragment of ?30 kg is likely to be formed by hydrogenous processes, whereas that from the lower part seems to be formed by diagenetic processes mainly. These assumptions are supported by pore-water data from two box cores taken in the same area. The manganese and iron profiles versus depth in these cores indicate a high flux of these metals to the uppermost sediment layer, and possibly into the overlying bottom water. Factor analysis for the principal components of the microprobe analytical results of the mainly hydrogenous ferromanganese crust demonstrates a strong correlation of manganese with the trace metals, of iron with phosphorus and an antipathetic relationship between iron and manganese. Similar results have also been reported for abyssal manganese nodules in the world oceans. Factor analysis for the principal components of the analytical data obtained for the diagenetic ferromanganese crust results in a clear dolomite (Ca/Mg) dilution factor only.

Annotated record of the detailed examination of Mn deposits from SEVENTOW (7TOW) Expedition stations

The cores described in this report were taken on the SEVENTOW Expedition in February-September 1970 by the Scripps Institution of Oceanography from the R/V Thomas Washington. A total of 193 cores and dredges were recovered and are available at Scripps for sampling and study.