Quantification of water content across a cement-clay interface using high resolution neutron radiography

In many designs for radioactive waste repositories, cement and clay will come into direct contact. The geochemical contrast between cement and clay will lead to mass fluxes across the interface, which consequently results in alteration of structural and transport properties of both materials that may affect the performance of the multi-barrier system. We present an experimental approach to study cement-clay interactions with a cell to accommodate small samples of cement and clay. The cell design allows both in situ measurement of water content across the sample using neutron radiography and measurement of transport parameters using through-diffusion tracer experiments. The aim of the high- resolution neutron radiography experiments was to monitor changes in water content (porosity) and their spatial extent. Neutron radiographs of several evolving cement-clay interfaces delivered quantitative data which allow resolving local water contents within the sample domain. In the present work we explored the uncertainties of the derived water contents with regard to various input parameters and with regard to the applied image correction procedures. Temporal variation of measurement conditions created absolute uncertainty of the water content in the order of ±0.1 (m3/m3), which could not be fully accounted for by correction procedures. Smaller relative changes in water content between two images can be derived by specific calibrations to two sample regions with different, invariant water contents.

Elemental abundance and water content at DSDP Leg 86 Holes

X-ray fluorescence analyses of 1143 samples from Site 576 (32°21.4'N, 164°16.5'E) and 539 samples from Site 578 (33°55.6'N, 151°37.7'E) for the elements Na, Mg, Al, Si, P, K, Ca, Ti, Mn, Fe, Ba, and S show consistent trends from Si-rich surficial deposits to dark brown clays rich in Mn, Fe, P, and Ti in early Cenozoic sections. These data sets form the basis for a detailed paleogeochemical stratigraphy of North Pacific "red" clays.

Inorganic geochemistry, epoch and water content in sediments at DSDP Hole 91-595A

This chapter summarizes the principal results of drilling at Deep Sea Drilling Project (DSDP) Site 595, where the Ngendei Seismic Experiment and the emplacement of DARPA's Marine Seismic System (MSS) were carried out. Background and objectives for this work are presented in the introductory chapter to this volume. Interpretation of the seismic experiment and drilling results are presented in subsequent parts of this volume. The chapter also provides a detailed operational summary of the successful deployment of the MSS during Leg 91.

Inorganic geochemistry, epoch and water content in sediments at DSDP Site 91-596

Originally, we had planned to piston core at Site 595 in order to meet the sedimentologic and biostratigraphic objectives outlined in the introductory chapter. However, consultation with our colleagues, Thomas Jordan and John Orcutt on board Melville, indicated that coring near the ocean bottom seismometer (OBS) array around Hole 595B could alter the programmed signal to noise ratio above which teleseisms trigger recording in the OBSs. They requested that we core no closer than about 8 km from three OBSs nearest Hole 595B, and selected a target for us about that distance to the west. Since a new beacon was required at this distance, a new site number, 596, was designated. Briefly, we planned to obtain oriented hydraulic piston cores to the top of the cherts, then core through the cherts using the extended core barrel (XCB) to basement. With improved recovery, we hoped to reach the sediment/basalt contact, and thus obtain a reliable biostratigraphic determination of the basement age. We planned to obtain at least one core in basement, perhaps more, with time permitting. We planned no geophysical program for the hole.

Cation exchange capacity and water content of ODP sites from Nankai

Pore fluid chlorinity lower than seawater is often observed in accretionary wedges and one of the possible causes of pore water freshening is the smectite to illite reaction. This reaction occurs during diagenesis in the 80-150°C temperature range. Low chlorinity anomalies observed at the toe of accretionary wedges have thus been interpreted as evidence for lateral fluid migration from inner parts of the wedge and the seismogenic zone. However, temperature conditions in Nankai Trough are locally high enough for the smectite to illite transition to occur in situ. Cation exchange capacity is here used as a proxy for smectite content in the sediment and the amount of interlayer water released during the smectite to illite reaction represents in average 12 water molecules per cation charge. Water and chloride budget calculations show that there is enough smectite to explain the chlorinity anomalies by in situ reactions. The shape of the pore fluid chlorinity profiles can be explained if compaction is also taken into account in the model. Lateral flow is not needed. This argument, based solely on chloride concentration, does not imply that lateral flow is absent. However, previous estimations of lateral fluid fluxes, and of the duration of transient flow events along the de.collement, should be reconsidered.