999 resultados para RUBIDIUM


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We present ab initio quantum chemistry calculations for elastic scattering and the radiative charge transfer reaction process and collision rates for trapped ytterbium ions immersed in a quantum degenerate rubidium vapor.
The collision of the ion (or ions) with the quasiatom is the key mechanism to transfer quantum coherences between the systems. We use first-principles
quantum chemistry codes to obtain the potential surfaces and coupling terms for the two-body interaction of Yb^+ with Rb. We find that the low energy collision has an inelastic radiative charge transfer process in agreement with recent experiments.
The charge transfer cross section agrees well with the semiclassical Langevin model at higher energies but is dominated by resonances at submillikelvin temperatures.

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We investigated commensalism of water use among annual shallow-rooted and perennial deep-rooted pasture legumes by examining the effect of hydraulic lift by Cullen pallidum (N.T.Burb.) J.W.Grimes and Medicago sativa on growth, survival and nutrient uptake of Trifolium subterraneum L. A vertically split-root design allowed separate control of soil water in top and bottom soil. Thirty-five days after watering ceased in the top tube, but soil remained at field capacity in the bottom tube, an increase in shallow soil water content by hydraulic lift was 5.6 and 5.9 g kg−1 soil overnight for C. pallidum and M. sativa, respectively. Trifolium subterraneum in this treatment maintained higher leaf water potentials (with M. sativa) or exhibited a slower decline (with C. pallidum) than without companion perennial plants; and shoot biomass of T. subterraneum was 56% (with C. pallidum) and 67% (with M. sativa) of that when both top and bottom tubes were at field capacity. Uptake of rubidium (a potassium analog) and phosphorus by T. subterraneum was not facilitated by hydraulic lift. Interestingly, phosphorus content was threefold greater, and shoot biomass 1.5–3.3-fold greater when T. subterraneum was interplanted with C. pallidum compared with M. sativa, although dry weight of C. pallidum was much greater than that of M. sativa. This study showed that interplanting with deep-rooted perennial legumes has benefited the survival of T. subterraneum.

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The effects of varying the alkali metal cation in the high-temperature nucleophilic synthesis of a semi-crystalline, aromatic poly(ether ketone) have been systematically investigated, and striking variations in the sequence-distributions and thermal characteristics of the resulting polymers were found. Polycondensation of 4,4'-dihydroxybenzophenone with 1,3-bis(4-fluorobenzoyl)benzene in diphenylsulfone as solvent, in the presence of an alkali metal carbonate M2CO3 (M= Li, Na, K, or Rb) as base, affords a range of different polymers that vary in the distribution pattern of 2-ring and 3-ring monomer units along the chain. Lithium carbonate gives an essentially alternating and highly crystalline polymer, but the degree of sequence-randomisation increases progressively as the alkali metal series is descended, with rubidium carbonate giving a fully random and non-thermally-crystallisable polymer. Randomisation during polycondensation is shown to result from reversible cleavage of the ether linkages in the polymer by fluoride ions, and an isolated sample of alternating-sequence polymer is thus converted to a fully randomised material on heating with rubidium fluoride.

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In this paper, we report the measurement of Rb(2) molecule formation rate constant due to a two body process in a magneto-optical trap as a function of the sample temperature. The ground state molecules are detected by two-photon ionization, through the intermediate a(3)Sigma(+)(u) -> 2(3)Pi(g) molecular band. Our results show that the Rb(2) molecules formed in the MOT could be due to a wave shape resonance, which enhances the molecule formation rate. This effect may be used to enhance the molecule production; and therefore it maybe important to future experiments involving production and trapping of cold ground state molecules.

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In this paper, I review some recent high-precision Rydberg state lifetime measurements using a cold-trapped sample of neutral atoms held in a magneto-optical trap. The measurements were performed in rubidium for the S, P and D states varying the principal quantum number from n = 26 to 45 using the field ionization technique. The experimental results were compared with quantum mechanical calculations and good agreement was observed. This is an important demonstration of how cold atomic samples can be used to perform high-precision spectroscopy in the time domain.

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A free-running, temperature stabilized diode laser has been injection-locked to an external cavity diode laser for use in cold Rydberg atom experiments. Cold rubidium atoms in a magneto-optical trap (MOT) are excited to Rydberg states using a 10 ns laser pulse. The Rydberg atoms spontaneously ionize due to dipole forces, and the collisional ionization dynamics are observed as a function of atom density and principal quantum number of the Rydberg state, n. The injection-locked diode laser will be used as a repumper in conjunction with a dark spontaneous-force optical trap (SPOT) to increase the Rydberg state density. We report on the design of the injection-locked laser system.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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O objetivo deste trabalho foi determinar o efeito de culturas de inverno e de primavera no crecimento do sistema radicular e na produtividade da soja, e comparar um método direto (trado) com um indireto (com rubídio), na análise do sistema radicular. Utilizou-se o delineamento experimental de blocos ao acaso, em parcelas subdivididas, com quatro repetições. As parcelas foram constituídas pelas culturas de inverno, triticale (X Triticosecale) e girassol (Helianthus annuus), e as subparcelas pelos culturas de primavera, milheto (Pennisetum glaucum), sorgo forrageiro (Sorghum bicolor) e crotalária júncea (Crotalaria juncea), além da escarificação, realizada em 2003 e 2009. A soja (Glycine max) foi cultivada no verão e seu sistema radicular foi avaliado por amostragem física das raízes, com trado, e por avaliação da atividade radicular com rubídio. Modificações na arquitetura ou na atividade do sistema radicular da soja não afetaram a produtividade. A distribuição física e a atividade radicular não foram afetados significativamente pelas espécies de inverno, mas o crescimento foi favorecido após o cultivo do milheto e do sorgo forrageiro, na primavera. A medida direta do sistema radicular com trado apresenta baixa correlação com a atividade radicular.

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Synthesis and crystallographic data are reported for the double rubidium-scandium chromate RbSc(CrO4)2. The parameters of the orthorhombic cell are a = 14.836(2) A ̊; b = 5.627(1) A ̊ and c = 8.835(4) A ̊, Z = 4. The compound is closely related to the lamellar double chromates with other alkali metal cations, iron, lanthanides and yttrium offering the advantage of obtaining inorganic materials for electronics. © 1995.

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Numerical simulations based on the time-dependent mean-field Gross-Pitaevskii equation was performed to explain the dynamics of collapsing and exploding Bose-Einstein condensates (BEC) of 85Rb atoms. The atomic interaction was manipulated by an external magnetic field via a Feshbach resonance. On changing the scattering length of atomic interaction from a positive to a large negative value, the condensate collapsed and ejected atoms via explosion.

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The scaling dependence of the recombination parameter as a function of the ratio between the energies of the atomic dimer and the most excited trimer states was derived. The scaling function tends to a unversal function in the limit of zero-range interaction or infinite scattering length. This paper reports on how one can obtain the trimer binding energy of a trapped atomic system, from the three-body recombination rate and the corresponding two-body scattering length.

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In the present work, we examined the effects of feeding a low protein diet during pregnancy on glucose-induced insulin secretion and glucose homeostasis in rats. Young (60 days), pregnant (P) or non-pregnant (NP) rats were fed during pregnancy or for 21 days (the NP) a normal (17%) or a low (6%) protein diet. Serum glucose and insulin levels and pancreas insulin content in the fed state; total area under serum glucose curve (AG) after a glucose load and serum glucose disappearance rate (Kitt) after insulin administration; as well as 86Rb outflow, 45Ca uptake and insulin secretion by isolated pancreatic islets in response to glucose were evaluated. Serum glucose was lower in 17%-P (12%) and 6%-P (27%) than in corresponding NP-rats. Serum insulin was higher in 17%- P (153%) and 6%-P (77%) compared to the corresponding NP-rats. Pancreatic insulin was higher in 6%-rats (55%) than in 17%-rats. No differences were found in AG among the groups whereas Kitt was lower in 6%-NP and higher in 6%-P than in the equivalent 17% rats. Increasing glucose concentration from 2.8 to 16.7 mmol/l, reduced 86Rb outflow from isolated islets from all groups. Increasing glucose concentration from 2.8 to 16.7 mmol/l elevated 45Ca uptake by 17%-NP (47%), 17%-P (40%) and 6%-P (214%) islets but not by 6%-NP ones. The increase in 45Ca uptake was followed by an increase in insulin release by the 17%-NP (2767%), 17%-P (2850%) and 6%-P (1200%) islets. In conclusion, 6%-P rats show impaired glucose induced insulin secretion related to reduced calcium uptake by pancreatic islets. However, the poor insulin secretion did not fully compensate the high peripheral sensitivity to the hormone, resulting in hypoglycemia.

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We study the statics and dynamics of a dipolar Bose-Einstein condensate (BEC) droplet bound by interspecies contact interaction in a trapped nondipolar BEC. Our findings are demonstrated in terms of stability plots of a dipolar 164Dy droplet bound in a trapped nondipolar 87Rb BEC with a variable number of 164Dy atoms and interspecies scattering length. A trapped nondipolar BEC of a fixed number of atoms can bind only a dipolar droplet containing fewer atoms than a critical number for the interspecies scattering length between two critical values. The shape and size (statics) as well as the small breathing oscillation (dynamics) of the dipolar BEC droplet are studied using numerical and variational solutions of a mean-field model. We also suggest an experimental procedure for achieving such a 164Dy droplet by relaxing the trap on the 164Dy BEC in a trapped binary 87Rb-164Dy mixture. © 2013 American Physical Society.

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We consider three-body systems in two dimensions with zero-range interactions for general masses and interaction strengths. The momentum-space Schrödinger equation is solved numerically and in the Born-Oppenheimer (BO) approximation. The BO expression is derived using separable potentials and yields a concise adiabatic potential between the two heavy particles. The BO potential is Coulomb-like and exponentially decreasing at small and large distances, respectively. While we find similar qualitative features to previous studies, we find important quantitative differences. Our results demonstrate that mass-imbalanced systems that are accessible in the field of ultracold atomic gases can have a rich three-body bound state spectrum in two-dimensional geometries. Small light-heavy mass ratios increase the number of bound states. For 87Rb-87Rb-6Li and 133Cs- 133Cs-6Li we find respectively three and four bound states. © 2013 IOP Publishing Ltd.

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We solve the three-body bound-state problem in three dimensions for mass imbalanced systems of two identical bosons and a third particle in the universal limit where the interactions are assumed to be of zero range. The system displays the Efimov effect and we use the momentum-space wave equation to derive formulas for the scaling factor of the Efimov spectrum for any mass ratio assuming either that two or three of the two-body subsystems have a bound state at zero energy. We consider the single-particle momentum distribution analytically and numerically and analyze the tail of the momentum distribution to obtain the three-body contact parameter. Our findings demonstrate that the functional form of the three-body contact term depends on the mass ratio, and we obtain an analytic expression for this behavior. To exemplify our results, we consider mixtures of lithium with either two caesium or rubidium atoms which are systems of current experimental interest. © 2013 American Physical Society.