Composition of palygorskite-rich and montmorillonite-rich zeolite-containing sediments from DSDP Sites 164 and 196

Cretaceous, Tertiary, and Quaternary sediments from Deep Sea Drilling Project Sites 164 and 196 (13°12' N, 161°31' W and 30°07' N, 148°34' E, respectively) were analyzed for major chemical elements and mineralogy. Sediments from these sites contain large proportions of authigenic minerals: mainly palygorskite, clinoptilolite and chert in the Cretaceous, and montmorillonite, phillipsite and chert in the Tertiary. The montmorillonite-phillipsite assemblage is thought to be derived from volcanic ash or glass, and the palygorskite-clinoptilolite assemblage is thought to be derived by reaction of biogenic silica with volcanic ash or glass or with montmorillonite and phillipsite. Both assemblages have generally moderate Ti/Al ratios, ranging from 0.026 to 0.047, so most of the palygorskite, clinoptilolite, montmorillonite and phillipsite could not be derived in situ from alteration of basaltic material. Plagioclase compositions suggest that the volcanic precursors were silicic or intermediate, but it is also possible that the sediments have been extensively fractionated by redistribution from nearby seamounts. Available data on other Late Cretaceous sediments in the Pacific were analyzed. Clinoptilolite and chert are present nearly everywhere where palygorskite is abundant; phillipsite is rare where palygorskite is abundant. It is suggested that increased water temperatures during the Cretaceous increased reaction rates and determined the alteration products.

Benthic foraminifera of surface sediments from the continental slope off Sierra Leone, North-West Africa

On "Meteor" cruise 30 (1973) 22 piston-cores were collected off Sierra Leone from water-depths between about 5000 m (Sierra Leone Basin) and 500 m (upper continental slope) with the objective to study the sediment composition and age as well as processes of sedimentation on the continental slope in a tropical humid region. Granulometric analysis and determinations of the carbonate contents of the sediment samples were carried out, as well as qualitative and quantitative analysis of the components of the grain size fractions > 63 µm and of the planktonic and benthonic foraminifera > 160 µm. Presently, the cold Canary Current influences the composition of the planktonic foraminifera within the northwestern area of investigation (profile A), whereas the planktonic fauna of the eastern area (profile C) seems to be truly tropical. In all Quaternary sediments from the continental slope off Sierra Leone, species of Globorotalia are less abundant than in truly pelagic sediments. For that reason, the zonation of the Pleistocene sediments based on the presence or absence of Globorotalia cultrata does not always agree with the climatic changes reflected in the sediments. Concerning past climates better results can be obtained by using the changes in percentage abundances of Globigerina sp. sp. and Globigerinoides sp. sp. as indicators for cool and warm temperatures. The Tertiary sediments contain a pelagic foraminiferal assemblage. In the Holocene sediments the benthonic foraminifera do not only serve as good paleodepth indicators, but their communities are also restricted to defined water masses, which change their positions in accordance with climatic changes. Thus, Cassidulina carinata in the area of investigation is an excellent indicator for sediments deposited during times, which were cooler than today; this is true for all cores from the continental slope off Sierra Leone independent of water-depth although this species presently abounds at water-depths around 600 m. The cores from the continental rise and from the Sierra Leone Basin (M30-261, M30-146, M30-147) were deposited below the calcium carbonate compensation depth. Only small sections of the cores consist of the original carbonate-free sediments, whereas the main part of the sediment column is redeposited material, rich in foraminifera, which normally live on the upper continental slope, or even on the shelf. From these cores only M30-261 can be subdivided into biostratigraphic zones ranging from zone V to zone Y. In all cores from the middle and upper continental slope of the eastern area of investigation (profile C; KL 230, 209-204) and in cores KL 183 and KL 184 from the northwestern area (profile A) we observed an undisturbed succession of sediments from the biostratigraphic zones X (partly), Y and Z. All cores from the central area (M30-181, M30-182, M30-262 to 264) and M30-187 from the upper slope of profile A show variable hiatuses in the sedimentary record. Locally, high velocity bottom currents were probably responsible for erosion, nondeposition or minimal sedimentation rates. These currents might have been initiated partly by the somewhat exposed position of this part of the continental slope, where the shelf edge bends from a northwest towards an eastern direction, and partly by very young tectonic movements. Fracture zones with vertically displaced fault blocs are frequent at Sierra Leone continental margin. According to seismic measurements by McMaster et al. (1975) the sites of the central area are located on an uplifted fault bloc explaining the reduced sediment rates or erosion. Unlike the central area, the eastern area (profile C) is situated on a downfaulted bloc with high sediment rates. The sediments from the cores of profile B as well as the turbiditic deep-sea sediments were deposited under a higher flow regime; therefore they are coarser than the extremely fine-grained sediments of the cores from profile C. Since the sand fraction (> 63 µm) is mainly composed of foraminifera, besides pteropods and light-colored fecal pellets, the carbonate content increases with the increasing percentage of the coarse grain fraction. Higher concentrations of quartz were only observed in core sections with considerable carbonate dissolution (mainly in the X-Zone), and, in general, in all sediments from the eastern area with higher terrigenous input including larger concentration of mica. Especially during times transitional between glacials and interglacials (or interstadials) the bottom currents were intensified. The percentages of coarse fraction and carbonate increase with increasing current velocities. Calcium carbonate dissolution becomes important in water depths > 3500 m. During cooler times the lysokline is depressed. Light-colored fecal pellets were redeposited from Late Neogene sediments (M30-187, M30-181). In the area of investigation they occur in the Holocene and mainly the Pleistocene sediments of the cores from the northwestern and central area because only here Tertiary sediments have been eroded at the uppermost continental slope. In the central area there are at least two periods of non-sedimentation and/or erosion which can be confined as being (1) not older than middle Pliocene and not younger than zone V and (2) younger than zone W. The local character of the erosion is documented by the fact that a complete Late Quaternary section is present in the cores of the northwestern and eastern area, each within less than 100 km from incomplete cores from the central area.

Eocene to Quaternary planktonic foraminifers from the Northwest Pacific

Eocene through Quaternary planktonic foraminifers were identified in cores recovered during Leg 126. Turbidites and volcanic ash beds are intercalated with hemipelagic sediments. Preservation of foraminifers is variable, ranging from excellent to poor and appears to have been affected by fluctuations in the carbonate compensation depth (CCD), depth of burial, changes in bottom water temperature, current velocity, sediment accumulation rates and seafloor topography. Preservation of foraminifers in Quaternary sediments is generally good, however, species abundance varies by a factor of I05-106 and reflects dilution by volcanogenic as well as terrigenous constituents and cannot be used for paleoceanographic reconstructions. In pre-Quaternary deposits planktonic foraminiferal tests frequently exhibit dissolution effects; biostratigraphic zonation and placement of zonal boundaries is difficult owing to hiatuses, dissolution facies, extraneously deposited sediments, and discontinuous coring. The Eocene foraminiferal faunas include specimens of the Globorotalia cerroazulensis plexus, markers of Zone P16 as well as Globigerina senni and Globigerinatheka spp., which became extinct before the end of the Eocene. Six hiatuses and/or dissolution periods, probably reflecting global cooling events and/or changes in oceanic circulation patterns were recorded at Site 792. Recrystallized, poorly preserved, possibly reworked Eocene species (Globigerina senni and Globigerapsis sp.) were recorded in sediments at Site 793.

Stratigraphic first occurrence of Emiliania huxleyi in sediments of the Chatham Rise (Table 2)

A quantitative analysis was carried out of planktonic diatoms (biogenic opal) and calcareous nannofossils (biogenic calcite) in late Quaternary sediments (MIS 1-6) from four cores along a N-S transect east of New Zealand from 39°50'S to 50°04'S across the E-W-trending submarine ridge, the Chatham Rise. This was done to trace movements of oceanic fronts and to improve calcareous nannofossil stratigraphy for the last 130 000 yr in the SW Pacific. Sites ODP 1123 and Q 858 are below present day subtropical surface waters north of Chatham Rise. Site DSDP 594 is below present-day mixed temperate-subantarctic surface water south of the rise, and site ODP 1120 is below subantarctic surface water. The more diverse and opportunistic planktonic diatoms provided marker species for subtropical surface waters (Alveus marina, Fragilariopsis doliolus, Rhizosolenia bergonii and Azpeitia nodulifer) and others for subantarctic surface waters (Nitzschia kerguelensis, Thalassiosira lentiginosa). Application of these tracers permits the following conclusions: (1) subtropical conditions persisted north of Chatham Rise throughout the past 130 000 yr, in spite of the cooling of surface waters during colder periods; (2) during warm times (MIS 5 and MIS 3, and in MIS 1), the sporadic occurrence of subtropical species south of Chatham Rise indicates occasional admixture of subtropical surface waters that far south; (3) subantarctic waters extended to the southern slopes of the Chatham Rise during MIS 5b, late MIS 5a to early MIS 4, during the warmer time intervals in early MIS 3, and during latest MIS 3 to early MIS 2; (4) subantarctic frontal conditions existed over southern Chatham Rise during early MIS 4 and late MIS 3 to early MIS 2; and (5) it is probable that during cooler times, MIS 6, MIS 5b, and in MIS 2, intensified particle transport from the Bounty Trough to the northern flank of Chatham Rise occurred by intensified boundary currents. The larger abundance fluctuations in both microfossil groups at the sites south of Chatham Rise than north of Chatham Rise reflect northward shifts of the Circumpolar Subantarctic Water (CSW) and a contemporaneous disappearance of Australasian Subantarctic Water (ASW), implying an elevated temperature gradient between the surface water masses north and south of the Chatham Rise at the times of such northward shifts of CSW. Calcareous nannofossils are less diverse than diatoms, and are less specialised. Some calcareous nannofossil species show abundance shifts at the same time at different latitudes. Two of these abundance shifts can be used for correlation between subtropical and subantarctic sediments in the SW Pacific: (1) reversal in the relative abundance of Calcidiscus leptoporus and Coccolithus pelagicus associated with the MIS 2/1 boundary; and (2) drop in abundance of Gephyrocapsa muellerae or medium-sized Gephyrocapsa at the MIS 4/3 boundary. An additional abundance shift seems to be restricted to subtropical to mixed temperate-subtropical-subantarctic surface waters: (3) increase in abundance of G. muellerae or medium-sized Gephyrocapsa at the beginning of MIS 2 below the Okareka tephra.

(Table 1) Textural characteristics of sediments at DSDP Leg 71 Holes

In conjunction with a study of ice-rafted detritus (IRD), textural analyses were carried out on Miocene to Quaternary sediments at Sites 511, 512, 513, and 514. Grain-size statistics were computed for the <62.5 µm fraction in order to identify changes in current velocity; the sand fraction was omitted from these determinations because it consists primarily of ice-raft and biogenic components. The contributions by terrigenous sediment in the 62.5-250 µm and the >250 µm fractions were determined.

Geochemistry of tetrapyrrole, tetraterpenoid, and perylene pigments in sediments from the Gulf of California

Results and discussion cover pigment analyses of 36 sediment samples recovered by Deep Sea Drilling Project Leg 64, and six samples from the Leg 64 site-survey cruise in the Guaymas Basin (Scripps Institution of Oceanography, Leg 3). Pigments investigated were tetrapyrroles, tetraterpenoids, and the PAH compound perylene. Traces of mixed nickel and copper ETIO-porphyrins were ubiquitous in all sediment samples, except for the very surface (i.e., <2 m sub-bottom), and their presence is taken as an indication of minor influxes of previously oxidized allochthonous (terrestrial) organic matter. Phorbides and chlorins isolated from Site 479 sediment samples (i.e., the oxygen-minimum locale, northeast of the Guaymas Basin) well represent the reductive diagenesis ("Treibs Scheme"; see Baker and Palmer, 1978; Treibs, 1936) of chlorophyll derivatives. Three forms of pheophytin-a, plus a variety of phorbides, were found to give rise to freebase porphyrins, nickel phylloerythrin, and nickel porphyrins, with increasing depth of burial (increasing temperature). Sediments from Sites 481, 10G, and 18G yielded chlorophyll derivatives characteristic of early oxidative alterations. Included among these pigments are allomerized pheophytin-a, purpurin-18, and chlorin-p6. The high thermal gradient imposed upon the late Quaternary sediments of Site 477 greatly accelerated chlorophyll diagenesis in the adjacent overlying sediments, that is, the production of large quantities of free-base desoxophylloerythroetioporphyrin (DPEP) occurred in a section (477-7-5) presently only 49.8 meters sub-bottom. Present depth and age of these sediments are such that only chlorins and phorbides would be expected. Carotenoid (i.e., tetraterpenoids) concentrations were found to decrease rapidly with increasing sub-bottom depth. Less deeply buried sediments (e.g., 0-30 m) yielded mixtures of carotenes and oxygen-substituted carotenoids. Oxygencontaining (oxy-, oxo-, epoxy-) carotenoids were found to be lost preferentially with increased depth of burial. Early carotenoid diagenesis is suggested as involving interacting reductions and dehydrations whereby dehydro-, didehydro-, and retro-carotenes are generated. Destruction of carotenoids as pigments may involve oxidative cleavage of the isoprenoid chain through epoxy intermediates, akin to changes in the senescent cells of plants. Perylene was found to be a common component of the extractable organic matter from all sediments investigated. The generation of alkyl perylenes was found to parallel increases in the existing thermal regime at all sites. Igneous sills and sill complexes within the sediment profile of Site 481 altered (i.e., scrambled) the otherwise straightforward thermally induced alkylation of perylene. The degree of perylene alkylation is proposed as an indicator of geothermal stress for non-contemporaneous marine sediments.

Mineralogical, sedimentological and paleontological analyses of ODP Hole 127-797B upper Quarternary sediments

Nearly continuous cores of Quaternary fine-grained sediments with distinct dark-light colored cycles were recovered from Sites 794, 795, and 797 in the basinal parts of the Japan Sea during Leg 127. A comparison of gray value (darkness) profiles supplemented by visual inspection of core photographs between sites indicated that most of the dark and light layers were correlatable between sites, and that two of the dark layers lie close to adjacent marker ash layers. These observations indicate that deposition of dark and light layers resulted from basin-wide synchronous events. In order to understand the origin of these dark-light cycles, petrographical, mineralogical, compositional, and paleontological studies were carried out on closely spaced samples from the upper Quaternary sediments recovered from Site 797. Age model was constructed based on comparison between variation in diatom abundance and the standard oxygen isotope curve of Imbrie et al. (1984), the latter was interpolated between the five age controlled levels established at Site 797. The two curves show similar patterns which enabled us to "tune" the sediment ages to the oxygen isotope stages. We have to use variation in diatom abundance as a substitute for oxygen isotope curve since oxygen isotopic data are not available at the studied sites. Bottom water oxygenation conditions were estimated based on two criteria: (1) the degree of lamina preservation and (2) the ratio of Corg to Stot. The surface water productivity was deduced from the Corg and biogenic silica content. Results suggest that the bottom water oxygenation level and the surface water productivity varied significantly in response to the glacial-interglacial cycles. Glacio-eustatic sea-level changes and subsequent changes in water circulation in the Japan Sea appear to have been responsible for these variations and consequent changes in sediment composition throughout the Quaternary.

Properties, sedimentation and accumulation rates, and chemical composition of bottom sediments from the Deryugin Basin, Sea of Okhotsk

Results of a study of contents and accumulation rates of Fe, Mn, and some trace elements in Upper Quaternary sediments of the Deryugin Basin are presented. Maps of average contents and accumulation rates of excessive Fe, Mn, Zn, Ba, Ni, Pb, Cu, and Mo in sediments of the first oxygen isotope stage (OIS) have been plotted. Anomalous contents and accumulation rates are confined to peripheral zones of the Deryugin sedimentary basin and large fracture zones. Different mechanisms of influence of fluid-dynamic processes on rate of hydrogenic and biogenic accumulation of ore elements are assumed.