Modeling precipitation and its effect on recrystallization during hot strip rolling of niobium steels

Using a physically based model, the microstructural evolution of Nb microalloyed steels during rolling in SSAB Tunnplåt’s hot strip mill was modeled. The model describes the evolution of dislocation density, the creation and diffusion of vacancies, dynamic and static recovery through climb and glide, subgrain formation and growth, dynamic and static recrystallization and grain growth. Also, the model describes the dissolution and precipitation of particles. The impeding effect on grain growth and recrystallization due to solute drag and particles is accounted for. During hot strip rolling of Nb steels, Nb in solid solution retards recrystallization due to solute drag and at lower temperatures strain-induced precipitation of Nb(C,N) may occur which effectively retard recrystallization. The flow stress behavior during hot rolling was calculated where the mean flow stress values were calculated using both the model and measured mill data. The model showed that solute drag has an essential effect on recrystallization during hot rolling of Nb steels.

Processing and mechanical properties of porous titanium-niobium shape memory alloy for biomedical applications

Ti-26 at.%Nb (hereafter Ti-26Nb) alloy foams were fabricated by space-holder sintering process. The porous structures of the foams were characterized by scanning electron microscopy (SEM). The mechanical properties of the Ti-26Nb foam samples were investigated using compressive test. Results indicate that mechanical properties of Ti-26Nb foam samples are influenced by foam porosity. The plateau stresses and elastic moduli of the foams under compression decrease with the increase of their porosities. The plateau stresses and elastic moduli are measured to be from 10~200 MPa and 0.4~5.0 GPa for the Ti-26Nb foam samples with porosities ranged from 80~50 %, respectively.

In vitro bioactivity evaluation of titanium and niobium metals with different surface morphologies

Current orthopaedic biomaterials research mainly focuses on designing implants that could induce controlled, guided and rapid healing. In the present study, the surface morphologies of titanium (Ti) and niobium (Nb) metals were tailored to form nanoporous, nanoplate and nanofibre-like structures through adjustment of the temperature in the alkali-heat treatment. The in vitro bioactivity of these structures was then evaluated by soaking the treated samples in simulated body fluid (SBF). It was found that the morphology of the modified surface significantly influenced the apatite-inducing ability. The Ti surface with a nanofibre-like structure showed better apatite-inducing ability than the nanoporous or nanoplate surface structures. A thick dense apatite layer formed on the Ti surface with nanofibre-like structure after 1 week of soaking in SBF. It is expected that the nanofibre-like surface could achieve good apatite formation in vivo and subsequently enhance osteoblast cell adhesion and bone formation.

Mechanochemical synthesis of niobium pentoxide nanoparticles

Acicular α-FeOOH particles are formed through aging of ferric oxyhydroxide colloidal solution formed by the neutralization of FeCl₃ aqueous solution by NaOH. The effect of foreign ion addition to the colloidal solution on the formation and morphology of α-FeOOH particles has been investigated. The magnetic properties of Fe₃O₄ particles made from the obtained particles have also been investigated. The rate constant of the formation of α-FeOOH remarkably decreased, but the crystallite size of α-FeOOH particles increased with increasing the quantity of phosphate ion added even with small amounts. These results have been explained as follows: the phosphate ions are selectively adsorbed on the (a) plane of α-FeOOH, cover the (a) plane, and block the crystal growth of the (a) plane of the α-FeOOH. The quantities of the phosphate ion adsorbed on the b and c planes are relatively small. The complex ion of Fe(OH)₄^- is preferentially deposited on both (b) and (c) planes, and the crystal growth of (b) and (c) planes is greatly accelerated. The relationship between the morphology of the formed α-FeOOH particles and the quantity of phosphate ion added has been investigated. The asterisk type particles: α-FeOOH particles heterogeneously junctioned to α-Fe₂O₃ particles, were formed when a small amount of phosphate was added to the mother liquid. The α-FeOOH crystal epitaxially grew on the junction interface with the α-Fe₂O₃ crystal. In the case of the aging at the temperature as high as 80°C, the cross type junctioned particles were stably formed at pH below 12.0. The Fe₃O₄ particles with screw-like unique three-dimensional morphology were produced from the heterogeneously junctioned particles.

Bioactive hydroxyapatite coating on titanium-niobium alloy through a sol-gel process

Hydroxyapatite (HA) was coated on the surface of a titanium-niobium (Ti-Nb) alloy by a sol-gel process. Triethyl phosphite and calcium nitrate were used as the phosphorus (P) and calcium (Ca) precursors respectively to prepare a Ca/P sol solution. The Ti-Nb alloy was dip-coated in the sol and heated at 600°C for 30 minutes. X-ray diffraction (XRD) analysis indicated the major phase constituent of the coating after heat treatment was HA. Scanning electron microscopy (SEM) observation showed that a few cracks were distributed on the HA coating. The in-vitro bioactivity of the HA coated Ti-Nb alloy was assessed using a cell culture of SaOS-2 osteoblast-like cells. The density of cell attachment was determined by MTT assay; the cell morphology was observed by SEM. Results indicated that the density of cell attachment on the surface of the Ti-Nb alloy was significantly increased by HA coating. Cell morphology observation showed that cells attached, spread and grew well on the HA coated surface. It can be concluded that the HA coating improved the in-vitro bioactivity of Ti-Nb alloy effectively.

Apatite formation on nano-structured titanium and niobium surface

Current orthopaedic biomaterials research mainly focuses on developing implants that could induce controlled, guided and rapid healing. In the present study, the surface morphologies of titanium (Ti) and niobium (Nb) metals were tailored to form nanoporous, nanoplate and nanofibrelike structures through adjustment of the temperature in the alkali treatment. The in vitro bioactivity of these structures was then evaluated by soaking in simulated body fluid (SBF). It was found that the morphology of the modified surface significantly influenced the apatite inducing ability. The Ti surface with a nanofiber-like structure showed better apatite inducing ability, than the nanoporous or nanoplate surface structures. A thick dense apatite layer formed on the Ti surface with nanofiberlike structure after 1 week soaking in SBF. It is expected that the anofibre-like surface could achieve good apatite formation in vivo and subsequently enhance osteoblast cell adhesion and bone formation in vivo.

Corrosion protection of AA2024-T3 using rare earth diphenyl phosphates

Existing corrosion protection technologies for aluminium alloys utilising chromates are environmentally damaging and extremely toxic. This paper presents a preliminary investigation into rare earth diphenyl phosphates as new environmentally benign corrosion inhibitors. Full immersion weight loss experiments, cyclic potentiodynamic polarisation measurements and Raman spectroscopy were used in this study. Results show cerium diphenyl phosphate (Ce(dpp)₃) acts as a cathodic inhibitor, decreasing cathodic current density and E_corr by passivating cathodic intermetallic particles on the alloy surface. Mischmetal diphenyl phosphate (Mm(dpp)₃) acts a mixed inhibitor, shifting E_corr to more noble values, decreasing cathodic current density, increasing the breakdown potential and suppressing pitting.

In vitro osteoblast-like cell proliferation on nano-hydroxyapatite coatings with different morphologies on a titanium-niobium shape memory alloy

The morphology of nanomaterials significantly affects their physical, chemical, and biological properties. In the present study, nano-hydroxyapatite coatings with different morphologies were produced on the surface of a titanium-niobium shape memory alloy via a hydrothermal process. The effect of the nano-hydroxyapatite coatings on the in vitro proliferation of SaOS-2 osteoblast-like cells was investigated. Factors including crystallinity, surface micro-roughness, and surface energy of the nano-hydroxyapatite coatings were discussed. Results show that in vitro proliferation of the osteoblast-like cells was significantly enhanced on the nano-hydroxyapatite-coated titanium-niobium alloy compared to the titanium-niobium alloy without coating. The cell numbers on the nano-hydroxyapatite-coated titanium-niobium alloy changed consistently with the surface energy of the hydroxyapatite coatings. This study suggests that surface energy as a characteristic parameter influencing the in vitro proliferation of osteoblast-like cells was predominant over the crystallinity and surface micro-roughness of the nano-hydroxyapatite coatings.

Effect of baking process on microstructures and mechanical properties of low silicon TRIP steel sheet with niobium

After 2% predeformation, the baking treatment with different schedule was carried out for low silicon TRIP steel sheet with niobium. The effects of baking temperature and time on microstructures and mechanical properties were investigated. The results showed that with increasing the baking temperature and time, the volume fraction of retained austenite decreases, and the volume fraction of tempered martensite increases; as baking temperature ranges from 80°C to 170°C, the bake-hardening (BH) value increases obviously, while from 170°C to 230°C, the variation of BH value is very slight; as baking time ranges from 2 min to 20 min, the BH value increases significantly, while the BH value decreases when baking time exceeds 20 min. So that when the baking temperature is 170°C and the baking time is 20 min, the low silicon TRIP steel sheet exhibits good bake-hardening behavior, and the highest BH value is above 70 MPa.

Effect of prestrain on microstructures and properties of Si-Al-Mn TRIP steel sheet with niobium

Paint baking treatment was carried out in a silicon oil bath at 170 °C for 20 min for Si-Al-Mn TRIP Steel sheet with different prestrains, and effect of prestrain on microstructures and properties was studied before and after baking. The results show that with the increasing of prestrain amount during prestraining and baking, the volume fraction of retained austenite decreases, and the volume fraction of martensite and bainite increases as well as yield strength increases; as prestrain ranges from 0 to 4%, the baking-hardening (BH) value increases; while the prestrain ranges from 4% to 16%, the BH value decreases; when the prestrain amount is 4%, the highest BH value is about 70 MPa for Si-Al-Mn TRIP steel sheet with niobium, which displays excellent baking-hardening behavior.