FAR INFRARED-LASER LINES AND ASSIGNMENTS OF CH3OH - A REVIEW

Methyl alcohol is the most important lasing molecule in the Far-Infrared (FIR) spectral region, and the most widely used for investigation and for applications. Since the last critical review of 1984, over seventy papers have been published dealing with the FIR laser lines and the infrared spectroscopy of CH3OH. In 1984 we could list about 330 FIR laser lines, 98 of which were measured in frequency and 105 assigned. Since then more than 70 papers were published increasing the number of the known laser lines to 575 (103 measured in frequency). Also the FIR and IR spectroscopy was largely improved thanks to the analysis of high resolution FT spectra, and the number of the correctly assigned laser lines has been increased to 224. The wavenumbers of the assigned lines can now be predicted with an accuracy of about 0.001 cm-1 or better, thus approaching the accuracy of the experimental frequency measurements.

A REVIEW OF OPTICALLY PUMPED FAR-INFRARED LASER LINES FROM METHANOL ISOTOPES

The technique of optical pumping in polar molecules is the most efficient for Far-Infrared (FIR) laser generation, providing also a versatile and powerful tool for molecular spectroscopy in this spectral region. Methanol (CH3OH) and its isotopic varieties are the best media for optically pumped FIR laser, with over thousand lines observed, and the most widely used for investigations and applications. In this sense, it is important organize and make available catalogues of FIR laser lines as complete as possible. Since the last critical reviews of 1984 [1] on methanol and its isotopic varieties [2,3,4], over hundred papers have been published dealing with hundreds of new FIR laser lines. In 1992 a review of FIR laser lines from CH3OH was presented [5]. In this communication we extend this work to the other methanol isotopes, namely CH3OD, CD3OH, CD3OD, (CH3OH)-C-13, (CD3OH)-C-13, (CD3OD)-C-13, (CH3OH)-O-18, CH2DOH, CHD2OH and CH2DOD.

ELECTRIC-FIELD EFFECTS ON ROTO-VIBRATIONAL TRANSITIONS OF (CD3OH)-C-13

We used a Stark-Optoacoustic cell and hybrid waveguide resonators to perform an Infrared and Far Infrared Stark Spectroscopy study on some transitions of (CD3OH)-C-13. Different behaviours of the transitions in the presence of a d.c. electric field were observed. The Stark splittings of six FIR laser lines ranging from 34 to 136 MHz/kVcm(-1) were determined. The analysis of the behaviour of the IR and FIR transitions in the presence of the external electric fields gives important and exclusive information on the levels involved in the transitions.

Optically pumped submillimeter laser lines from CD2Cl2 using a large tunability CW CO2 laser

Twenty-five new laser lines have been obtained is the wavelength region from 155 to 830 mu m by optically pumping the CD2Cl2 (deuterated dichloromethane) molecule with a CW CO3 laser having a tunability range of 300 MHz. The wavelength, polarization relative to that of CO2 pumping radiation, and offset relative to the CO2 center frequency were determined for all of the new lines and some other already known laser emissions. For all of them we give also the relative intensity and the optimum pressure of operation.

DIODE-LASER AND FOURIER-TRANSFORM SPECTROSCOPY OF THE (CH3OH)-C-13 C-O STRETCHING MODE

In this work we present high resolution Doppler limited absorption spectra measurements of the C-O stretching mode of (CH3OH)-C-13, obtained from diode laser spectroscopy, and the Fourier Transform spectrum obtained at 0. 12 cm-1 resolution. By using these data and previously known spectroscopic information, we determined the frequency and the J quantum number for the multiplets of the P and R(J) branches of the C-O stretching fundamental band. Infrared transitions in coincidence with emission lines of the regular CO2 laser and some of its isotope parents are pointed out.

NEW FIR LASER LINES AND FREQUENCY MEASUREMENTS FROM OPTICALLY PUMPED CD-13(3)OH-3

We report the discovery of 57 new fir laser lines from (CD3OH)-C-13 molecule optically pumped by a waveguide CO2 laser of 300 MHz tunability. For all lines, precise frequency offset measurements between the CO2 line center and the center of the absorbing (CD3OH)-C-13 line were performed using the transferred Lamb-Dip technique. We have also measured directly the frequency of seven FIR laser lines by heterodyning with already known laser lines.We present a complete list of all known laser lines (134) and frequency measurements (24) for this molecule.

Investigation for long wavelength FIR laser lines for EPR studies: New lines from CH2=CF2

The results described in this work are part of a systematic search for long wavelength laser lines to be used in high magnetic field EPR applications and in plasma diagnostic. Four new far-infrared laser lines of CH2 = CF2 (1,1 difluoroethylene), optically pumped by a waveguide CO2 laser, have been discovered and characterized in wavelength, polarization relative to the pumping radiation and offset relative to the CO2 center frequency. New measurements of polarization and offset of 5 already known laser lines are also reported. A table of all of the known CO2 pumped FIR laser lines from this molecule is given.

Vibrational and rotational spectroscopy of (CD3OD)-C-13

We have used Fourier Transform spectral data on the C-O stretching mode of (CD3OD)-C-13 in order to perform a vibro-rotational analysis for this molecule. We have estimated a few molecular parameters of the ground and C-O stretching vibrational modes. Based on these parameters, and by using the Kwan-Dennison model, we propose assignments for a number of far-infrared laser transitions of (CD3OD)-C-13.

Desarrollo de Técnicas Interferométricas para Radares de Alta Resolución en Milimétricas

En esta tesis doctoral se aborda el desarrollo de técnicas interferométricas para radares de alta resolución en milimétricas. Específicamente, se centra en el desarrollo de técnicas para radares terrestres y en concreto aquellas relacionadas con el seguimiento, clasificación y generación de imágenes de blancos móviles. Aparte del desarrollo teórico y simulación de las diferentes técnicas, uno de los grandes retos de esta tesis es la verificación experimental de las mismas. Para este propósito, se empleará un prototipo de sensor radar interferométrico de muy alta resolución y de ondas milimétricas. El primer capítulo de la tesis realiza una pequeña introducción a las técnicas interferométricas y presenta los objetivos, motivación y organización del presente trabajo. El segundo capítulo hace una pequeña introducción a los radares interferométricos de alta resolución en milimétricas y presenta el sensor radar experimental con el que se llevarán a cabo la validación de las distintas técnicas presentadas. El tercer capítulo recoge las distintas técnicas interferométricas desarrolladas para el seguimiento y cálculo de la altura de blancos móviles en radares de alta resolución. Entre ellas se encuentran: el seguimiento de blancos móviles en sucesión de imágenes ISAR, el cálculo de altura de blancos en imágenes radar bidimensionales distancia-tiempo y su equivalente en imágenes distancia-Doppler. El cuarto capítulo presenta una aplicación de las técnicas interferométricas para la vigilancia de tráfico en carreteras. Se describirán dos configuraciones radar que permiten calcular la velocidad de todos los blancos iluminados por el radar identificando de manera unívoca a los blancos en función del carril por el que circulen. El quinto capítulo presenta técnicas interferométricas aplicadas a la vigilancia en entornos marítimos basadas en la generación de imágenes interferométricas. Para demostrar la viabilidad del uso de estas imágenes se ha desarrollado un simulador de blancos móviles extensos realistas. Abstract This Ph. D thesis deals with the development of radar interferometry techniques for high-resolution millimeter wave sensors. It focuses on the development of techniques for ground-based radars and specifically those related to monitoring, classification and imaging of moving targets. Apart from the theoretical development and simulation, another major technical challenge of this thesis is the experimental verification of the different techniques. For that purpuse, a very high resolution interferometric millimeter wave radar sensor is used. The first chapter of the thesis makes a brief introduction to the interferometric techniques and shows the goals, motivation and organization of this work. The second chapter provides a brief introduction to high resolution interferometric radars in millimeter waves and presents the experimental radar sensor which will be used for the validation of the various techniques presented. The third chapter presents the different interferometric techniques developed for monitoring and obtaining the height of moving targets in high resolution radars. Among them are: tracking of moving targets in a succession of ISAR images, targets height calculation using bidimensional range-time radar images and the equivalente technique using range-Doppler images. The fourth chapter presents the application of interferometric techniques for road traffic monitoring. Two radar configurations are described. Both of them are able to obtain the speed for simultaneuslly illuminated targets, and univocally identify each target based on the detected road lane. The fifth chapter presents the application of interferometric techniques to maritime surveillance based on interferometric imaging. To demonstrate the feasibility of the presented techniques a realistic simulator of extended moving targets has been developed.