Synthesis and characterization of photo-crosslinkable main-chain liquid-crystalline polymers containing bis(benzylidene)cycloalkanone units

A series of new photo-crosslinkable main-chain liquid-crystalline polymers containing bis(benzylidene)cycloalkanone units have been studied. These units in the polymers function as mesogens as well as photoactive centres. Polyesters with three different bis(4-hydroxybenzylidene)cycloalkanones corresponding to three cycloalkanones, namely cyclopentanone, cyclohexanone and cycloheptanone, have been prepared. Three dicarboxylic acids with ether linkages, which were derived from oligoethylene oxides, namely triethylene glycol, tetraethylene glycol and pentaethylene glycol, have been used as spacers in these polymers. Polymerization was carried out by both solution and interfacial polycondensation; the latter method gave high-molecular-weight polymers. Structural characterizations were done by ultra-violet, infra-red and H-1 nuclear magnetic resonance spectroscopy. Liquid-crystalline properties were studied by differential scanning calorimetry and polarized-light optical microscopy. These polymers show a nematic mesophase. Liquid-crystalline transition temperatures were correlated with polymer structure. The decrease in transition temperature with increase in cycloalkanone ring size was explained in terms of the change in geometrical anisotropy of bis(benzylidene)cycloalkanone units. MNDO (modified neglect of differential overlap) calculations were performed on the model compounds, bis(4-acetyloxybenzylidene)cycloalkanone to elucidate the geometrical variation of the mesogenic units with cycloalkanone ring size. Studies of photolysis reveal the two kinds of photoreactions that proceed in these polymer systems, namely photoisomerization and photo-crosslinking. The former reaction disrupts the parallel stacking of the chromophores and is reflected as an increase in the ultra-violet spectral intensity. The favourability of these two reactions depends on the mobility of the polymer chains. When the photolysis was done below T-g, photo-crosslinking dominates over photoisomerization. Above T-g, photoisomerization is followed by photo-crosslinking. The photosensitivity of the polymers decreases with increase in size of the cycloalkanone ring.

Synthesis and Properties of a Novel (Main-Chain)– (Side-Chain) Polymeric Peroxide

A novel (main-chain)-(side-chain) vinyl polyperoxide, poly(dipentene peroxide)(PDP), an alternating copolymer of dipentene (DP) and oxygen, has been synthesized by thermal oxidative polymerization of DP. The PDP was characterized by 1H NMR, 13C NMR, FTIR, DSC, TGA, and EI-MS studies. The overall activation energies of the degradation from Kissinger’s method were 28 and 33 kcal/mol, respectively, for the endocyclic and acyclic peroxide units. The side-chain peroxy groups were found to be thermally more stable than the main chain. Above 45°C the rate of polymerization increases sharply at a particular instant showing an “autoacceleration” with the formation of knee point. The kinetics of autoacceleration has been studied at various temperatures (45–70°C) and pressures (50–250 psi). © 2000 John Wiley&Sons, Inc. J Appl Polym Sci 79: 1549–1555, 2001

Rapid determination of main constituents of packed juices by reverse phase-high performance liquid chromatography: an insight in to commercial fruit drinks

The present work reports the compositional analysis of thirteen different packed fruit juices using high performance liquid chromatography (HPLC). Vitamin C, organic acids (citric and malic) and sugars (fructose, glucose and sucrose) were separated, analyzed and quantified using different reverse phase methods. A new rapid reverse phase HPLC method was developed for routine analysis of vitamin C in fruit juices. The precision results of the methods showed that the relative standard deviations of the repeatability and reproducibility were < 0.05 and < 0.1 respectively. Correlation coefficient of the calibration models developed was found to be higher than 0.99 in each case. It has been found that the content of Vitamin C was less variable amongst different varieties involved in the study. It is also observed that in comparison to fresh juices, the packed juices contain lesser amounts of vitamin C. Citric acid was found as the major organic acids present in packed juices while maximum portion of sugars was of sucrose. Comparison of the amount of vitamin C, organic acids and sugars in same fruit juice of different commercial brands is also reported.

Structural variations in aromatic 2 pi-electron three-membered rings of the main group elements

Structural variations of different Z pi-aromatic three-membered ring systems of main group elements, especially group 14 and 13 elements as compared to the classical description of cyclopropenyl cation has been reviewed in this article. The structures of heavier analogues as well as group 13 analogues of cyclopropenyl cation showed an emergence of dramatic structural patterns which do not conform, to the general norms of carbon chemistry. Isolobal analogies between the main group fragments have been efficiently used to explain the peculiarities observed in these three-membered ring systems.

Continuum in the X-Z-Y Weak Bonds: Z= Main Group Elements

The Continuum in the variation of the X-Z bond length change from blue-shifting to red-shifting through zero-shifting in the X-Z---Y complex is inevitable. This has been analyzed by ab-initio molecular orbital calculations using Z= Hydrogen, Halogens, Chalcogens, and Pnicogens as prototypical examples. Our analysis revealed that, the competition between negative hyperconjugation within the donor (X-Z) molecule and Charge Transfer (CT) from the acceptor (Y) molecule is the primary reason for the X-Z bond length change. Here, we report that, the proper tuning of X-and Y-group for a particular Z-can change the blue-shifting nature of X-Z bond to zero-shifting and further to red-shifting. This observation led to the proposal of a continuum in the variation of the X-Z bond length during the formation of X-Z---Y complex. The varying number of orbitals and electrons available around the Z-atom differentiates various classes of weak interactions and leads to interactions dramatically different from the H-Bond. Our explanations based on the model of anti-bonding orbitals can be transferred from one class of weak interactions to another. We further take the idea of continuum to the nature of chemical bonding in general. (C) 2015 Wiley Periodicals, Inc.

Main Progress of Microgravity Sciences and Space Life Sciences Research in China

The progress of the research activities on space material sciences, microgravity ‰uid physics and combustion, space life sciences and biotechnology research, fundamental Physics in China are brie‰y summarized in the present paper. The major space missions and experimental results obtained on board the Chinese recoverable/non-recoverable satellites and the Chinese manned spaceship named ``Shen-Zhou'' are presented summarily. The recent main activities of the ground-based studies in China are introduced in brief.

La traducción como “instrumento poético” : Raúl Gustavo Aguirre, ente Rimbaud y Char

Resumen: La figura del poeta-traductor encuentra en Raúl Gustavo Aguirre visos de complejidad altamente productivos para la teoría de la traducción. Principal difusor de la obra de René Char en la Argentina, Aguirre traduce y publica, desde el lugar del seguidor y discípulo, la obra de Char en los años cincuenta; con Char comparte, además, la devoción por Arthur Rimbaud, que el autor de Fureur et mystère considera intocable, “fenómeno cuya única razón es ser” (Char 1955). La hipótesis del artículo es que Aguirre construye, en base a su tarea como traductor de Illuminations y de Une Saison en enfer, su propia legitimidad como poeta, al intervenir sobre ese supuesto núcleo intocable que es, para Char, la poesía de Rimbaud.

Plumas letradas en la Revista Latinidad (1939-1947) : el aporte de intelectuales locales en una publicación de la colectividad franco-argentina

Resumen: En el presente trabajo se analiza el aporte que un grupo de poetas, políticos e intelectuales argentinos en la revista Latinidad –creada por el impresor francés Mauricio Bouxin en 1920 y reeditada entre 1939 y 1947–, para dar cuenta de una posible apertura en la recepción de colaboraciones. Esto, en una variedad de sentidos: en cuanto a la nacionalidad y pertenencia de quienes escribían, su espectro ideológico y militancia, el posicionamiento en cuanto a la Segunda Guerra Mundial –tópico principal de la publicación– y, en cuanto a opiniones sobre política interna argentina. Plantearemos cómo la latinidad fue propuesta como un factor cohesionante, no sólo dentro de la propia comunidad francesa, sino en el contexto latinoamericano con el que pretendían estrechar lazos de identidad compartida, en el marco del conflicto bélico mundial.

Luces de cabotaje: la poesía de la transición y la generación de la democracia en los albores del nuevo milenio

[ES] La poesía del siglo XXI muestra un panorama complejo donde coinciden autores de distintos grupos, edades y sensibilidades. Este artículo propone un recorrido por los nombres más destacados y las tendencias más relevantes de la actualidad. Los principales autores del 50, del 68 y del 80 son los protagonistas de una poesía que ha reflejado las transformaciones políticas, ideológicas y literarias de la generación de la democracia

Main Progress of Microgravity Sciences and Space Life Sciences Research in China

Yves Bonnefoy and Translation into English: when poets, linguists and translators think alike

Santamaría, José Miguel; Pajares, Eterio; Olsen, Vickie; Merino, Raquel; Eguíluz, Federico (eds.)

KE Workshop Report - Main Drivers for Successful re-use of Research Data

On 23-24 September 2009 an international discussion workshop on “Main Drivers for Successful Re-Use of Research Data” was held in Berlin, prepared and organised by the Knowledge Exchange working group on Primary Research Data. The main focus of the workshop was on the benefits, challenges and obstacles of re-using data from a researcher’s perspective. The use cases presented by researchers from a variety of disciplines were supplemented by two key notes and selected presentations by specialists from infrastructure institutions, publishers, and funding bodies on national and European level. Researchers' perspectives The workshop provided a critical evaluation of what lessons have been learned on sharing and re-using research data from a researcher’s perspective and what actions might be taken on to still improve the successful re-use. Despite the individual differences characterising the diverse disciplines it became clear that important issues are comparable. Combine forces to support re-use and sharing of data Apart from several technical challenges such as metadata exchange standards and quality assurance it was obvious that the most important obstacles to re-using research data more efficiently are socially determined. It was agreed that in order to overcome this problem more efforts should be made to rise awareness and combine forces to support re-using and sharing of research data on all levels (researchers, institutions, publishers, funders, governments).

Odontocete Stranding Patterns in the Main Hawaiian Islands 1937–2002): how do they compare with live animal surveys?

In this study we (1) synthesized 65 yr of odontocete stranding data around the main Hawaiian Islands (1937–2002); (2) analyzed stranding patterns and trends over time; and (3) compared occurrence patterns based on sightings of live animals with stranding data and evaluated the compatibility of these data sets. From 1937 to 2002, 202 odontocete strandings were recorded by the National Marine Fisheries Service, Pacific Islands Regional Office. Strandings increased through time due to increased reporting effort and occurred throughout the year. The four most common of 16 species reported were Kogia spp. (18%), spinner dolphins (Stenella longirostris) (15%), striped dolphins (Stenella coeruleoalba) (11%), and sperm whales (Physeter macrocephalus) (10%). The highest proportion of strandings was recorded on O‘ahu (48%), followed by Maui/La¯na‘i (24%), Kaua‘i (12%), Hawai‘i (11%), and Moloka‘i (5%). Comparison with four previously published live animal survey studies suggests that stranding records are a good indicator of species composition and yield reasonable data on the frequency of occurrence of species in the region they cover.

Flood risk management: What are the main drivers of prevention?

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Far-field spot compression without energy loss in main lob in wireless laser communication

Far-field spot compression without energy loss in main lob is of great significance to wireless laser communication. In this letter, we propose two schemes to obtain far-field spot compression without energy loss in main lob. One scheme is based on the simulated annealing (SA) algorithm. Using SA algorithm, we design the phase profile of the diffractive phase element (DPE). Using the designed DPE, far-field spot compression without energy loss in main lob is achieved. The other scheme is based on YG algorithm. By means of YG algorithm, we appropriately designed the DPE in the emitting plane. Using the DPE, far-field spot compression without energy loss in main lob is obtained. (c) 2007 Elsevier GmbH. All rights reserved.