Quantifying rock fabrics: a test of autocorrelation of the spatial distribution of cristals

A novel test of spatial independence of the distribution of crystals or phases in rocks based on compositional statistics is introduced. It improves and generalizes the common joins-count statistics known from map analysis in geographic information systems. Assigning phases independently to objects in RD is modelled by a single-trial multinomial random function Z(x), where the probabilities of phases add to one and are explicitly modelled as compositions in the K-part simplex SK. Thus, apparent inconsistencies of the tests based on the conventional joins{count statistics and their possibly contradictory interpretations are avoided. In practical applications we assume that the probabilities of phases do not depend on the location but are identical everywhere in the domain of de nition. Thus, the model involves the sum of r independent identical multinomial distributed 1-trial random variables which is an r-trial multinomial distributed random variable. The probabilities of the distribution of the r counts can be considered as a composition in the Q-part simplex SQ. They span the so called Hardy-Weinberg manifold H that is proved to be a K-1-affine subspace of SQ. This is a generalisation of the well-known Hardy-Weinberg law of genetics. If the assignment of phases accounts for some kind of spatial dependence, then the r-trial probabilities do not remain on H. This suggests the use of the Aitchison distance between observed probabilities to H to test dependence. Moreover, when there is a spatial uctuation of the multinomial probabilities, the observed r-trial probabilities move on H. This shift can be used as to check for these uctuations. A practical procedure and an algorithm to perform the test have been developed. Some cases applied to simulated and real data are presented. Key words: Spatial distribution of crystals in rocks, spatial distribution of phases, joins-count statistics, multinomial distribution, Hardy-Weinberg law, Hardy-Weinberg manifold, Aitchison geometry

Fabrics of pre- and syntectonic granite plutons and chronology of shear zones in the Eastern Borborema Province, NE Brazil

We used the fabrics of two granite plutons and U/Pb (SHRIMP) zircon ages to constrain the tectonic evolution of the E-trending Patos shear zone (Borborema Province, NE Brazil). The pre-tectonic Teixeira batholith consists of an amphibole leucogranite locally with aegirine-augite. Zircons from a syenogranite yielded crystallization ages of 591 +/- 5 Ma. The batholith fabrics were determined by anisotropy of magnetic susceptibility (AMS) and mineral shape preferred orientation. The fabrics support pre-transcurrent batholith emplacement, as evidenced by: (i) magmatic/magnetic fabrics in low susceptibility (<0.35 mSI) leucogranites highly discordant to the regional host rock structure, and (ii) concordant magnetic fabrics restricted to high susceptibility (>1 mSI) corridors connected to shear zones branching off from Patos. One of these satellite shear zones controlled the syntectonic emplacement of the Serra Redonda pluton, which yields a crystallization age of 576 +/- 3 Ma. This late shearing event marks the peak regional deformation that, south of Patos, was coupled to crustal shortening nearly perpendicular to the shear belt. The chronology of the deformational events indicates that the major shear zones of the eastern Borborema are late structures active after the crustal blocks amalgamated. (C) 2007 Elsevier Ltd. All rights reserved.

Effect of synthesis parameters on the electrical conductivity of polypyrrole-coated poly(ethylene terephthalate) fabrics

The effects of pyrrole, anthraquinone-2-sulphonic acid (AQSA) and iron(III) chloride (FeCl3) concentrations, reaction time and temperature on the electrical conductivity of polypyrrole (PPy) - coated poly(ethylene terephthalate) (PET) fabrics were investigated. With an increase in both the AQSA and FeCl3 concentrations, resistivity decreased to a point beyond which higher concentrations led to increased surface resistivity. Erosion of the polymer coating, in dynamic synthesis from continual abrasion, manifested as an exponential increase in the resistance of the coated textile substrate. This was not encountered in static synthesis conditions. Temperature affected the degree of surface and bulk polymerisation. The effect of polymerisation temperature on conductivity was negligible. Conductive polymer coating on textiles through chemical polymerisation enabled a smooth coherent film to encase individual fibres, which did not affect the tactile properties of the host substrate. The optimum FeCl3/pyrrole and AQSA FeCl3/pyrrole molar ratios were found to be 2.22 and 0.40 respectively.

Characterization of conducting polymer coated synthetic fabrics for heat generation

Heat generation in fabrics coated with the conductive polymer polypyrrole was investigated. The PET fabrics were coated by chemical synthesis using four different oxidizing agent–dopant combinations. The samples from the four different dopant systems all show an increase in temperature when a fixed voltage is applied to the fabric. The antraquinone-2-sulfonic acid (AQSA) sodium salt doped polypyrrole coating was the most effective in heat generation whereas the sodium perchlorate dopant system was the least effective. The power density per unit area achieved in polypyrrole coated polyester–Lycra® fabric with 0.027 mol/l of AQSA acting as dopant was 430 W/m². The power density per unit area achieved for the sodium perchlorate system, using the same synthesis conditions, was 55 W/m².

Characterization and application of objective pilling classification to patterned fabrics

Previously, the authors proposed a new, simple method of frequency domain analysis based on the two-dimensional discrete wavelet transform to objectively measure the pilling intensity in sample fabric images. The method was further characterized, and the results obtained indicate that standard deviation and variance are the most appropriate measures of the dispersion of wavelet details coefficients for analysis, that the relationship between wavelet analysis scale and fabric inter-yarn pitch was empirically confirmed, and, that fabrics with random patterns do not appear to impact on the effectiveness of the analysis method.

Soluble poly-3-alkylpyrrole polymers on films and fabrics

Conductive textiles with specific properties can be produced by the chemical polymerisation of a range of 3-alkylpyrroles in the presence of textiles. The morphologies of these coatings are altered from the traditional conductive coatings. Comparison using a SEM reveals substantial differences.

Generating heat from conducting polypyrrole-coated PET fabrics

Heating effects in polypyrrole-coated polyethyleneterephthalate (PET)-Lycra® fabrics were studied. Chemical synthesis was employed to coat the PET fabrics by polypyrrole using ferric chloride as oxidant and antraquinone- 2-sulfonic acid (AQSA) and naphthalene sulfonic acid (NSA) as dopants. The coated fabrics exhibited reasonable electrical stability, possessed high electrical conductivity, and were effective in heat generation. Surface resistance of polypyrrole-coated fabrics ranged from approximately 150 to 500 /square. Different connections between conductive fabrics and the power source were examined. When subjected to a constant voltage of 24 V, the current transmitted through the fabric decreased about 10% in 72 h. An increase in resistance of conductive fabrics subjected to constant voltage was observed

Measuring the influence of fibre-to-fabric properties on the pilling of wool fabrics

This study ranks the contribution of various fibre, yarn and fabric attributes to the pilling of wool knitwear. On the basis of an artificial neural network modelling, a combination of sensitivity analysis, forwards/backwards search and genetic algorithms was used to identify the importance of various fibre/yarn/fabric input parameters. The three different techniques show broad similarities in their assessment of which input parameters are important or are not important in affecting fabric pilling. The ranking shows that fabric cover factor has the most effect on pilling, followed by yarn count and thin places, fibre length, yarn twist, etc. It is further illustrated that the directional trend of the predicted pilling outputs for a selection of inputs was in line with the expected behaviour. To verify the findings of input feature selection, input factors deemed to have a small effect on the predicted pilling output, such as fibre length and diameter variations and curvature, were removed and the subsequent performance statistically compared to the original multi-layer perceptron. Differences between the outputs predicted by the original and pruned models are found not to be statistically significant at the 5% significance level. Results from this study may help manufacturers and knitwear designers in choosing the most appropriate materials and structures to reduce the pilling propensity of wool knitwear.

Conductive fabrics for heating applications

By coating textiles with electrically conductive organic polymers, we are able to produce functional, intelligent fabrics. These fabrics can be utilised in applications such as gas sensors, actuators, electromagnetic shielding, radar absorption, selected frequency filtering in indoor wireless applications, and heating applications where vital parts of the body can be heated without embedding any wiring through the fabric.

Heat generation in fabrics coated with the conductive polymer polypyrrole was investigated. The fabrics were coated by chemical synthesis methods by oxidizing the pyrrole monomer in the presence of the fabric substrate. Ferric chloride was selected as the oxidizing agent and anthraquinone-2-sulfonic acid (AQSA) sodium salt monohydrate as the dopant.

Conductive fabrics were characterized by resistivity measurements, scanning electron microscopy, thermal imaging, current transmission over a period of time and calculations of power density per unit area. Effects of reaction conditions on the electrical properties and heat generated are presented. Polypyrrole coated fabrics were stable and possessed high electrical conductivity. Resistivity values ranged from 100-500 ohms/square depending on the reaction parameters. When subjected to a constant voltage of 24V, the polypyrrole coated polyester-Lycra® fabric doped with AQSA reached a maximum temperature of 42°C and a power density per unit area of 430 W/m² was achieved.

Objective assessment of pilling of nonwoven fabrics using the two dimensional discrete wavelet transform

Fabric pilling is a serious problem for the apparel industry, causing an unsightly appearance and premature wear. Woolen products are particularly prone to pilling. Recently, a process for production of woolen nonwoven apparel fabrics has been commercialized in Australia, and may lead to new markets for Australian wool. However, the success of such nonwoven fabrics will partly rely on their propensity to pill. A key element in the control of fabric pilling is the evaluation of resistance to pilling by testing. Resistance to pilling is normally tested in the laboratory by processes that simulate accelerated wear, followed by a manual assessment of the degree of pilling by an expert based on a visual comparison of the sample to a set of test images. To bring more objectivity into the pilling rating process, a number of automated systems based on image analysis have been developed. The authors previously proposed a new method of image analysis based on the two-dimensional discrete wavelet transform to objectively measure the pilling intensity for woven fabrics. This paper presents preliminary work in extending this method to nonwoven fabrics.

Improvement of adhesion of conductive polypyrrole coating on wool and polyester fabrics using atmospheric plasma treatment

In this paper wool and polyester fabrics were pretreated with atmospheric plasma glow discharge (APGD) to improve the ability of the substrate to bond with anthraquinone-2-sulfonic acid doped conducting polypyrrole coating. A range of APGD gas mixtures and treatment times were investigated. APGD treated fabrics were tested for surface contact angle, wettability and surface energy change. Effect of the plasma treatment on the binding strength was analyzed by studying abrasion resistance, surface resistivity and reflectance. Investigations showed that treated fabrics exhibited better hydrophilicity and increased surface energy. Surface treatment by an APGD gas mixture of 95% helium/5% nitrogen yielded the best results with respect to coating uniformity, abrasion resistance and conductivity.

A controlled experiment on yarn hairiness and fabric pilling

This study focused on the hairiness of worsted wool yarns and how it affects the pilling propensity of knitted wool fabrics. Conventional worsted ring spun yarns were compared with comparable SolospunTM yarns and yarns modified with a hairiness reducing air nozzle in the winding process (JetWind). Measurements of yarn hairiness (S3) on the Zweigle G565 hairiness meter showed a reduction in the S3 value of approximately 46% was achieved using SolospunTM ring spinning attachment and a 33% reduction was achieved using the JetWind process. Interestingly, subsequent evaluation of the pilling performance of fabrics made from the SolospunTM spun yarn and JetWind modified yarn showed a half grade and full grade improvement, respectively over a similar fabric made from conventional ring spun yarns. This result suggested that a relatively large reduction in yarn hairiness was needed to achieve a moderate improvement in fabric pilling, and that the nature of yarn hairiness was also a key factor in influencing fabric pilling propensity. It is postulated that the wrapping of surface hairs by the air vortex in the JetWind process may limit the ability of those surface fibers to form fuzz and reach the critical height required for pill formation.

Objective grading of fabric pilling with wavelet texture analysis

A new objective fabric pilling grading method based on wavelet texture analysis was developed. The new method created a complex texture feature vector based on the wavelet detail coefficients from all decomposition levels and horizontal, vertical and diagonal orientations, permitting a much richer and more complete representation of pilling texture in the image to be used as a basis for classification. Standard multi-factor classification techniques of principal components analysis and discriminant analysis were then used to classify the pilling samples into five pilling degrees. The preliminary investigation of the method was performed using standard pilling image sets of knitted, woven and non-woven fabrics. The results showed that this method could successfully evaluate the pilling intensity of knitted, woven and non-woven fabrics by selecting the suitable wavelet and associated analysis scale.

Photochromic wool fabrics from a hybrid silica coating

In this work, a photochromic wool fabric has been prepared by applying a photochromic-dye hybrid silica sol-gel onto the surface of fabric. The photochromic fabric was found to have a very quick optical response. Two types of silica were used as the matrix material, and the type of silica had a small effect only on the photochromic performance, the fabric washing fastness, and water contact angle, but affected the fabric handle property considerably. The silica from a precursor containing a long alkyl chain showed very little influence on the fabric handle and better photochromic performance than that containing a phenyl group.