The electrochemical cleavage of the nitrobenzoyl group from butyl nitrobenzoates in N,N-dimethylformamide

The applicability of the nitrobenzoyl group [NO2C6H4CO-] to protecting the functional hydroxyl group was investigated through study of the electrochemical behaviour of the butyl 4-, 3- and 2-nitrobenzoate compounds. These isomers are reduced in two cathodic steps. The first, at potentials of ca. -0.9 V vs. SCE, is attributed to the formation of rather stable anion radicals, involving one-electron transfer. The second, at potentials of ca. -1.7 V vs. SCE, occurs with a two-electron transfer in an ECE process, in which the dianion produced undergoes scission of the C-O bond giving n-butanoate ions with high yields (similar to 80%)

An HPLC-PAD method to analyse flavonoid glycosides and styrylpyrones from Cryptocarya species (Lauraceae)

An HPLC-PAD method has been developed in order to evaluate simultaneously the main secondary metabolites, flavonoid glycosides and styrylpyrones, of leaves of Cryptocarya moschata. The sample preparation, consisting of extraction, liquid-liquid extraction and centrifugation, requires minimum sample manipulation but produces high yields with reproducibility, selectivity and simplicity. HPLC on a C, column presents each class of metabolites grouped and with good resolution of the main compounds. The experimental conditions can be used to study inter- and intra-specific variability of secondary metabolites in Cryptocarya spp. Copyright (c) 2005 John Wiley A Sons, Ltd.

Desenvolvimento e produtividade do algodoeiro em função de espaçamentos e aplicação de regulador de crescimento

Currently, the cultivation of the cotton plant is based on a scale production model, characterized by high yields and intensive use of fertilizers, agrochemicals and mechanization. The objective of this study was to evaluate the influence of different row spacings on cotton crops, with or without growth regulator, and their effects in crop development and yield. The experimental design was in completely randomized blocks, in a 3x3 factorial scheme with 4 replications, using three row spacings: 0.45, 0.70 and 0.90 m. Three growth regulator conditions were tested: a) application split into four stages, b) single application at 70 d.a.e, and c) no regulator application. The project was conducted in the city of Selviria, Mato Grosso do Sul state, in November 2005. It was verified that the application of growth regulator is efficient in the limitation of plant height. The highest yield and boll mass was found in the split application of the regulator. The number of bolls and reproductive branches per plant was higher in the wider row spacings.

Optimal laser control of molecular photoassociation along with vibrational stabilization

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Improving the field production environment for soybeans

During the past 10 years, soybeans have reached a prominent position among crops in the world. A substantial contribution to world production has been achieved by tropical countries, due to favorable conditions for high yields. Two limitations keep commercial yields below those obtained in experimental results (above 3,000 kg/ha): one is the lack of local adapted varieties and the other is an adequate field production environment. Solutions must be obtained by local research data. Seedbed preparation is one of the most important production steps, since the other production practices are dependent on it. Conventional methods and minimum tillage, when soybeans follow another crop, are being used, with the problem of soil compaction and losses by erosion. Looking for superior strains of Rhizobium is crucial because nitrogen can be supplied by a proper symbiosis. The addition of limestone to the soil is a common practice used to raise the pH to proper levels. The use of fertilizers should be guided by local research findings. Chemical control of weeds, pests and diseases is needed to prevent yield losses, but possible effects on the environment should be considered. © 1981 American Oil Chemists' Society.

Effect of lecithin and soy oil on the fermentative performance of Saccharomyces uvarum I Z 1904

The proposal of this work was to study the effects of lecithin and soy oil on the fermentative performance of Saccharomyces uvarum I Z 1904, a yeast used in the industrial production of ethanol. High Test Molasses (HTM) was chosen as the fermentation media because it is a substratum that is poor in nutrients, and because it permits one to distinguish the action of lipids from other nutritional factors. The study of the optimization of the concentration of lipids by surface response analysis showed that the lipids favor the performance of the yeast principally when applied separately. Maximum concentrations of the two sources of lipids in the media stimulated the budding rate but did not constitute a protection against cell death. Considering the action of lipids on the cellular parameters studied, the supplementation of the media with 3.0 g/l of soy oil permitted the obtention of maximum responses of cellular viability, budding rate and viability of the buds after 6 successive cycles. In relation to the fermentative parameters, the use of 1.5 g/l of soy oil provided high yields and an equilibrium between the mass of ethanol produced (EM) and the alcoholic yield (Y p/s) , whereas the cellular viability after 6 cycles did not differ statistically from that observed with 3g/l of oil.

Mango flower induction in the brazilian northeast Semi-arid with gibberellin synthesis inhibitors

Mangoes in the Brazilian semi-arid stands out in the national scenario due to high yields and fruit quality, and also to the possibility of all-year production taking advantage of the climatic conditions as well as management technique (irrigation, pruning and growth regulators application) for plant growth and blossom control. Paclobutrazol soil drench applied is normally used for production management of mangoes. This research deals with the evaluation of the effect of foliar applied growth regulators to mango, cultivar 'Kent', as regard to their efficiency for blossom management, in order to allow off season mango production. Three growth regulators (prohexadione-Ca, trinexapac-ethyl and chlormequat chloride) were foliar applied, at two dosages and compared to paclobutrazol applied as soil-drench. In order to compare the effects of the treatment, data were recorded related to panicle emission (percentage and length), period of time until blossom and production, yield (number and plant weight) and post-harvest quality of the fruit (total soluble solids, titratable acidity, pH, firmness, flesh and skin color and appearance). The results showed that prohexadione-Ca and chlormequat chloride induced a 15-day early harvest, while paclobutrazol, alone or combined with prohexadione-Ca, allow to harvest 25 days in advance, when compared to trinexapac-ethyl and control trees. Growth regulators foliar applied and paclobutrazol applied as soil-drench delayed mangoes fruit ripening in post-harvest.

Bond markets for Latin American debt in the 1990s

Includes bibliography

Upland rice growth and mineral nutrition as affected by cultivars and sulfur availability

A better understanding of the differential growth of upland rice (Oryza sativa L.) cultivars with increasing soil S availability could help improve rice yield under upland conditions. The objective of this study was to evaluate root and shoot growth and nutrition of upland traditional and modern rice cultivars as affected by S availability. The experimental design was completely randomized in a 3 (rates of S) × 3 (cultivars) factorial with four replications. Low availability of S in the soil reduces root and shoot development and the efficiency of N, P, and S uptake, as well as the concentration and content of these nutrients in rice cultivars. At 0 mg dm-3 of S, rice cultivars prioritize root growth over shoots, and the traditional cultivar does so with greater intensity. Our results suggested that more development of traditional cultivars under low S availability facilitates its adaptation in soils under this condition. On the other hand, the intermediate and modern cultivars are more responsive to S fertilization. Moreover, S fertilization allows significant increases in upland rice growth and must be considered in cropping systems aiming for high yields. © Soil Science Society of America.

Caracterização edafoclimática e proposta para a determinação do risco de redução de safra na região do Pontal do Paranapanema - SP

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Desenvolvimento de cinco linhagens de Agaricus Bisporus Lange (Imbach) (“champignon de Paris”) em diferentes formulações de composto e meios de cultura

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Desenvolvimento de metodologia para extração de substâncias húmicas de turfas utilizando se hidróxido de potássio

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Influência do substrato no cultivo e na composição química do cogumelo Pleurotus florida

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Desenvolvimento e produção do algodoeiro em função de espaçamentos e aplicação de regulador de crescimento

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estabilidade e adaptabilidade de cultivares de soja, incluindo transgênicas, na região dos chapadões

Pós-graduação em Agronomia - FEIS