Influencia de las economías de escala en la metalurgia del aluminio y en la industria de transformaciones del metal y sus aleaciones

Incluye Bibliografía

Estudo sobre o uso de compostos de nióbio em reações multicomponentes de aza-Diels-Alder

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Preparação e caracterização estrutural de complexos quirais de nióbio, utilizando álcoois terpênicos quirais como ligantes

Pós-graduação em Ciência e Tecnologia de Materiais - FC

Estudo sobre o uso do pentacloreto de nióbio em reações multicomponentes para síntese de derivados de 4-ARIL-3,4-DI-Hidrocumarinas

Pós-graduação em Ciência e Tecnologia de Materiais - FC

Desenvolvimento de cerâmicas texturizadas de titanato de bismuto puro e dopado com nióbio

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Desenvolvimento de cerâmicas multicamadas de carbeto de silício destinadas a aplicações térmicas

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Fotocatalisadores a base de dióxido de titânio modificados com nióbio para redução de gás carbônico a metanol

Pós-graduação em Química - IQ

Preparação de substratos de carbeto de silício para fins aeroespaciais

This conclusion thesis has the objective of produce substrates of Silicon Carbide from the powder of SiC for aerospace use. The powder of SiC was pressed in cylindrical form by the process called “wet way”. For the inicial pressing process was used a uniaxial squeezer and after that was used a isostatic squeezer, after that the samples were synthesized. The next step was the machining and polishing to improve the features of the surface of the sample. Then the roughness was measured, as also the Arquimedes method and optical microscopy and scanning eletron microscopy. Some innovations were done, in one of the lots little vacancys were done with organic material or silicon to reduce the weight of the sample; and the other innovation were the use of a slip film of SiC on the surface of the sample, that were after synthesized with LASER to reduce the roughness, in this samples the roughness were reduce in 50 % if compared with the other samples

Lixamento do Pinus elliotti com carbeto de silício e óxido de aluminio

The Sanding is a complex process involving many variables that affect the quality of the part produced, working mainly in the timber industry in the production of panels (MDF, MDP, HDF, etc...) and furniture. However, these industries use the sanding process empirically, not optimizing it. The aim of this study was to compare the behavior of sandpaper white aluminum oxide (OA-white) and Black silicon carbide (SiC-black), analyzing variables in the process as: strength, power, emission, vibration, wear particle size of sanding, and its consequences on the surface finish of the workpiece. Made the process of plane grinding samples of Pinus elliottii, processed in parallel to the fibers, which were sanded with sandpaper grain OA white and black 3-SiC abrasive conditions (new, moderately eroded and severely eroded) grain sizes in 3 (80, 100, and 120 mesh). 6 replicates was performed for each condition tested. Each trial was captured output variables of the sanding process: strength, power, emission and vibration. With two stages totaling 108 trials. After the sanded samples, it has the same surface quality by raising the surface roughness Ra. Through experiment, it can be concluded that abrasives OA-white tended to have higher strength, power, emissions and less vibration in the sanding process, compared to the SiC-black. However, surface finish exhibited similar to the particle size of 80 to 100 mesh, worn abrasive conditions. However, the particle size of 120 mesh, obtained by the roughness of sandpaper OA-bank was higher compared to SiC-black to all conditions of sandpaper due to its toughness

Estudo sobre o uso do pentacloreto de nióbio, como ácido de Lewis, na síntese de enaminas através da reação de adição de Michael

The NbCl5 being a strong electrophile, is a potential candidate to act as a Lewis acid, and therefore it mediates various organic reactions. For this reason, it has received continuous attention by Brazilian researchers, especially in recent decades, since Brazil holds the largest reserves of niobium, besides being the largest producer of this element. The Michael addition reaction is one of the most widely used for forming carbon-carbon bonds and takes place by the addition of nucleophiles to activated olefins. Although this type of reaction is usually catalyzed by base, there are reports in the literature on the use of various Lewis acids in this type of reaction. The synthesis of enamines based acetilenodicarboxilates and amines, aromatic or alkyl, by Michael addition reaction is quite interesting, since these are valuable synthetic intermediates for the synthesis of heterocyclic and they are used in multicomponent reactions. The derivatives of anilino-fumarate also have a great potential for medical application. In this study we investigated the use of niobium pentachloride as Lewis acid to catalyze the Michael additions between the derivatives of aniline and acetilenodicarboxilates the synthesis of enamines

Desenvolvimento de recobrimento submicrométrico de óxido de nióbio para aplicação em tubulações de prospecção de petróleo

Pós-graduação em Engenharia Mecânica - FEG

Síntese de 14-aril-14h-dibenzol[a,j]xantenos e 4-aril-3,4-di-hidrobenzo[f]cumarinas promovida pelo pentacloreto de nióbio, com potencial aplicação na preparação de corantes sensibilizadores para utilização em dispositivos de Grätzel

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estudos sobre a aplicação do pentacloreto de nióbio na síntese de derivados de 4-aril-3,4-di- hidrocumarinas

Coumarin is a natural active compound that can be found in many plants. The coumarins have many properties such as bronchodilator, anti-inflammatory, antioxidant, anticoagulant, antibiotics, immunomodulatory, antimicrobial and antiviral, thus, they are widely used in medical applications. More recently the coumarin derivatives have attracted the interest of many research groups in the field of new materials, for example the possibility of their use as sensitizers in dye-sensitized solar cells (DSSC) and lasers. The MCRs are defined as a process in which three or more reactants are combined in the same reaction pot, resulting in products with good structural complexity a single step, in addition to economy of atoms and selectivity and is a very important feature in modern synthetic methodology. In this work we investigated the use of niobium pentachloride as catalyst of the multicomponent reactions between phenolic derivatives, various aromatic aldehydes and β-diester derivatives in the synthesis of 4-aryl-3,4-dihydrocoumarin derivatives. The reactions were carried out at room temperature, under inert atmosphere (N2), using dichloromethane anhydrous (CH2 Cl2) as solvent, with a reaction time of most 120 hours. The products were isolated by column chromatography on silica gel and submitted to spectrometric and spectroscopic analysis. The results show that NbCl5 is an excellent agent for promoting the synthesis of 4-aryl-3,4-dihydrocoumarin derivatives through multicomponent reactions, obtaining yields varying from 45 to 95%

Influência da adição do nióbio no comportamento mecânico e microestrutural do aço SAE 6150

Pós-graduação em Engenharia Mecânica - FEG

A influência do tamanho de grão ferrítico da peça na integridade superficial de peças erodidas

Pós-graduação em Engenharia Mecânica - FEIS