Transferência de calor transiente na agitação linear intermitente de latas

Foi estudada a transferência de calor transiente na agitação linear e intermitente (ALI) de embalagens metálicas contendo simulantes de alimentos, objetivando-se sua aplicação em processos de pasteurização ou esterilização e conseqüentes tratamentos térmicos mais eficientes, homogêneos e com produto de melhor qualidade. Foram utilizados quatro meios fluidos simulantes de alimentos de diferentes viscosidades e massas específicas: três óleos e água. Foram combinados efeitos de cinco tratamentos, sendo: meio simulante (4 níveis), espaço livre (3 níveis), freqüência de agitação (4 níveis), amplitude de agitação (2 níveis) e posição das latas (4 níveis). Os ensaios de aquecimento e resfriamento foram feitos em tanque com água à temperatura de 98 °C e 17-20 °C, respectivamente. Com os dados de penetração de calor em cada experimento, foram calculados os parâmetros de penetração de calor fh, jh, fc e jc. Os resultados foram modelados utilizando-se grupos de números adimensionais e expressos em termos de Nusselt, Prandtl, Reynolds e funções trigonométricas (com medidas de amplitude e freqüência de agitação, espaço livre e dimensões da embalagem). Foram estabelecidas as duas Equações gerais para as fases de aquecimento e resfriamento: Nu = ReA 0,199.Pr 0,288.sen(xa/AM)0,406.cos(xf/FA) 1,039.cos((xf/FA).(EL/H).p) 4,556 Aquecimento Nu = 0,1295.ReA 0,047.Pr 0,193.sen(xa/AM)0,114.cos(xf/FA) 0,641.cos((xf/FA).(EL/H).p) 2,476 Resfriamento O processo de ALI pode ser aplicado em pasteurizadores ou autoclaves estáticas horizontais e verticais, com modificações simples. Concluiu-se que a ALI aumenta significativamente a taxa de transferência de calor, tanto no aquecimento como no resfriamento.

Análise de desempenho de um fogão solar construído a partir de sucatas de antena de tv

Given the growing environmental crisis caused by degradation, mainly due to the use of polluting energy sources, increasing the growing use of renewable energies worldwide, with emphasis on solar energy, an abundant supply and available to everyone, which can be harnessed in several ways: electricity generation; dehydration of food; heating, disinfection and distillation and cooking. The latter has as its primary feature the viability of clean, renewable energy for society, combating ecological damage caused by large-scale use of firewood for cooking foods, use in tropical countries with high solar radiation, and has funding NGOs throughout the world with the goal of achieving low-income population. The proposed project consists of a solar cooker for concentration, working from the reflection of sunlight by a hub that they converge to a focal point at the bottom of the pot, getting lots of heat. The solar cooker under study consists of two elliptical reflecting parabolas made from the recycling of scrap TV antenna, having 0.29 m² of surface area for each antenna, which were covered by multiple mirrors of 2 mm thick and mounted on a metal structure, with correction for the mobility of the apparent movement of the sun. This structure was built with the recycling of scrap metal, possessing a relatively low cost compared with other solar cookers, around US$ 50.00. This cost becomes negligible, since that will involve a great benefit to not have fuel costs for each meal, unlike the use of gas or firewood for cooking food. The tests show that the cooker has reached the maximum temperature of 740 ° C, for boiling water in an average time of 28 minutes, cooking various types of foods such as potatoes, rice and pasta in an average time of 45 minutes and still going as a solar oven, making pizza baking and meat. These cooking times do not differ much from the cooking times on a gas stove, it becomes the solar cooker as a good consumer acceptance, and furthermore not to deliver the same gases that can poison the food as with the wood stove. Proves the viability of using the stove to cook or bake in two daily meals for a family, still presenting a position to improve his performance with the addition of new materials, equipment and techniques

Germinação de sementes de Stryphnodendron adstringens (Mart.) Coville de diferentes origens submetidas a tratamentos para superação de dormência

Sementes de diferentes procedências podem apresentar variações na intensidade de dormência, respondendo de forma diferenciada aos tratamentos e dificultando a indicação da melhor metodologia para superá-la. Este trabalho teve o objetivo de identificar métodos para superar a dormência e promover a germinação de sementes de barbatimão de diferentes procedências. Sementes dessa espécie foram colhidas em sete fragmentos de Cerrado localizados na região de Botucatu, SP, e submetidas aos seguintes tratamentos de superação de dormência: testemunha, escarificação mecânica (lixa 220), H2O quente por 20 min e escarificação com H2SO4 (95%) por 40, 60 e 80 min. As sementes foram avaliadas quanto ao teor de água, teste de germinação, comprimento de plântulas, índice de velocidade de germinação e condutividade elétrica. A escarificação em ácido sulfúrico por 60 min foi o tratamento mais eficiente para superar a dormência, acelerar e aumentar a porcentagem de germinação e resultar plântulas de maior tamanho, para as sementes de diferentes locais de origem.

Nutritional composition, phenolic compounds, nitrate content in eatable vegetables obtained by conventional and certified organic grown culture subject to thermal treatment

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Surface characterization of feldspathic ceramic using ATR FT-IR and ellipsometry after various silanization protocols

Objectives. This study characterized the feldspathic ceramic surfaces after various silanization protocols.Methods. Ceramic bars (2 mm x 4 mm x 10 mm) (N = 18) of feldpathic ceramic (VM7, VITA Zahnfabrik) were manufactured and finished. Before silane application, the specimens were ultrasonically cleaned in distilled water for 10 min. The ceramic specimens were randomly divided into nine groups (N = 2 per group) and were treated with different silane protocols. MPS silane (ESPE-Sil, 3M ESPE) was applied to all specimens and left to react at 20 degrees C for 2 min (G20). After drying, the specimens were subjected to heat treatment in an oven at 38 degrees C (G38), 79 degrees C (G79) or 100 degrees C (G100) for 1 min. Half of the specimens of each group were rinsed with water at 80 degrees C for 15 s (G20B, G38B, G79B, G100B). The control group (GC) received no silane. Attenuated total reflection infrared Fourier transform analysis (ATR FT-IR) was performed using a spectrometer. Thickness of silane layer was measured using a spectroscopic ellip-someter working in the lambda = 632.8 nm (He-Ne laser) at 70 degrees incidence angle. Surface roughness was evaluated using an optical profilometer. Specimens were further analyzed under the Scanning Electron Microscopy (SEM) to observe the topographic patterns.Results. ATR FT-IR analysis showed changes in Si-O peaks with enlarged bands around 940 cm(-1). Ellipsometry measurements showed that all post-heat treatment actions reduced the silane film thickness (30.8-33.5 nm) compared to G20 (40 nm). The groups submitted to rinsing in hot water (B groups) showed thinner silane films (9.8-14.4 nm) than those of their corresponding groups (without washing) (30.8-40 nm). Profilometer analysis showed that heat treatments (Ra approximate to 0.10-0.19 mu m; Rq approximate to 0.15-0.26 mu m) provided a smoother surface than the control group (Ra approximate to 0.48 mu m; Rq approximate to 0.65 mu m). Similar patterns were also observed in SEM images.Significance. Heat treatment after MPS silane application improved the silane layer network. Rinsing with boiling water eliminated the outmost unreacted regions of the silane yielding to thinner film thicknesses. (C) 2011 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Heat treatment and inactivation of trypsin-chymotrypsin inhibitors and lectins from beans (Phaseolus vulgaris L.)

This work investigates some factors affecting the inactivation of common bean trypsin inhibitor and phytohemagglutin. Trypsin inhibitor activity was totally stable to heat treatment (30 min, 97C) in the total protein extract, albumin or globulin fraction. Heat treatment of the whole beans easily inactivated the inhibitor. Heat resistance of trypsin inhibitor was intermediate in the bean flour which received the same heat treatment. Independent of sample, the inhibitor was very stable to heat treatment at neutral and acidic pH and labile under strong alkaline conditions. Heating for 30 min in boiling water at pH 12 resulted in complete inactivation of the trypsin inhibitor. Autoclaving (121C) soaked whole beans and flour for 5 min inactivated 55% of the trypsin inhibitor activity in the soaked flour and 75% in the whole beans. After autoclaving 20 min, inactivation of trypsin inhibitor was about 65% in the flour and 80% in the whole beans. The phytohemagglutinin (lectin) activity was totally destroyed in the autoclaved beans after 5 min and in the flour after 15 min.

Bond strength of hard chairside reline resins to a rapid polymerizing denture base resin before and after thermal cycling

Purpose: This study assessed the shear bond strength of 4 hard chairside reline resins (Kooliner, Tokuso Rebase Fast, Duraliner II, Ufi Gel Hard) to a rapid polymerizing denture base resin (QC-20) processed using 2 polymerization cycles (A or B), before and after thermal cycling. Materials and Methods: Cylinders (3.5 mm x 5.0 mm) of the reline resins were bonded to cylinders of QC-20 polymerized using cycle A (boiling water-20 minutes) or B (boiling water; remove heat-20 minutes; boiling water-20 minutes). For each reline resin/polymerization cycle combination, 10 specimens (groups CAt e CBt) were thermally cycled (5 and 55°C; dwell time 30 seconds; 2,000 cycles); the other 10 were tested without thermal cycling (groups CAwt ad CBwt). Shear bond tests (0.5 mm/min) were performed on the specimens and the failure mode was assessed. Data were analyzed by 3-way ANOVA and Newman-Keuls post-hoc test (α=.05). Results: QC-20 resin demonstrated the lowest bond strengths among the reline materials (P<.05) and mainly failed cohesively. Overall, the bond strength of the hard chairside reline resins were similar (10.09±1.40 to 15.17±1.73 MPa) and most of the failures were adhesive/cohesive (mixed mode). However, Ufi Gel Hard bonded to QC-20 polymerized using cycle A and not thermally cycled showed the highest bond strength (P<.001). When Tokuso Rebase Fast and Duraliner II were bonded to QC-20 resin polymerized using cycle A, the bond strength was increased (P=.043) after thermal cycling. Conclusions: QC-20 displayed the lowest bond strength values in all groups. In general, the bond strengths of the hard chairside reline resins were comparable and not affected by polymerization cycle of QC-20 resin and thermal cycling.

Effect of microwave disinfection on physical and mechanical properties of acrylic resins

This study evaluated the effect of microwave energy on the hardness, impact strength and flexural strength of the Clássico, Onda-Cryl and QC-20 acrylic resins. Aluminum die were embedded in metallic or plastic flasks with type III dental stone, in accordance with the traditional packing technique. A mixing powder/liquid ratio was used according to the manufacturer's instructions. After polymerization in water batch at 74°C for 9 h, boiling water for 20 min or microwave energy at 900 W for 10 min, the specimens were deflasked after flask cooling at room temperature, and submitted to finishing. Specimens non-disinfected and disinfected by microwave irradiation were submitted to hardness, impact and flexural strength tests. Each specimen was immersed in distilled water and disinfected in a microwave oven calibrated to 650 W for 3 min. Knoop hardness test was performed with 25 g load for 10 s, impact test was carried out using the Charpy system with 40 kpcm, and 3-point bending test with a crosshead speed of 0.5 mm/min until fracture. Data were submitted to statistical analysis by ANOVA and Tukey's test (α=0.05). Disinfection by microwave energy decreased the hardness of Clássico and Onda-Cryl acrylic resins, but no effect was observed on the impact and flexural strength of all tested resins.

Postharvest characteristics and treatments to overcome latex exuded from cut flowers of lotus

Lotus (Nelumbo nucifera Gaertn.) is a perennial herbaceous aquatic ornamental plant with potential to be used as a new cut flower for the Brazilian ornamental market. It shows exotic and attractive flowers and has a strong market appeal, once it is known as a symbol of purity, holiness and immortality. However, flowers have a short-vase life. Lotus flower stem exudes a large quantity of sticky milky sap from the cut surface, which is produced in laticifers, spatially associated with both xylem and phloem. It has been reported that latex coagulates on the cut surface preventing or reducing water absorption and reducing flowers' vaselife, requiring treatments to stop the flow of latex. The objective of this study was to report observations of lotus postharvest characteristics and evaluate treatments to overcome latex flow. The experiment was conducted as a complete randomized design with three replications of four stems in each vase and eight treatments; a control (distilled water), pretreatment of cut stem-ends with hot water (40° C/1 minute), boiling water (3 seconds), isopropyl alcohol 90% (10 minutes) or citric acid (pH = 2.8/1h) and, maintenance of stems in a holding solution of Tween® 20 (0.01%), citric acid (200 mg L-1) or Tween® 20 (0.01%) plus citric acid (200 mg L-1). Treatments had no significant effect on flowers vaselife which was only about three days, although isopropyl alcohol, hot and boiling water completely stopped latex flow. Cut stem-ends pretreated with citric acid (pH = 2.8/1 h) showed a significantly higher relative water content of petals compared to others treatments. The senescence symptom of lotus cut flowers was mainly characterized by abscission of turgid petals and dehiscence of stamens without any visual change of petal color and brightness.

Influência de diferentes resinas acrílicas e técnicas de polimerização na resistência de união e dureza shore A de materiais reembasadores macios

Pós-graduação em Reabilitação Oral - FOAR

Desenvolvimento de novos procedimentos analíticos para a determinação de paracetamol em amostras de medicamentos

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Qualidade fisiológica de sementes de Piptadenia moniliformis Benth

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Biologia e caracterização morfológica e morfometrica dos estágios imaturos e adulto de Calosoma granulatum Perty, 1830 (Coleoptera: Carabidae)

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Análisis Integrado de Seguridad de un accidente de SGTR en un reactor nuclear tipo PWR

El accidente de rotura de tubos de un generador de vapor (Steam Generator Tube Rupture, SGTR) en los reactores de agua a presión es uno de los transitorios más exigentes desde el punto de vista de operación. Los transitorios de SGTR son especiales, ya que podría dar lugar a emisiones radiológicas al exterior sin necesidad de daño en el núcleo previo o sin que falle la contención, ya que los SG pueden constituir una vía directa desde el reactor al medio ambiente en este transitorio. En los análisis de seguridad, el SGTR se analiza desde un punto determinista y probabilista, con distintos enfoques con respecto a las acciones del operador y las consecuencias analizadas. Cuando comenzaron los Análisis Deterministas de Seguridad (DSA), la forma de analizar el SGTR fue sin dar crédito a la acción del operador durante los primeros 30 min del transitorio, lo que suponía que el grupo de operación era capaz de detener la fuga por el tubo roto dentro de ese tiempo. Sin embargo, los diferentes casos reales de accidentes de SGTR sucedidos en los EE.UU. y alrededor del mundo demostraron que los operadores pueden emplear más de 30 minutos para detener la fuga en la vida real. Algunas metodologías fueron desarrolladas en los EEUU y en Europa para abordar esa cuestión. En el Análisis Probabilista de Seguridad (PSA), las acciones del operador se tienen en cuenta para diseñar los cabeceros en el árbol de sucesos. Los tiempos disponibles se utilizan para establecer los criterios de éxito para dichos cabeceros. Sin embargo, en una secuencia dinámica como el SGTR, las acciones de un operador son muy dependientes del tiempo disponible por las acciones humanas anteriores. Además, algunas de las secuencias de SGTR puede conducir a la liberación de actividad radiológica al exterior sin daño previo en el núcleo y que no se tienen en cuenta en el APS, ya que desde el punto de vista de la integridad de núcleo son de éxito. Para ello, para analizar todos estos factores, la forma adecuada de analizar este tipo de secuencias pueden ser a través de una metodología que contemple Árboles de Sucesos Dinámicos (Dynamic Event Trees, DET). En esta Tesis Doctoral se compara el impacto en la evolución temporal y la dosis al exterior de la hipótesis más relevantes encontradas en los Análisis Deterministas a nivel mundial. La comparación se realiza con un modelo PWR Westinghouse de tres lazos (CN Almaraz) con el código termohidráulico TRACE, con hipótesis de estimación óptima, pero con hipótesis deterministas como criterio de fallo único o pérdida de energía eléctrica exterior. Las dosis al exterior se calculan con RADTRAD, ya que es uno de los códigos utilizados normalmente para los cálculos de dosis del SGTR. El comportamiento del reactor y las dosis al exterior son muy diversas, según las diferentes hipótesis en cada metodología. Por otra parte, los resultados están bastante lejos de los límites de regulación, pese a los conservadurismos introducidos. En el siguiente paso de la Tesis Doctoral, se ha realizado un análisis de seguridad integrado del SGTR según la metodología ISA, desarrollada por el Consejo de Seguridad Nuclear español (CSN). Para ello, se ha realizado un análisis termo-hidráulico con un modelo de PWR Westinghouse de 3 lazos con el código MAAP. La metodología ISA permite la obtención del árbol de eventos dinámico del SGTR, teniendo en cuenta las incertidumbres en los tiempos de actuación del operador. Las simulaciones se realizaron con SCAIS (sistema de simulación de códigos para la evaluación de la seguridad integrada), que incluye un acoplamiento dinámico con MAAP. Las dosis al exterior se calcularon también con RADTRAD. En los resultados, se han tenido en cuenta, por primera vez en la literatura, las consecuencias de las secuencias en términos no sólo de daños en el núcleo sino de dosis al exterior. Esta tesis doctoral demuestra la necesidad de analizar todas las consecuencias que contribuyen al riesgo en un accidente como el SGTR. Para ello se ha hecho uso de una metodología integrada como ISA-CSN. Con este enfoque, la visión del DSA del SGTR (consecuencias radiológicas) se une con la visión del PSA del SGTR (consecuencias de daño al núcleo) para evaluar el riesgo total del accidente. Abstract Steam Generator Tube Rupture accidents in Pressurized Water Reactors are known to be one of the most demanding transients for the operating crew. SGTR are special transient as they could lead to radiological releases without core damage or containment failure, as they can constitute a direct path to the environment. The SGTR is analyzed from a Deterministic and Probabilistic point of view in the Safety Analysis, although the assumptions of the different approaches regarding the operator actions are quite different. In the beginning of Deterministic Safety Analysis, the way of analyzing the SGTR was not crediting the operator action for the first 30 min of the transient, assuming that the operating crew was able to stop the primary to secondary leakage within that time. However, the different real SGTR accident cases happened in the USA and over the world demonstrated that operators can took more than 30 min to stop the leakage in actual sequences. Some methodologies were raised in the USA and in Europe to cover that issue. In the Probabilistic Safety Analysis, the operator actions are taken into account to set the headers in the event tree. The available times are used to establish the success criteria for the headers. However, in such a dynamic sequence as SGTR, the operator actions are very dependent on the time available left by the other human actions. Moreover, some of the SGTR sequences can lead to offsite doses without previous core damage and they are not taken into account in PSA as from the point of view of core integrity are successful. Therefore, to analyze all this factors, the appropriate way of analyzing that kind of sequences could be through a Dynamic Event Tree methodology. This Thesis compares the impact on transient evolution and the offsite dose of the most relevant hypothesis of the different SGTR analysis included in the Deterministic Safety Analysis. The comparison is done with a PWR Westinghouse three loop model in TRACE code (Almaraz NPP), with best estimate assumptions but including deterministic hypothesis such as single failure criteria or loss of offsite power. The offsite doses are calculated with RADTRAD code, as it is one of the codes normally used for SGTR offsite dose calculations. The behaviour of the reactor and the offsite doses are quite diverse depending on the different assumptions made in each methodology. On the other hand, although the high conservatism, such as the single failure criteria, the results are quite far from the regulatory limits. In the next stage of the Thesis, the Integrated Safety Assessment (ISA) methodology, developed by the Spanish Nuclear Safety Council (CSN), has been applied to a thermohydraulical analysis of a Westinghouse 3-loop PWR plant with the MAAP code. The ISA methodology allows obtaining the SGTR Dynamic Event Tree taking into account the uncertainties on the operator actuation times. Simulations are performed with SCAIS (Simulation Code system for Integrated Safety Assessment), which includes a dynamic coupling with MAAP thermal hydraulic code. The offsite doses are calculated also with RADTRAD. The results shows the consequences of the sequences in terms not only of core damage but of offsite doses. This Thesis shows the need of analyzing all the consequences in an accident such as SGTR. For that, an it has been used an integral methodology like ISA-CSN. With this approach, the DSA vision of the SGTR (radiological consequences) is joined with the PSA vision of the SGTR (core damage consequences) to measure the total risk of the accident.

Neighborhood-corrected interface discontinuity factors for multi-group pin-by-pin diffusion calculations for LWR

Performing three-dimensional pin-by-pin full core calculations based on an improved solution of the multi-group diffusion equation is an affordable option nowadays to compute accurate local safety parameters for light water reactors. Since a transport approximation is solved, appropriate correction factors, such as interface discontinuity factors, are required to nearly reproduce the fully heterogeneous transport solution. Calculating exact pin-by-pin discontinuity factors requires the knowledge of the heterogeneous neutron flux distribution, which depends on the boundary conditions of the pin-cell as well as the local variables along the nuclear reactor operation. As a consequence, it is impractical to compute them for each possible configuration; however, inaccurate correction factors are one major source of error in core analysis when using multi-group diffusion theory. An alternative to generate accurate pin-by-pin interface discontinuity factors is to build a functional-fitting that allows incorporating the environment dependence in the computed values. This paper suggests a methodology to consider the neighborhood effect based on the Analytic Coarse-Mesh Finite Difference method for the multi-group diffusion equation. It has been applied to both definitions of interface discontinuity factors, the one based on the Generalized Equivalence Theory and the one based on Black-Box Homogenization, and for different few energy groups structures. Conclusions are drawn over the optimal functional-fitting and demonstrative results are obtained with the multi-group pin-by-pin diffusion code COBAYA3 for representative PWR configurations.