α-B-Keggin型杂多化合物K_5H[Co_4(VW_9O_(33))_2]·5H_2O的合成和结构

合成了新化合物K_5H[Co_4(VW_9O_(33))·5H_2O,并运用IR,UV-ViS,DTA和单晶X射线衍射对其结构进行了表征.测定结果证实标题化合物具有α-B-Keggin型结构,两个(VW_9O_(33)~(7-)结构单元由四个Co(Ⅱ)O_6 八面体连接.杂多化合物属单斜晶系P2_(1/n),a=1.2307(3)nm,b=2.1250(4)nm,c=1.5817(3)nm,β=91.86(3)°,V=4.1343(14)nm~3,R=0.0895,R_w=0.2180.

Ce~（3＋），Tb~（3＋）在Al_4B_2O_9和Al_（18）B_4O_（33）基质中的发光

采用固相反应法在Ａｌ２Ｏ３－Ｂ２Ｏ３体系中合成了Ａｌ４Ｂ２Ｏ９和Ａｌ１８Ｂ４Ｏ３３两个相关化合物，测定了在两种基质中Ｃｅ３＋，Ｔｂ３＋和Ｃｅ３＋－Ｔｂ３＋的光谱，观察到在两种基质中Ｃｅ３＋的光谱相似，Ｃｅ３＋的发射峰位置在Ａｌ１８Ｂ４Ｏ３３中比Ａｌ４Ｂ２Ｏ９稍有红移。实验表明，Ａｌ１８Ｂ４Ｏ３３将是一种好的发光基质

n-C_(16)H_(33)NH_3X和(n-C_(16)H_(33)NH_3)_2MX_4的红外光谱研究

在室温和液氮温度下研究了(n-C_(16)H_(33)NH_3)_2MX_4(简称C_(16)MX)及其相应化合物n-C_(16)H_(33)NH_3X(简称C_(16)X)于4000～50cm~(-1)范围的红外光谱。结果表明,它们都形成N-H…X型氢键,氢键强度是C_(16)X大于C_(16)MX。后者氢键的强度是按Cl>Br>I的顺序递减。C_(16)MX的光谱性质可按金属离子性质分为Cu~(2+)(Cu~(2+)、Cd~(2+)、Mn~(2+))和Zn~(2+)(Zn~(2+)、Co~(2+))两组,阴离子配位多面体的形状对其光谱性质有明显影响。还比较了室温与低温下的远红外光谱,证明了M—X键是离子键。

文33块沙二下段油藏动态模型及剩余油预测

By applying synthetically multi-subject theories, methods and technology, such as petroleum geology, sedimentology, seep mechanics, geochemistry, geophysics and so on; and by making full use of computer; combining quantity and quality, macroscopic and microscopic, intensive static and active description, comprehensive studying and physical modeling, 3 dimension and 4 dimension description; the paper took Wen-33 block of Zhongyuan oil field as an example; and studied reservoir macroscopic and microscopic parameter changing rule and evolve mechanics in different water-blood stage. The reservoir dynamic model and remaining-oil distribution mode was established, and several results were achieved as follows: (1) Three types of parameter gaining, optimizing and whole data body of Wen33th reservoir were established. Strata framework, structure framework, reservoir types and distribution of Wen33th reservoir were discussed. Reservoir genesis types, space distribution law and evolve rule of Wen33th reservoir were explained. 4D dynamic model of macroscopic parameter of reservoir flow dynamic geologic function of Wen33th reservoir was established. The macroscopic remaining-oil distribution and control factor was revealed. The models of the microscopic matrix field, pore-throat network field, fluid field, clay mineral field of Wen-33 block were established. The characters, changing rules and controlled factors in different water stage were revealed. The evolve rule and mechanics of petroleum fluid field in Wen-33 block reservoir were revealed. Macroscopic and microscopic remaining oil distribution mode of Wen-33 block were established. Seven types, namely 12 shapes of dynamic model of microscopic remaining oil were discussed, and the distribution of mover remaining oil was predicted. Emulation model: mathematical model and prediction model of Wen-33 block were established. The changing mechanics of reservoir parameter and distribution of remaining-oil were predicted. Firstly, the paper putting forward that the dynamic geologic function of petroleum development is the factor of controlling remaining-oil, which is the main factor leading to matrix field, network field, clay mineral field, fluid field, physic and chemical field, stress field and fluid field forming and evolving. (10) A set of theories, methods and technologies of investigating, describing, characterizing and predicting complex fault-block petroleum were developed.

Practice links [Issue 33, April 2009]

Practice Links is a free e-publication for practitioners working in Irish social services, voluntary and nongovernmental sectors. Practice Links was created to enable practitioners to keep up-to-date with new publications, electronic resources and conference opportunities. Issue 33 features the Biennial child protection and welfare social work conference.